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![PROCESS OF PRODUCING AND APPLICATIONS OF THREE COMPONENT BENZO[1,2-B:4,5-B] DITHIOPHENE-THIENOTHIOPHENE RANDOMLY SUBSTITUTED POLYMERS FOR ORGANIC SOLAR CELLS](/abs-image/US/2015/12/03/US20150349259A1/abs.jpg.150x150.jpg)
21.发明申请PROCESS OF PRODUCING AND APPLICATIONS OF THREE COMPONENT BENZO[1,2-B:4,5-B] DITHIOPHENE-THIENOTHIOPHENE RANDOMLY SUBSTITUTED POLYMERS FOR ORGANIC SOLAR CELLS 有权三元组苯并[1,2-B：4,5-B]二苯基乙烯基苯并噻唑的有机太阳能电池的随机取代聚合物的生产和应用方法公开(公告)号：US20150349259A1
公开(公告)日：2015-12-03
申请号：US14722433
申请日：2015-05-27
Applicant: PHILLIPS 66 COMPANY
Inventor： Kathy Woody , Hui Huang , Ting He
CPC classification number: H01L51/0036 , H01L51/0043 , H01L51/0047 , H01L51/4253 , Y02E10/549
Abstract: A process of polymerizing f with wherein the stoichiometric ratio of f≈(g+h) and f, g and h are not equal to 0. This process can also have R1 selected from the group consisting of alkyl group, alkoxy group, aryl groups and combinations thereof. Additionally, x and y can be different from each other and can be independently selected from the group consisting of: alkyl group, alkoxy group, aryl groups, where y=1-3, where y=0-12, where R2 is selected from the group consisting of H, alkyl group, alkoxy group, aryl groups, where R3 is selected from the group consisting of H, alkyl group, alkoxy group, aryl groups, where R4 and R5 are independently selected from the group consisting of H, alkyl group, alkoxy group, aryl groups, —NR6R7 where R6 and R7 are independently selected from the group consisting of H, alkyl group, alkoxy group, aryl groups.
Abstract translation: 聚合f的方法，其中f≈（g + h）和f，g和h的化学计量比不等于0.该方法还可以具有选自烷基，烷氧基，芳基 及其组合。 另外，x和y可以彼此不同，并且可以独立地选自：烷基，烷氧基，芳基，其中y = 1-3，其中y = 0-12，其中R 2选自 由H，烷基，烷氧基，芳基组成的组，其中R 3选自H，烷基，烷氧基，芳基，其中R 4和R 5独立地选自H，烷基 基团，烷氧基，芳基，-NR 6 R 7，其中R 6和R 7独立地选自H，烷基，烷氧基，芳基。
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公开(公告)号：US11639421B2
公开(公告)日：2023-05-02
申请号：US17238578
申请日：2021-04-23
Applicant: PHILLIPS 66 COMPANY
Inventor： Hualong Pan , Kathy Woody , Brian Worfolk , Taeshik Earmme
Abstract: A random copolymer comprising the monomer units A and B. In this random copolymer A comprises and B comprises Additionally, R1 R2, R3 and R4 are side chains independently selected from the group consisting of: H, Cl, F, CN, alkyl, alkoxy, alkylthio, ester, ketone and aryl groups. X1 and X2 are different and at least one is a Cl and the other is selected from the group consisting of: H, F, CN, alkyl, alkoxy, ester, ketone, amide and aryl groups.
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公开(公告)号：US11629231B2
公开(公告)日：2023-04-18
申请号：US17238523
申请日：2021-04-23
Applicant: PHILLIPS 66 COMPANY
Inventor： Hualong Pan , Kathy Woody , Brian Worfolk , Taeshik Earmme
Abstract: A random copolymer comprising the monomer units A and B. In this random copolymer A comprises and B comprises Additionally, R1 R2, R3 and R4 are side chains independently selected from the group consisting of: H, Cl, F, CN, alkyl, alkoxy, alkylthio, ester, ketone and aryl groups. X1 and X2 are independently selected from the group consisting of: H, Cl, F, CN, alkyl, alkoxy, ester, ketone, amide and aryl groups.
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公开(公告)号：US11228000B2
公开(公告)日：2022-01-18
申请号：US17002964
申请日：2020-08-26
Applicant: PHILLIPS 66 COMPANY
Inventor： Hualong Pan , Kathy Woody
Abstract: A polymer comprising wherein Ar1 and Ar2 are optional and either the same or different and independently selected from an aryl group or an heteroaryl group. In this polymer, W is selected from the group consisting of: S, Se, O, and N-Q; and Q is selected from the group consisting of: a straight-chain or branched carbyl, silyl, or hydrocarbyl, a branched or cyclic alkyl with 1 to 30 atoms, a fused substituted aromatic ring, and a fused unsubstituted aromatic ring. Additionally, in the polymer, R1 is selected from the group consisting of: a straight-chain or branched carbyl, silyl, or hydrocarbyl, a branched or cyclic alkyl with 1 to 30 atoms, a fused substituted aromatic ring, and a fused unsubstituted aromatic ring and wherein x+y=1.
