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公开(公告)号：US20180002559A1
公开(公告)日：2018-01-04
申请号：US15704275
申请日：2017-09-14
Applicant: THE CLOROX COMPANY
Inventor： David R. Scheuing , David J. Lestage , Carl W. Bennett , Mona M. Knock , Charles W. Scales , William L. Smith , Rui Zhang
IPC: C09D133/02 , A01N33/12 , A01N59/00 , A01N59/16 , C09D5/14 , A01N25/10 , C11D3/395 , C11D1/62 , C11D3/37
CPC classification number: C09D133/02 , A01N25/10 , A01N33/12 , A01N59/00 , A01N59/16 , C09D5/14 , C11D1/62 , C11D3/3769 , C11D3/3953
Abstract: The present invention relates to aqueous compositions of associative polyelectrolyte complexes (PECs), optionally containing surfactants, biocidal agents and/or oxidants, which can provide surface protection to treated articles including reduced soiling tendency, reduced cleaning effort and improved soil repellancy, as well as providing bacteriostatic properties to treated surfaces that thereby gain resistance to water, environmental exposure and microbial challenge. Treatment means and compositions are provided that employ associative polyelectrolyte complexes formed by combining a water soluble cationic first polyelectrolyte with a water soluble second polyelectrolyte bearing groups of opposite charge to the first polyelectrolyte under suitable mixing conditions where the one polyelectrolyte present in molar excess is added in the form of a first aqueous solution during a mixing step to a second aqueous solution comprising the oppositely charged polyelectrolyte present in molar deficiency. Also provided are means to form stable associative polyelectrolyte complexes in aqueous solutions having R values from about 0.10 to 20, including near stoichiometric R values approaching 1, being the ratio of charged groups present on the component polyelectrolytes employed.
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公开(公告)号：US09695386B2
公开(公告)日：2017-07-04
申请号：US15404327
申请日：2017-01-12
Applicant: THE CLOROX COMPANY
Inventor： Evan Rumberger , Marisa MacNaughtan , William L. Smith , Kelsey Kornaus
IPC: C11D3/39 , C11D3/395 , C11D3/50 , C11D3/08 , C11D3/04 , C11D3/10 , C11D17/00 , C11D17/06 , A01N59/06 , A01N25/34 , C11D1/00 , C11D3/12
CPC classification number: C11D3/3953 , A01N25/08 , A01N25/34 , A01N59/06 , C01B11/064 , C01B11/066 , C11D1/00 , C11D3/04 , C11D3/042 , C11D3/044 , C11D3/046 , C11D3/08 , C11D3/10 , C11D3/12 , C11D3/1213 , C11D3/3757 , C11D3/3956 , C11D3/50 , C11D17/0073 , C11D17/041 , C11D17/06
Abstract: The invention relates to compositions, methods of use, and methods of manufacture for an intercalated bleach compound and compositions thereof. The intercalated bleach compound has the formula Mx(OCl)y(O)m(OH)n where M is an alkaline earth metal such as magnesium, calcium or mixture thereof. The values of x and y independently equal any number greater than or equal to 1 (e.g., 1, 2, 3, 4, etc.), and m and n independently equal any number greater than or equal to 0 (e.g., 0, 1, 2, 3, 4, etc.), but m and n are not both 0. In addition, the molar ratio of the alkaline earth metal (e.g., magnesium or calcium) to hypochlorite is at least 3:1. In other words, x is ≧3y. The compounds exhibit excellent stability, little or no chlorine bleach odor, exhibit excellent pH buffering characteristics, and less reactivity with organic materials as compared to alternative chlorine bleach products.
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23.发明授权公开(公告)号：US09074166B1
公开(公告)日：2015-07-07
申请号：US14659085
申请日：2015-03-16
Applicant: THE CLOROX COMPANY
Inventor： David R. Scheuing , Arun Agarwal , David E. Dabney , Gregory P. Dado , Lafayette D. Foland , Shuman Mitra , Jacqueline M. Pytel , William L. Smith , Erika Szekeres , Michael R. Terry , Kenneth L. Vieira
CPC classification number: C11D3/3953 , C11D3/3418 , C11D3/3951 , C11D3/3956
Abstract: The invention relates to compositions including a hypohalite or hypochlorous acid and a soluble salt of 2,4,6 mesitylene sulfonate. The compositions may include a surfactant, a buffer, or combinations thereof. Other adjuvants may also be present. Such compositions do not require the inclusion of high concentrations of sodium hydroxide or other soluble hydroxide salts to drastically increase pH (and thus stability), although such hydroxides may be present if desired.
