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21.
公开(公告)号:US20200017677A1
公开(公告)日:2020-01-16
申请号:US16468062
申请日:2017-12-06
Applicant: 3M INNOVATIVE PROPERTIES COMPANY
Inventor: Ying Lin , Hassan Sahouani , Michael A. Kropp , Matthew J. Kryger , Luke E. Heinzen , Jonathan W. Kemling
Abstract: A catalyst-containing particle including a core and an acidic coating layer thereon, wherein the core includes a nitrogen-containing catalyst for a thermoset polymeric system, and the acidic coating layer comprises a binder; and a method of making such particles. A curable, one-part epoxy/thiol resin composition that includes: an epoxy/thiol resin mixture including: an epoxy resin component that includes an epoxy resin having at least two epoxide groups per molecule; a thiol component that includes a polythiol compound having at least two primary thiol groups; and catalyst-containing particles dispersed in the epoxy/thiol resin mixture; wherein each particle includes a core and an acidic coating layer thereon, wherein the core includes a nitrogen-containing catalyst for the epoxy resin; and a method of curing such curable composition.
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公开(公告)号:US11884850B2
公开(公告)日:2024-01-30
申请号:US16643606
申请日:2018-09-14
Applicant: 3M INNOVATIVE PROPERTIES COMPANY
Inventor: Eric G. Larson , Michael A. Kropp , Matthew J. Kryger , Shijing Cheng
CPC classification number: C09J7/35 , C09J11/06 , F16B15/0092 , C09J2433/00 , C09J2463/00
Abstract: A thermally curable adhesive film, a tape, and a method of making the tape, wherein the film includes: a crosslinked (meth)acrylate matrix; and a thermally curable, one-part epoxy/thiol resin composition incorporated within the crosslinked (meth)acrylate matrix; wherein the thermally curable, one-part epoxy/thiol resin composition comprises: an epoxy resin component comprising an epoxy resin having at least two epoxide groups per molecule; a thiol component comprising a polythiol compound having at least two thiol groups; a nitrogen-containing catalyst for the epoxy resin; and an organic acid.
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公开(公告)号:US20230012969A1
公开(公告)日:2023-01-19
申请号:US17762498
申请日:2020-10-02
Applicant: 3M INNOVATIVE PROPERTIES COMPANY
Inventor: Mario A. Perez , Li Yao , Eumi Pyun , Binhong Lin , Michael A. Kropp , Kalc C. Vang , Matthew J. Kryger
IPC: C08G61/08 , C08K3/38 , H01M50/193
Abstract: A composition is described comprising a cyclic olefin; a ring opening metathesis polymerization catalyst; and at least 40 wt. % of thermally conductive particles. The thermally conductive particles are selected such that the composition after curing has a thermal conductivity of at least 1W/M*K. In one embodiment, the thermally conductive particle comprises a combination of smaller and larger thermally conductive particles. In another embodiment, the thermally conductive particles comprise boron nitride particles. Also described are (e.g. structural) adhesives, methods of bonding and articles.
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24.
公开(公告)号:US20220396658A1
公开(公告)日:2022-12-15
申请号:US17770366
申请日:2020-12-10
Applicant: 3M INNOVATIVE PROPERTIES COMPANY
Inventor: Kolby L. White , Li Yao , Joseph D. Rule , Matthew J. Kryger , Michael A. Kropp
Abstract: The present disclosure provides a two-part composition polymeric material including a first part and a second part. The first part includes an inorganic filler and a polymeric material including a polymerized reaction product of a polymerizable composition including components. The components include a uretdione-containing material including a reaction product of a diisocyanate reacted with itself; a first hydroxyl-containing compound; and an optional second hydroxyl-containing compound having a single OH group. The second part includes a polythiol having an average sulfhydryl group functionality of 2 or greater. Further, a method of adhering two substrates is provided, including obtaining a two-part composition; combining at least a portion of the first part with at least a portion of the second part to form a mixture; disposing at least a portion of the mixture on a first substrate; and contacting a second substrate with the mixture disposed on the first substrate. The disclosure also provides a polymerized product of the two-part composition and a battery module. Advantageously, two-part compositions can be used as coatings and adhesive systems including high loadings of inorganic filler, such as thermally conductive filler, with handling and performance similar to existing two-part urethane systems, but with less sensitivity to water.
