公开(公告)号：US20170098765A1

公开(公告)日：2017-04-06

申请号：US15245994

申请日：2016-08-24

Applicant: PHILLIPS 66 COMPANY

Inventor： Brian Worfolk ,  Nneka Uguru Eboagwu ,  Joseph Bullock

IPC: H01L51/00

CPC classification number: H01L51/002 ,  H01L51/0047 ,  H01L51/4273 ,  H01L2251/306 ,  Y02E10/549

Abstract: A process of reacting (SnOx)yZnO(1-y) and a fullerene dopant to produce an electron transport layer. (SnOx)yZnO(1-y) is produced from reacting an organic Zn precursor in the amounts of (1-y); an organic Sn precursor in the amounts of y; and a base in the amount of (1-y) to 1.

公开(公告)号：US11639421B2

公开(公告)日：2023-05-02

申请号：US17238578

申请日：2021-04-23

Applicant: PHILLIPS 66 COMPANY

Inventor： Hualong Pan ,  Kathy Woody ,  Brian Worfolk ,  Taeshik Earmme

IPC: C08G75/32 ,  C08G75/06

Abstract: A random copolymer comprising the monomer units A and B. In this random copolymer A comprises and B comprises Additionally, R1 R2, R3 and R4 are side chains independently selected from the group consisting of: H, Cl, F, CN, alkyl, alkoxy, alkylthio, ester, ketone and aryl groups. X1 and X2 are different and at least one is a Cl and the other is selected from the group consisting of: H, F, CN, alkyl, alkoxy, ester, ketone, amide and aryl groups.

公开(公告)号：US11629231B2

公开(公告)日：2023-04-18

申请号：US17238523

申请日：2021-04-23

Applicant: PHILLIPS 66 COMPANY

Inventor： Hualong Pan ,  Kathy Woody ,  Brian Worfolk ,  Taeshik Earmme

IPC: C08G75/32 ,  C08G75/06

Abstract: A random copolymer comprising the monomer units A and B. In this random copolymer A comprises and B comprises Additionally, R1 R2, R3 and R4 are side chains independently selected from the group consisting of: H, Cl, F, CN, alkyl, alkoxy, alkylthio, ester, ketone and aryl groups. X1 and X2 are independently selected from the group consisting of: H, Cl, F, CN, alkyl, alkoxy, ester, ketone, amide and aryl groups.

公开(公告)号：US20220380494A1

公开(公告)日：2022-12-01

申请号：US17726757

申请日：2022-04-22

Applicant: PHILLIPS 66 COMPANY

Inventor： Hualong Pan ,  Reed Eisenhart ,  Brian Worfolk ,  Laura Nielsen

IPC: C08F28/06 ,  H01L31/0216

Abstract: A polymer comprising wherein m+n=1.

公开(公告)号：US10804468B2

公开(公告)日：2020-10-13

申请号：US15644230

申请日：2017-07-07

Applicant: PHILLIPS 66 COMPANY

Inventor： Hualong Pan ,  Kathy Woody ,  Brian Worfolk ,  Taeshik Earmme

IPC: H01L51/00 ,  C08G61/12 ,  H01L51/42

Abstract: A molecular complex comprising wherein X1 and X2 are independently selected from the group consisting of: H, Cl, F, CN, alkyl, alkoxy, ester, ketone, amide and aryl groups; R1, R2, R1′ and R2′ are side chains independently selected from the group consisting of: H, Cl, F, CN, alkyl, alkoxy, alkylthio, ester, ketone and aryl groups; R3 are selected from the group consisting of alkyl group, alkoxy group, aryl groups and combinations thereof; and wherein the thiophene groups are unsymmetrical.

公开(公告)号：US20190233578A1

公开(公告)日：2019-08-01

申请号：US16254018

申请日：2019-01-22

Applicant: PHILLIPS 66 COMPANY

Inventor： Joe Bullock ,  Brian Worfolk ,  Taeshik Earmme ,  Hualong Pan ,  Kathy Woody

IPC: C08G61/12 ,  H01L51/42 ,  H01L51/00

Abstract: A polymer comprising: In this polymer R1, R2, R3, R4, R5, R6, R7, R8, R9 and Rio are independently selected from H, F, Cl, S, CN, or substituted, unsubstituted, straight-chain, branched, or cyclic alkyls ranging from 1 to 100 carbon atoms. The length of the polymer can range with n from about 1 to about 100,000 repeat units.