Abstract translation: 本发明涉及包含次卤酸盐或次氯酸和2,4,6-三甲苯磺酸盐的可溶性盐的组合物。 组合物可以包括表面活性剂，缓冲剂或其组合。 也可以存在其它佐剂。 这样的组合物不需要包含高浓度的氢氧化钠或其它可溶性氢氧化物盐，以显着增加pH（因而稳定性），尽管如果需要可存在这种氢氧化物。
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公开(公告)号：US09074164B2
公开(公告)日：2015-07-07
申请号：US14050085
申请日：2013-10-09
Applicant: The Clorox Company
Inventor： Evan Rumberger , Marisa Macnaughtan , William L. Smith , Kelsey Kornaus
CPC classification number: C11D3/3953 , A01N25/08 , A01N25/34 , A01N59/06 , C01B11/064 , C01B11/066 , C11D1/00 , C11D3/04 , C11D3/042 , C11D3/044 , C11D3/046 , C11D3/08 , C11D3/10 , C11D3/12 , C11D3/1213 , C11D3/3757 , C11D3/3956 , C11D3/50 , C11D17/0073 , C11D17/041 , C11D17/06
Abstract: The invention relates to compositions, methods of use, and methods of manufacture for an intercalated bleach compound and compositions thereof. The intercalated bleach compound has the formula Mx(OCl)y(O)m(OH)n where M is an alkaline earth metal such as magnesium, calcium or mixture thereof. The values of x and y independently equal any number greater than or equal to 1 (e.g., 1, 2, 3, 4, etc.), and m and n independently equal any number greater than or equal to 0 (e.g., 0, 1, 2, 3, 4, etc.), but m and n are not both 0. In addition, the molar ratio of the alkaline earth metal (e.g., magnesium or calcium) to hypochlorite is at least 3:1. In other words, x is ≧3y. The compounds exhibit excellent stability, little or no chlorine bleach odor, exhibit excellent pH buffering characteristics, and less reactivity with organic materials as compared to alternative chlorine bleach products.
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25.发明授权公开(公告)号：US08933010B2
公开(公告)日：2015-01-13
申请号：US14244582
申请日：2014-04-03
Applicant: The Clorox Company
Inventor： David R. Scheuing , Travers Anderson , William L. Smith , Erika Szekeres , Rui Zhang
Abstract: The invention relates to polymer-micelle complex. The polymer-micelle complexes include a positively charged micelle selected from the group consisting of a monomeric quaternary ammonium compound, a monomeric biguanide compound, and mixtures thereof. The positively charged micelle is electrostatically bound to a water-soluble polymer bearing a negative charge. The polymer does not comprise block copolymer, latex particles, polymer nanoparticles, cross-linked polymers, silicone copolymer, fluorosurfactant, or amphoteric copolymer. The compositions do not form a coacervate, and do not form a film when applied to a surface.
