Abstract:
A moisture-curable composition includes a polymer preparable by free-radical copolymerization of monomers comprising at least one monomer A and at least one monomer B. Monomer(s) A comprise free-radically polymerizable hydrolyzable silane. Monomer(s) B include a divalent group selected from the group consisting of —(CF2O)a—, —(CF2CF2O)b—, —(CF2CF2CF2O)c—, —(CF2CF2CF2CF2O)d—, —(CF2CF(CF3)O)e—, and combinations thereof, wherein a, b, c, d, and e represent integers in the range of from 0 to 130, and wherein 1≦
Abstract:
Copolymers containing at least one perfluoropolyether segment and multiple aminooxalylamino groups are described. Methods of making the copolymers are also described. The copolymers can be prepared by reacting an oxalylamino-containing compound and an amine compound having at least two primary amino groups, at least two secondary amino groups, or at least one primary amino group plus at least one secondary amino group.
Abstract:
A curable composition comprises (a) at least one polyorganosiloxane, fluorinated polyorganosiloxane, or combination thereof comprising reactive silane functionality comprising at least two hydroxysilyl moieties; (b) at least one polyorganosiloxane, fluorinated polyorganosiloxane, or combination thereof comprising reactive silane functionality comprising at least two hydrosilyl moieties; and (c) at least one photoactivatable composition comprising at least one organoborate salt selected from tetraarylborate, triarylorganoborate, diaryldiorganoborate, and aryltriorganoborate salts (and combinations thereof) of at least one base selected from amidines, guanidines, phosphazenes, proazaphosphatranes, and combinations thereof; wherein at least one of the components (a) and (b) has an average reactive silane functionality of at least three.
Abstract:
A curable composition comprises (a) at least one polyorganosiloxane, fluorinated polyorganosiloxane, or combination thereof comprising reactive silane functionality comprising at least two hydroxysilyl moieties; (b) at least one polyorganosiloxane, fluorinated polyorganosiloxane, or combination thereof comprising reactive silane functionality comprising at least two hydrosilyl moieties; and (c) a catalyst composition comprising (1) at least one base selected from amidines, guanidines, phosphazenes, proazaphosphatranes, and combinations thereof, and (2) at least one Lewis acid; wherein at least one of the components (a) and (b) has an average reactive silane functionality of at least three.
Abstract:
An article (100) has a polyester film backing (110) and a primer layer (120) including a carboxylated styrene butadiene copolymer crosslinked with a polyfunctional aziridine disposed on a major surface of the polyester film backing (110). Another article includes a polyester backing (110), a primer layer (120) including a carboxylated styrene butadiene copolymer crosslinked with a polyfunctional aziridine disposed on a major surface of the polyester backing (110), and a phenolic layer (140) disposed on the primer layer (120) on a surface opposite the polyester backing (110). The phenolic layer (120) can include abrasive particles (160). Processes for making the articles are also described, as well as methods for abrading a workpiece and improving adhesion between a polyester film backing (110) and a phenolic layer (120) on the polyester backing (110).
Abstract:
Described herein is a pressure sensitive adhesive is comprising: (a) a high molecular weight (meth)acrylate polymer wherein the high molecular weight (meth)acrylate polymer is derived from (i) a C4 to C24 (meth)acrylate ester monomer; and (ii) 0 to less than 10 wt % of a polar comonomer based on the weight of the high molecular weight (meth)acrylate polymer; and (b) 10 to 100 parts of a low molecular weight fluorinated polymer per 100 parts of the high molecular weight (meth)acrylate polymer, wherein the low molecular weight fluorinated polymer has a glass transition temperature (Tg) of less than 40° C. The low molecular weight fluorinated polymer is preferably derived from fluorinated (meth)acrylate, fluorinated (meth)acrylate comprising a sulfonylamide group, fluorinated vinyl monomers, fluorinated vinyl ethers, or fluorinated styrene.
Abstract:
Fluorinated silane compounds, compositions containing the fluorinated silane compounds, and articles prepared using the fluorinated silane compounds and compositions are described. The fluorinated silane compounds can be soluble or dispersible in aqueous media, such as water, and can be used to coat articles, such as glass articles.
Abstract:
Antistatic polymers include divalent segments having the formulas (I) and (II) and wherein R1 represents an alkyl group having from 1 to 18 carbon atoms, R2 and R3 represent alkyl groups having from 1 to 4 carbon atoms, R4 represents an alkylene group having from 2 to 8 carbon atoms, and R5 independently represents H or methyl. Methods of making antistatic polymers are also disclosed.
Abstract:
Modified poly(diorganosiloxanes), compositions, and articles comprising the same. The modified poly(diorganosiloxanes) can be soluble or dispersable in aqueous media. The articles can have modified poly(diorganosiloxanes) affixed thereto.
Abstract:
Antistatic polymers include divalent segments having the formulas (I) and (II) and wherein R1 represents an alkyl group having from 1 to 18 carbon atoms, R2 and R3 represent alkyl groups having from 1 to 4 carbon atoms, R4 represents an alkylene group having from 2 to 8 carbon atoms, and R5 independently represents H or methyl. Methods of making antistatic polymers are also disclosed.