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公开(公告)号:US12104827B2
公开(公告)日:2024-10-01
申请号:US17919306
申请日:2021-05-06
Applicant: 3M INNOVATIVE PROPERTIES COMPANY
Inventor: Adam D. Miller , Timothy J. Hebrink , Neeraj Sharma
IPC: F24S20/63 , F24S10/70 , F24S23/74 , F24S70/225 , F24S23/70
CPC classification number: F24S20/63 , F24S10/70 , F24S23/74 , F24S70/225 , F24S2023/84
Abstract: A hybrid solar window comprises: at least one glazing; a wave-length-selective solar mirror positioned to reflect IR toward an IR absorbing element. The IR absorbing elements comprises a conduit having a respective fluid inlet and fluid outlet, and an IR absorbing compound, wherein the IR absorbing compound is in thermal communication with the conduit. The wavelength-selective solar mirror has an average visible light transmittance of at least 50 percent and an average IR reflectance of at least 50 percent over the wavelength range of 850 to 1150 nanometers, inclusive. The IR absorbing element is configured to transfer thermal energy to a heat transfer fluid circulating through the conduit, wherein the IR absorbing element has an average visible light transmittance of at least 30 percent, and wherein each IR absorbing element has an average IR absorptance of at least 50 percent over the wavelength range 850 to 1150 nanometers, inclusive. Certain IR absorbing elements are also disclosed.
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公开(公告)号:US20240322052A1
公开(公告)日:2024-09-26
申请号:US18189399
申请日:2023-03-24
Applicant: 3M INNOVATIVE PROPERTIES COMPANY
Inventor: Sean M. Sweetnam , Stephen P. Maki , Timothy J. Hebrink , David J. Rowe , Daniel M. Pierpont , Kevin W. Gotrik , James A. Phipps
IPC: H01L31/0216 , G02B1/10
CPC classification number: H01L31/02164 , G02B1/10
Abstract: Ultraviolet light shielding articles are provided. An ultraviolet light shielding article includes a flexible substrate having a major surface and a multilayer optical film disposed on the major surface of the substrate. The multilayer optical film is comprised of at least a plurality of alternating first and second inorganic optical layers collectively reflecting and absorbing at an incident light angle of at least one of 0°, 15°, 30°, 45°, 60°, or 75°, an average of at least 50, 60, 70, 80, 90, or 95 percent of incident ultraviolet light over at least a 30-nanometer wavelength reflection bandwidth in a wavelength range from 190 nanometers (nm) to 400 nm. Solar cell covers including an ultraviolet shielding articles are also provided.
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23.
公开(公告)号:US20240229227A1
公开(公告)日:2024-07-11
申请号:US18559484
申请日:2022-03-09
Applicant: 3M INNOVATIVE PROPERTIES COMPANY
Inventor: Sean M. Sweetnam , Stephen P. Maki , Timothy J. Hebrink , Daniel M. Pierpont , Mark D Weigel , David J Rowe , Brandon R Pietz , Christopher S. Lyons , Kevin D. Hagen
CPC classification number: C23C14/35 , C08J7/0423 , C23C14/0036 , C23C14/0676 , C23C14/08 , C23C14/12 , C23C14/24 , C23C14/5833 , C08J2323/28 , C08J2433/08 , C08J2467/02
Abstract: Barrier films including a (co)polymeric substrate, at least one dyad on the substrate, each dyad made of a (co)polymer layer and an oxide layer overlaying the (co)polymer layer, and an outer (co)polymer layer overlaying the dyads. Optionally, at least one outer oxide layer overlays the outer (co)polymer layer. The barrier films transmit visible light and transmits, at an incident light angle of at least one of 0°, 30°, 45°, 60°, or 75°, at most 70 percent of incident ultraviolet light at a wavelength range from at least 100 nanometers to 400 nanometers or in a wavelength range from at least 100 nm to 350 nm. The barrier films exhibit atomic oxygen degradation of less than 1×10−20 mg/atom. The barrier films may be applied to decorative objects or electronic devices, (e.g., light receiving or emitting devices, in a satellite or aircraft. Methods of making the barrier films also are disclosed.