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公开(公告)号:US20210388152A1
公开(公告)日:2021-12-16
申请号:US17284817
申请日:2019-12-03
Applicant: 3M INNOVATIVE PROPERTIES COMPANY
Inventor: Kolby L. White , Joseph D. Rule , Michael A. Kropp , Matthew J. Kryger , Susan E. DeMoss , Jonathan D. Zook , Zachary J. Thompson
Abstract: The present disclosure provides a polymeric material including a polymerized reaction product of a polymerizable composition including components and has a solids content of 90% or greater. The components include a uretdione-containing material including a reaction product of a diisocyanate reacted with itself; a first hydroxyl-containing compound; an optional second hydroxyl-containing compound having a single OH group; an epoxy component; and an accelerator. The first hydroxyl-containing compound has more than one OH group and the optional second hydroxyl-containing compound is a primary alcohol or a secondary alcohol. The present disclosure also provides a two-part composition, in which a polymeric material is included in the first part and the second part includes at least one thiol-containing compound. Further, a method of adhering two substrates is provided, including obtaining a two-part composition; combining at least a portion of the first part with at least a portion of the second part to form a mixture; disposing at least a portion of the mixture on a first substrate; and contacting a second substrate with the mixture disposed on the first substrate. The disclosure also provides a polymeric material and a method of making a two-part composition. Advantageously, two-part compositions according to the present disclosure can be used as coatings and adhesive systems with handling and performance similar to existing two-part urethane systems, but with less sensitivity to water.
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公开(公告)号:US20210340309A1
公开(公告)日:2021-11-04
申请号:US17284814
申请日:2019-12-04
Applicant: 3M INNOVATIVE PROPERTIES COMPANY
Inventor: Kolby L. White , Joseph D. Rule , Matthew J. Kryger , Michael A. Kropp , Jay S. Schlechte , Zachary J. Thompson
IPC: C08G18/79 , C08G18/80 , C08G18/58 , C08G18/32 , C08G18/50 , C08G18/48 , C09D175/12 , C09J175/12
Abstract: The present disclosure provides a polymeric material including a polymerized reaction product of a polymerizable composition including components and has a solids content of 90% or greater. The components include a uretdione-containing material including a reaction product of a diisocyanate reacted with itself; a first hydroxyl-containing compound; an optional second hydroxyl-containing compound having a single OH group, wherein; and an epoxy component. The epoxy component is present in an amount of 35% by weight or greater, based on the total weight of the polymerizable composition. The first hydroxyl-containing compound has more than one OH group and the optional second hydroxyl-containing compound is a primary alcohol or a secondary alcohol. The present disclosure also provides a two-part composition, in which the polymeric material is included in the first part and the second includes at least one amine. Further, a method of adhering two substrates is provided, including obtaining a two-part composition; combining at least a portion of the first part with at least a portion of the second part to form a mixture; disposing at least a portion of the mixture on a first substrate; and contacting a second substrate with the mixture disposed on the first substrate. The disclosure also provides a polymeric material and a method of making a two-part composition. Advantageously, two-part compositions can be used as coatings and adhesive systems with handling and performance similar to existing two-part urethane systems, but with less sensitivity to water, or with performance similar to toughened epoxy systems.