Abstract translation: 本发明涉及聚合物 - 胶束复合物。 聚合物 - 胶束复合物包括选自单体季铵化合物，单体双胍化合物及其混合物的带正电荷的胶束。 带正电的胶束静电结合到带有负电荷的水溶性聚合物上。 聚合物不包含嵌段共聚物，胶乳颗粒，聚合物纳米颗粒，交联聚合物，硅氧烷共聚物，含氟表面活性剂或两性共聚物。 组合物不形成凝聚层，并且当施加到表面时不形成膜。
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Patent Agency Ranking
公开(公告)号：US20140200300A1
公开(公告)日：2014-07-17
申请号：US14227363
申请日：2014-03-27
Applicant: The Clorox Company
Inventor： David R. Scheuing , Thomas F. Fahlen , Jared Heymann , Mike Kinsinger , William Ouellette , William L. Smith
IPC: C09D147/00
CPC classification number: C09D147/00 , A01N25/10 , A01N33/12 , A01N59/00 , B01J45/00 , C09D5/14 , C09D5/1662 , C09D7/001 , C09D7/002 , C09D7/20 , C09D7/43 , C09D133/00 , C09D133/02 , C09D139/00 , C11D3/0036 , C11D3/227 , C11D3/3723 , C11D3/3757 , C11D3/3765 , C11D3/3769 , C11D3/3773 , C11D3/3776 , C11D3/378 , C11D3/3942 , C11D3/3947 , C11D3/3953 , C11D3/3956 , C11D3/48
Abstract: The invention relates to compositions and methods of treatment employing compositions comprising polyelectrolyte complexes. The compositions include a water-soluble first polyelectrolyte bearing a net cationic charge or capable of developing a net cationic charge and a water-soluble second polyelectrolyte bearing a net anionic charge or capable of developing a net anionic charge. The total polyelectrolyte concentration of the first solution is at least 110 millimolar. The composition is free of coacervates, precipitates, latex particles, synthetic block copolymers, silicone copolymers, cross-linked poly(acrylic) and cross-linked water-soluble polyelectrolyte. The composition may be a concentrate, to be diluted prior to use to treat a surface.
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27.发明授权公开(公告)号：US08728454B1
公开(公告)日：2014-05-20
申请号：US13663792
申请日：2012-10-30
Applicant: The Clorox Company
Inventor： David R. Scheuing , Travers Anderson , William L. Smith , Erika Szekeres , Rui Zhang
Abstract: The invention relates to polymer-micelle complex. The polymer-micelle complexes include a positively charged micelle selected from the group consisting of a monomeric quaternary ammonium compound, a monomeric biguanide compound, and mixtures thereof. The positively charged micelle is electrostatically bound to a water-soluble polymer bearing a negative charge. The polymer does not comprise block copolymer, latex particles, polymer nanoparticles, cross-linked polymers, silicone copolymer, fluorosurfactant, or amphoteric copolymer. The compositions do not form a coacervate, and do not form a film when applied to a surface.
Abstract translation: 本发明涉及聚合物 - 胶束复合物。 聚合物 - 胶束复合物包括选自单体季铵化合物，单体双胍化合物及其混合物的带正电荷的胶束。 带正电的胶束静电结合到带有负电荷的水溶性聚合物上。 聚合物不包含嵌段共聚物，胶乳颗粒，聚合物纳米颗粒，交联聚合物，硅氧烷共聚物，含氟表面活性剂或两性共聚物。 组合物不形成凝聚层，并且当施加到表面时不形成膜。
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公开(公告)号：US20140120054A1
公开(公告)日：2014-05-01
申请号：US13663792
申请日：2012-10-30
Applicant: THE CLOROX COMPANY
Inventor： David R. Scheuing , Travers Anderson , William L. Smith , Erika Szekeres , Rui Zhang
Abstract: The invention relates to polymer-micelle complex. The polymer-micelle complexes include a positively charged micelle selected from the group consisting of a monomeric quaternary ammonium compound, a monomeric biguanide compound, and mixtures thereof. The positively charged micelle is electrostatically bound to a water-soluble polymer bearing a negative charge. The polymer does not comprise block copolymer, latex particles, polymer nanoparticles, cross-linked polymers, silicone copolymer, fluorosurfactant, or amphoteric copolymer. The compositions do not form a coacervate, and do not form a film when applied to a surface.