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公开(公告)号：US11158805B2
公开(公告)日：2021-10-26
申请号：US17002977
申请日：2020-08-26
Applicant: PHILLIPS 66 COMPANY
Inventor： Hualong Pan , Kathy Woody
Abstract: A method of forming a polymer, the method begins by combining 4,7-bis(5-bromo-4-alkylthiophen-2-yl)-5-chloro-6-fluorobenzo[c][1,2,5]thiadiazole, [4-alkyl-5-[5-(trimethylstannyl)thiophen-2-yl]thiophen-2-yl]trimethylstannane, (3,3′-difluoro-[2,2′-bithiophene]-5,5′-diyl)bis(trimethylstannane), Pd2dba3 and P(o-tol)3 to form the polymer: In this polymer R1 and R2 are independently selected from the group consisting of a straight-chain or branched carbyl, silyl, or hydrocarbyl, a branched or cyclic alkyl with 1 to 30 atoms, a fused substituted aromatic ring, and a fused unsubstituted aromatic ring; and the ratio of x is between 0.6 to 0.8 and y is between 0.2 and 0.4.
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Patent Agency Ranking
公开(公告)号：US20210066607A1
公开(公告)日：2021-03-04
申请号：US17002990
申请日：2020-08-26
Applicant: PHILLIPS 66 COMPANY
Inventor： Hualong Pan , Kathy Woody
IPC: H01L51/00
Abstract: A polymer comprising wherein Ar1 and Ar2 are optional and either the same or different and independently selected from an aryl group or an heteroaryl group. In this polymer, W is selected from the group consisting of: S, Se, O, and N-Q; and Q is selected from the group consisting of: a straight-chain or branched carbyl, silyl, or hydrocarbyl, a branched or cyclic alkyl with 1 to 30 atoms, a fused substituted aromatic ring, and a fused unsubstituted aromatic ring. Additionally, in the polymer, R4 and R5 are selected from the group consisting of: a straight-chain or branched carbyl, silyl, or hydrocarbyl, a branched or cyclic alkyl with 1 to 30 atoms, a fused substituted aromatic ring, and a fused unsubstituted aromatic ring; and x+y=1.
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公开(公告)号：US20210061797A1
公开(公告)日：2021-03-04
申请号：US17002805
申请日：2020-08-26
Applicant: PHILLIPS 66 COMPANY
Inventor： Hualong Pan , Kathy Woody , Brian J. Worfolk
IPC: C07D417/14
Abstract: A comonomer comprising: wherein W is selected from the group consisting of: S, Se, O, and N-Q; and Q is selected from the group consisting of: a straight-chain or branched carbyl, silyl, or hydrocarbyl, a branched or cyclic alkyl with 1 to 30 atoms, a fused substituted aromatic ring, and a fused unsubstituted aromatic ring. In this comonomer, A and B are independently selected from the group consisting of: H, Br, an aryl group, and a heteroaryl group.
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![Unsymmetrical benzo[1,2-b:4,5-b′]dithiophene and benzothiadiazole-based molecular complexes](/abs-image/US/2020/10/13/US10804468B2/abs.jpg.150x150.jpg)
28.发明授权公开(公告)号：US10804468B2
公开(公告)日：2020-10-13
申请号：US15644230
申请日：2017-07-07
Applicant: PHILLIPS 66 COMPANY
Inventor： Hualong Pan , Kathy Woody , Brian Worfolk , Taeshik Earmme
Abstract: A molecular complex comprising wherein X1 and X2 are independently selected from the group consisting of: H, Cl, F, CN, alkyl, alkoxy, ester, ketone, amide and aryl groups; R1, R2, R1′ and R2′ are side chains independently selected from the group consisting of: H, Cl, F, CN, alkyl, alkoxy, alkylthio, ester, ketone and aryl groups; R3 are selected from the group consisting of alkyl group, alkoxy group, aryl groups and combinations thereof; and wherein the thiophene groups are unsymmetrical.
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公开(公告)号：US20190233578A1
公开(公告)日：2019-08-01
申请号：US16254018
申请日：2019-01-22
Applicant: PHILLIPS 66 COMPANY
Inventor： Joe Bullock , Brian Worfolk , Taeshik Earmme , Hualong Pan , Kathy Woody
Abstract: A polymer comprising: In this polymer R1, R2, R3, R4, R5, R6, R7, R8, R9 and Rio are independently selected from H, F, Cl, S, CN, or substituted, unsubstituted, straight-chain, branched, or cyclic alkyls ranging from 1 to 100 carbon atoms. The length of the polymer can range with n from about 1 to about 100,000 repeat units.
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30.发明授权公开(公告)号：US10361370B2
公开(公告)日：2019-07-23
申请号：US15644253
申请日：2017-07-07
Applicant: PHILLIPS 66 COMPANY
Inventor： Hualong Pan , Kathy Woody , Brian Worfolk , Taeshik Earmme , Joseph E. Bullock
Abstract: An organic photovoltaic device comprising an electron transport layer disposed between an anode and a polymer layer. In this organic photovoltaic device the polymer layer can also be disposed between the electron transport layer and a cathode. The electron transport layer comprises (AOx)yBO(1-y) with an optional fullerene dopant. The polymer comprises a molecular complex comprising wherein X1 and X2 are independently selected from the group consisting of: H, Cl, F, CN, alkyl, alkoxy, ester, ketone, amide and aryl groups; R1, R2, R1′ and R2′ are side chains independently selected from the group consisting of: H, Cl, F, CN, alkyl, alkoxy, alkylthio, ester, ketone and aryl groups; R3 are selected from the group consisting of alkyl group, alkoxy group, aryl groups and combinations thereof; G is an aryl group; and wherein the thiophene groups are unsymmetrical.
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