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公开(公告)号:US20240114905A1
公开(公告)日:2024-04-11
申请号:US18274779
申请日:2022-01-28
Applicant: 3M INNOVATIVE PROPERTIES COMPANY
Inventor: Mahfuza B. Ali , Jodi L. Connell , Judith M. Invie , Narina Y. Stepanova , Bryan V. Hunt , Timothy J. Hebrink
Abstract: The composition includes an antimicrobial monomer represented by formula CH2═C(R1)—C(O)—O-Q-N+(R)2CnH2n+1(X—), a non-fluorinated crosslinking monomer having at least two acrylate groups, methacrylate groups, or a combination thereof, a polar monomer having at least one of acrylic acid, methacrylic acid, or a carboxylate salt thereof, and a nonpolar monomer represented by formula CH2═C(R1)—C(O)—O—R2. The antimicrobial monomer, the non-fluorinated crosslinking monomer, the polar monomer, and the nonpolar monomer together account for greater than 95 percent by weight, based on the total weight of the composition. The article includes a film having a plurality of pendent groups represented by formula —C(O)—O-Q-N+(R)2CnH2n+1(X—) covalently bonded in a crosslinked non-fluorinated acrylic network. A method of making an article is also described.
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公开(公告)号:US20230213243A1
公开(公告)日:2023-07-06
申请号:US17996437
申请日:2021-04-16
Applicant: 3M INNOVATIVE PROPERTIES COMPANY
Inventor: Timothy J. Hebrink , Milind B. Sabade
Abstract: Passive cooling articles may include a first element defining a high absorbance in an atmospheric infrared wavelength range and a high average reflectance in a solar wavelength range. The first element may define a first major surface (114, 214, 314, 414) positioned and shaped to reflect solar energy in the solar wavelength range to an energy absorber (108, 208, 308, 408, 508, 608) spaced a distance from the first major surface (114, 214, 314, 414). The energy absorber (108, 208, 308, 408, 508, 608) may be a heating panel or a photovoltaic cell. A second element may define a high thermal conductivity and thermally coupled to a second major surface (116, 216, 416) of the first element to transfer thermal energy from the second element to the first element to cool the second element.
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公开(公告)号:US20230011414A1
公开(公告)日:2023-01-12
申请号:US17783843
申请日:2020-12-15
Applicant: 3M INNOVATIVE PROPERTIES COMPANY
Inventor: Timothy J. Hebrink , Michelle M. S. Mok , Vivian W. Jones , Milind B. Sabade , James P. Burke , James A. Phipps
Abstract: A composite cooling film including non-fluorinated organic polymeric layer, a metal layer disposed inwardly of the non-fluorinated organic polymeric layer, and an antisoiling, ultraviolet-absorbing hardcoat layer that is disposed outwardly of the non-fluorinated organic polymeric layer.
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公开(公告)号:US20220112319A1
公开(公告)日:2022-04-14
申请号:US17298218
申请日:2019-11-19
Applicant: 3M INNOVATIVE PROPERTIES COMPANY
Inventor: Timothy J. Hebrink , Jeffrey O. Emslander , Katelyn M. Leniczek , Jacob D. Young , Darrin H. Lee , Chris R. Birkholz , Jinsheng Zhou , Pingfan Wu , Derek J. Dehn , Christopher J. Rother
IPC: C08F214/26 , C08F214/22 , C08F214/28 , B29C48/08 , B29C48/18 , C08F220/06 , C08F210/02
Abstract: A composite film comprises first and second layers. The first layer comprises a first copolymer of monomers comprising tetrafluoroethylene, hexafluoropropylene, and vinylidene fluoride, wherein the first copolymer contains at least 35 mole percent of vinylidene fluoride monomer units. The second layer is disposed on the first layer, and comprises a second copolymer comprising 50 to 83 weight percent of ethylene monomer units and at least 17 weight percent of alkyl (meth)acrylate monomer units represented by the formula (I) wherein R1 is H or methyl, and each R2 is independently an alkyl group having from 1 to 4 carbon atoms. Methods of making the composite film and articles including it are also disclosed.