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公开(公告)号：US20130273174A1
公开(公告)日：2013-10-17
申请号：US13887245
申请日：2013-05-03
Applicant: THE CLOROX COMPANY
Inventor： David R. Scheuing , David J. Lestage , Carl W. Bennett , Mona M. Knock , Charles W. Scales , William L. Smith , Rui Zhang
IPC: C09D133/02
CPC classification number: C09D133/02 , A01N25/10 , A01N33/12 , A01N59/00 , A01N59/16 , C09D5/14 , C11D1/62 , C11D3/3769 , C11D3/3953
Abstract: The present invention relates to aqueous compositions of associative polyelectrolyte complexes (PECs), optionally containing surfactants, biocidal agents and/or oxidants, which can provide surface protection to treated articles including reduced soiling tendency, reduced cleaning effort and improved soil repellancy, as well as providing bacteriostatic properties to treated surfaces that thereby gain resistance to water, environmental exposure and microbial challenge. Treatment means and compositions are provided that employ associative polyelectrolyte complexes formed by combining a water soluble cationic first polyelectrolyte with a water soluble second polyelectrolyte bearing groups of opposite charge to the first polyelectrolyte under suitable mixing conditions where the one polyelectrolyte present in molar excess is added in the form of a first aqueous solution during a mixing step to a second aqueous solution comprising the oppositely charged polyelectrolyte present in molar deficiency. Also provided are means to form stable associative polyelectrolyte complexes in aqueous solutions having R values from about 0.10 to 20, including near stoichiometric R values approaching 1, being the ratio of charged groups present on the component polyelectrolytes employed.
Abstract translation: 本发明涉及可以含有表面活性剂，杀生物剂和/或氧化剂的缔合性聚电解质配合物（PEC）的含水组合物，其可以为经处理的制品提供表面保护，包括减少污染趋势，降低清洁力和改善污垢排斥性，以及 为处理过的表面提供抑菌特性，从而获得对水的抗性，环境暴露和微生物的攻击。 提供了处理装置和组合物，其使用通过将水溶性阳离子第一聚电解质与具有相反电荷的水溶性第二聚电解质承载基团与第一聚电解质组合而形成的缔合聚电解质复合物，其中在其中加入以摩尔过量存在的一种聚电解质 在混合步骤期间第一水溶液的形式包含摩尔不足存在的相反电荷的聚电解质的第二水溶液。 还提供了在具有约0.10至20的R值的水溶液中形成稳定的缔合聚电解质络合物的方法，包括接近化学计量的R值接近1，即所用组分聚电解质上存在的带电基团的比例。
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公开(公告)号：US20130109608A1
公开(公告)日：2013-05-02
申请号：US13720743
申请日：2012-12-19
Applicant: The Clorox Company
Inventor： William L. Smith , Evan Rumberger
CPC classification number: A61K8/022 , A61K8/20 , A61K8/362 , A61Q11/02 , C11D1/22 , C11D3/10 , C11D3/2079 , C11D3/2082 , C11D3/33 , C11D3/3409 , C11D3/349 , C11D3/37 , C11D3/3761 , C11D3/3776 , C11D3/378 , C11D3/3953 , C11D17/0073
Abstract: A solid composition including calcium and/or magnesium hypochlorite, a builder (e.g., one or more of carbonate, bicarbonate, sesquicarbonate), an acid, a water-soluble polymer, at least one anionic surfactant, and optionally, a hydrotrope. The composition does not include any potassium hypochlorite, sodium hypochlorite, lithium hypochlorite, N-halogenated compounds, peroxides, persulfates, hydantoins, isocyanurates, or carboxylic acids that also have hydroxyl, amino, amido, imino, or imido groups. Upon dissolution of the composition in water, the calcium and/or magnesium hypochlorite and acid react to form hypochlorous acid. The use of hypochlorous acid, rather than direct use of an alkaline or alkaline earth hypochlorite results in a composition that is typically acidic rather than basic, and that results in improved cleaning. The composition is particularly suited tor cleaning and disinfecting dentures.
Abstract translation: 包括钙和/或次氯酸钙的固体组合物，助洗剂（例如碳酸盐，碳酸氢盐，倍半碳酸盐中的一种或多种），酸，水溶性聚合物，至少一种阴离子表面活性剂和任选的水溶助长剂。 该组合物不包括也具有羟基，氨基，酰胺基，亚胺基或亚氨基的任何次氯酸钾，次氯酸钠，次氯酸锂，N-卤代化合物，过氧化物，过硫酸盐，乙内酰脲，异氰脲酸酯或羧酸。 当组合物溶解在水中时，次氯酸钙和/或镁反应形成次氯酸。 使用次氯酸而不是直接使用碱性或碱性碱性次氯酸盐导致通常是酸性而不是碱性的组合物，并且导致改进的清洁。 该组合物特别适用于清洁和消毒假牙。
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