公开(公告)号：US10361370B2

公开(公告)日：2019-07-23

申请号：US15644253

申请日：2017-07-07

Applicant: PHILLIPS 66 COMPANY

Inventor： Hualong Pan ,  Kathy Woody ,  Brian Worfolk ,  Taeshik Earmme ,  Joseph E. Bullock

IPC: H01L51/00 ,  C08G61/12 ,  H01L51/42 ,  H01L51/44

Abstract: An organic photovoltaic device comprising an electron transport layer disposed between an anode and a polymer layer. In this organic photovoltaic device the polymer layer can also be disposed between the electron transport layer and a cathode. The electron transport layer comprises (AOx)yBO(1-y) with an optional fullerene dopant. The polymer comprises a molecular complex comprising wherein X1 and X2 are independently selected from the group consisting of: H, Cl, F, CN, alkyl, alkoxy, ester, ketone, amide and aryl groups; R1, R2, R1′ and R2′ are side chains independently selected from the group consisting of: H, Cl, F, CN, alkyl, alkoxy, alkylthio, ester, ketone and aryl groups; R3 are selected from the group consisting of alkyl group, alkoxy group, aryl groups and combinations thereof; G is an aryl group; and wherein the thiophene groups are unsymmetrical.

公开(公告)号：US20180026195A1

公开(公告)日：2018-01-25

申请号：US15644253

申请日：2017-07-07

Applicant: PHILLIPS 66 COMPANY

Inventor： Hualong Pan ,  Kathy Woody ,  Brian Worfolk ,  Taeshik Earmme ,  Joseph E. Bullock

IPC: H01L51/00

CPC classification number: H01L51/0036 ,  H01L51/0003 ,  H01L51/0028 ,  H01L51/0031 ,  H01L51/0047 ,  H01L51/4246 ,  H01L51/4253 ,  H01L51/441 ,  Y02E10/549

Abstract: An organic photovoltaic device comprising an electron transport layer disposed between an anode and a polymer layer. In this organic photovoltaic device the polymer layer can also be disposed between the electron transport layer and a cathode. The electron transport layer comprises (AOx)yBO(1-y) with an optional fullerene dopant. The polymer comprises a molecular complex comprising wherein X1 and X2 are independently selected from the group consisting of: H, Cl, F, CN, alkyl, alkoxy, ester, ketone, amide and aryl groups; R1, R2, R1′ and R2′ are side chains independently selected from the group consisting of: H, Cl, F, CN, alkyl, alkoxy, alkylthio, ester, ketone and aryl groups; R3 are selected from the group consisting of alkyl group, alkoxy group, aryl groups and combinations thereof; G is an aryl group; and wherein the thiophene groups are unsymmetrical.

公开(公告)号：US20170098773A1

公开(公告)日：2017-04-06

申请号：US15245969

申请日：2016-08-24

Applicant: PHILLIPS 66 COMPANY

Inventor： Joseph Bullock ,  Brian Worfolk

IPC: H01L51/00 ,  C07C227/10 ,  C07C67/29

CPC classification number: H01L51/0047 ,  C07C67/29 ,  C07C213/06 ,  C07C227/10 ,  C07C2604/00 ,  H01L51/4253 ,  C07C219/22

Abstract: A process of dissolving in a solvent to produce a first mixture. To the first mixture a reagent is added to produce a second mixture. A H—R′—R″ is then added to the second mixture to produce a third mixture. The third mixture is then refluxed to produce

公开(公告)号：US20220363813A1

公开(公告)日：2022-11-17

申请号：US17726775

申请日：2022-04-22

Applicant: PHILLIPS 66 COMPANY

Inventor： Hualong Pan ,  Reed Eisenhart ,  Brian Worfolk ,  Laura Nielsen

IPC: C08G61/12 ,  H01L51/00

Abstract: A repeat unit comprising In the repeat unit, X1 and X2 are independently selected from the group consisting of: F, Cl, H, and combinations thereof. Additionally, in this monomer, R′ and R″ are independently selected from an alkyl group, an aryl group, or combinations thereof. Also, R3, and R4 are independently selected from unsubstituted or substituted branched alkyls with 1 to 60 carbon atoms and unsubstituted or substituted linear alkyls with 1 to 60 carbon atoms.