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公开(公告)号:US11254104B2
公开(公告)日:2022-02-22
申请号:US16086138
申请日:2017-03-27
Applicant: 3M INNOVATIVE PROPERTIES COMPANY
Inventor: Timothy J. Hebrink , Joseph A. Richie , Jacob D. Young
IPC: B32B27/08 , B32B27/18 , B32B27/30 , B32B27/32 , B32B27/36 , B32B27/40 , B32B7/02 , B32B3/30 , B32B27/20 , B32B27/28
Abstract: A multilayer fluoropolymer film comprising, in order: a first layer comprising a first polymer, the first polymer comprising at least 35 mol percent tetrafluoroethylene comonomer, at least 15 mole percent vinylidene fluoride comonomer, and at least 5 mol percent hexafluoropropylene comonomer, based on the total mol percent of the first polymer; a second layer comprising a second polymer, the second polymer comprising at least 50 mol percent vinylidene fluoride comonomer, based on the total mol percent of the second polymer; and a third layer comprising a third polymer, the third polymer comprising at least 50 mol percent methylmethacrylate comonomer, based on the total mol percent of the third polymer. The multilayer fluoroplymer films are useful for example, in multi-layer film applications (e.g., traffic sign protection, commercial graphic protection, paint protection, windows, windshields, building exteriors, and photo voltaics).
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公开(公告)号:US10914878B2
公开(公告)日:2021-02-09
申请号:US16464123
申请日:2017-12-12
Applicant: 3M INNOVATIVE PROPERTIES COMPANY
Inventor: Timothy J. Hebrink , Todd G. Pett
IPC: G02B5/26 , B42D25/382 , B42D25/387 , G01N21/64 , G02B5/20 , G02B5/08 , G02B5/28 , B42D25/328 , B42D25/355 , B42D25/23 , B42D25/28 , B42D25/29
Abstract: Various embodiments disclosed relate to multilayer films including hidden fluorescent features. The present disclosure includes a multilayer optical film including an isotropic multilayer optical film having first and second opposed major surfaces. The isotropic multilayer optical film reflects at least 50% of a light that is at least one of ultraviolet light or visible light, having an incident angle less than a cutoff angle from normal to the first major surface of the isotropic multilayer optical film, wherein the cutoff angle is in a range from 10° to 70°. The isotropic multilayer optical film allows at least 50% of the light having an incident angle of more than the cutoff angle from normal to the first major surface of the isotropic multilayer optical film to pass through the isotropic multilayer optical film. The isotropic multilayer optical film includes a marking on the second major surface of the isotropic multilayer optical film, the marking including at least one fluorescent compound. Various embodiments of multilayer optical films described herein are useful, for example, as anti-counterfeiting features, such as in identification documents or cards, currency, labels for pharmaceuticals or other high value products, or financial cards.
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30.
公开(公告)号:US09670300B2
公开(公告)日:2017-06-06
申请号:US14654121
申请日:2013-12-20
Applicant: 3M INNOVATIVE PROPERTIES COMPANY
Inventor: David B. Olson , Patricia M. Savu , Timothy J. Hebrink
IPC: C08F220/10 , H01L31/0203 , C08F220/22 , C08F220/34 , C08J5/18 , C08F220/14 , C08L33/10 , C08F220/30
CPC classification number: C08F220/10 , C08F220/14 , C08F220/22 , C08F220/34 , C08F2220/303 , C08J5/18 , C08J2327/16 , C08J2333/10 , C08J2333/16 , C08J2427/16 , C08J2433/12 , C08L33/10 , H01L31/0203 , C08F2220/346 , C08F2220/302 , C08L27/16
Abstract: A thermoplastic copolymer that includes a first divalent unit having a pendent ultraviolet absorbing group and a second divalent unit that is fluorinated. A fluoropolymer composition including the thermoplastic copolymer is also disclosed.
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