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公开(公告)号:US20210317252A1
公开(公告)日:2021-10-14
申请号:US17265049
申请日:2019-09-19
Applicant: 3M INNOVATIVE PROPERTIES COMPANY
Inventor: Kolby L. White , Matthew J. Kryger , Joseph D. Rule , Michael A. Kropp , Adrian T. Jung
IPC: C08G18/22 , C08G18/28 , C08G18/32 , C08G18/42 , C08G18/48 , C08G18/50 , C08G18/78 , C08G18/79 , C08G18/80 , C08G59/40 , C08G59/50 , C09D175/12 , C09J175/12 , B32B7/12 , B32B37/12
Abstract: The present disclosure provides a polymeric material including a polymerized reaction product of a polymerizable composition including components, and a thermally activatable amine curative, and has a solids content of 90% or greater. The components include a uretdione-containing material including a reaction product of a diisocyanate reacted with itself; a first hydroxyl-containing compound; and an optional second hydroxyl-containing compound having a single OH group. The first hydroxyl-containing compound has more than one OH group and the optional second hydroxyl-containing compound is a primary alcohol or a secondary alcohol. The present disclosure also provides a two-part composition, in which a polymeric material is included in the first part and the second part includes at least one liquid amine. Further, a method of adhering two substrates is provided, including obtaining a two-part composition; combining at least a portion of the first part with at least a portion of the second part to form a mixture; disposing at least a portion of the mixture on a first substrate; and contacting a second substrate with the mixture disposed on the first substrate. The disclosure also provides a polymeric material and a method of curing a two-part composition. Advantageously, two-part compositions according to the present disclosure can be used as coatings and adhesive systems having a two-step cure with handling and performance similar to existing two-part urethane systems, but with less sensitivity to water.
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公开(公告)号:US11084959B2
公开(公告)日:2021-08-10
申请号:US16305907
申请日:2017-06-21
Applicant: 3M INNOVATIVE PROPERTIES COMPANY
Inventor: Hassan Sahouani , Ying Lin , Mary M. Caruso Dailey , Jing Fang , Kim M. Vogel , Michael A. Kropp , Matthew J. Kryger
IPC: C09J163/00 , B32B7/12 , B32B15/18 , B32B15/092 , C08G59/14 , C08K5/3492
Abstract: Curable compositions are provided including a curable system that requires a thermally generated amine to cause curing of the system, and a self-assembled particle distributed in the curable system. The curable system contains at least one reactive moiety and the self-assembled particle comprises a reactive amine ionically bound to a chromonic network. A multilayer article is also provided, including a substrate, a chromonic amine layer disposed on the substrate, and a curable layer disposed on the chromonic amine layer. Methods of making a cured composition and of adhering two substrates together are further provided.
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29.
公开(公告)号:US11059967B2
公开(公告)日:2021-07-13
申请号:US16468062
申请日:2017-12-06
Applicant: 3M INNOVATIVE PROPERTIES COMPANY
Inventor: Ying Lin , Hassan Sahouani , Michael A. Kropp , Matthew J. Kryger , Luke E. Heinzen , Jonathan W. Kemling
Abstract: A catalyst-containing particle including a core and an acidic coating layer thereon, wherein the core includes a nitrogen-containing catalyst for a thermoset polymeric system, and the acidic coating layer comprises a binder; and a method of making such particles. A curable, one-part epoxy/thiol resin composition that includes: an epoxy/thiol resin mixture including: an epoxy resin component that includes an epoxy resin having at least two epoxide groups per molecule; a thiol component that includes a polythiol compound having at least two primary thiol groups; and catalyst-containing particles dispersed in the epoxy/thiol resin mixture; wherein each particle includes a core and an acidic coating layer thereon, wherein the core includes a nitrogen-containing catalyst for the epoxy resin; and a method of curing such curable composition.
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公开(公告)号:US20210062048A1
公开(公告)日:2021-03-04
申请号:US17048338
申请日:2019-04-11
Applicant: 3M INNOVATIVE PROPERTIES COMPANY
Inventor: Thomas B. Galush , David T. Amos , Edward E. Cole , Daniel R. Fronek , Naiyong Jing , Matthew J. Kryger , Kiu-Yuen Tse , Scott A. Van Wert
Abstract: Tapes including an elastomeric backing layer having two major surfaces, wherein the backing layer includes a high temperature resistant elastomer (e.g., a high consistency silicone rubber elastomer), and a pressure sensitive adhesive layer, wherein the pressure sensitive adhesive layer comprises a silicone pressure sensitive adhesive.
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