Intercalates and exfoliates formed with long chain (C6+) or aromatic matrix polymer-compatible monomeric, oligomeric or polymeric intercalant compounds, and composite materials containing same
    21.
    发明授权
    Intercalates and exfoliates formed with long chain (C6+) or aromatic matrix polymer-compatible monomeric, oligomeric or polymeric intercalant compounds, and composite materials containing same 失效
    与长链(C6 +)或芳族基质聚合物相容的单体,低聚或聚合物插入剂化合物形成的嵌入层和去角质层,以及含有相同的复合材料

    公开(公告)号:US06242500B1

    公开(公告)日:2001-06-05

    申请号:US09580999

    申请日:2000-05-26

    Abstract: Intercalates formed by contacting a layered material, e.g., a phyllosilicate, with an intercalant surface modifier selected from the group consisting of a compound having an alkyl radical containing at least 6 carbon atoms, a compound containing an aromatic ring, and mixtures thereof, said surface modifier including a matrix material-reactive functional group, to sorb or intercalate the intercalant surface modifier between adjacent platelets of the layered material. Sufficient intercalant surface modifier is sorbed between adjacent platelets to expand the adjacent platelets to at least about 10 Å, up to about 100 Å. The intercalated complex can be combined with an organic liquid into a viscous carrier material, for delivery of the carrier material, or for delivery of an active compound; or the intercalated complex can be combined with a matrix polymer to form a strong, filled polymer matrix.

    Abstract translation: 通过使层状材料例如页硅酸盐与选自由含有至少6个碳原子的烷基的化合物的嵌入剂表面改性剂,含有芳香环的化合物及其混合物而形成的插层体,所述表面 改性剂包括基质材料反应性官能团,以吸附或嵌​​入分层材料的相邻片晶之间的嵌入剂表面改性剂。 在相邻血小板之间吸附足够的嵌入剂表面改性剂以将相邻的血小板膨胀至至少约10埃,至多约100埃。 插入的复合物可以与有机液体结合成粘性载体材料,用于递送载体材料或递送活性化合物; 或者插层的复合物可以与基质聚合物组合以形成强的,填充的聚合物基质。

    Modified kaolins
    22.
    发明授权
    Modified kaolins 失效
    改性高岭土

    公开(公告)号:US6022821A

    公开(公告)日:2000-02-08

    申请号:US51783

    申请日:1998-04-15

    Abstract: A process for the preparation of a modified kaolin from a kaolin group mineral which includes expansion and contraction of layers of the kaolin group mineral. The layers comprising one Si-tetrahedral sheet and one Al-octahedral sheet. The expansion and contraction may be initiated by initial intercalation of a reagent which can penetrate kaolin layers to reach an interlayer region therebetween to form an intercalate. Subsequently, the intercalation nay be followed by de-intercalation which involves the removal of the reagent. By the above process, there is provided crystalline modified kaolins having the following properties: (i) an increased interlayer space compared to corresponding kaolin group minerals; (ii) an increased susceptibility to intercalation by cations, anions or salts compared to corresponding kaolin group minerals; and (iii) an increased exfoliated morphology compared to corresponding kaolin group minerals.

    Abstract translation: PCT No.PCT / AU96 / 00667 Sec。 371日期:1998年4月15日 102(e)日期1998年4月15日PCT 1996年10月23日PCT公布。 公开号WO97 / 15427 日期1997年5月1日一种由高岭土矿物制备改性高岭土的方法,包括高岭土矿物层的膨胀和收缩。 这些层包含一个Si-四面体片和一个Al-八面体片。 膨胀和收缩可以通过初始插入试剂来开始,试剂可以穿透高岭土层以达到其间的层间区域以形成插层。 随后,插层之后可以进行去夹层,其中涉及去除试剂。 通过上述方法,提供具有以下性质的结晶改性高岭土:(i)与相应的高岭土组矿物相比增加的层间距; (ii)与相应的高岭土组矿物相比,阳离子,阴离子或盐对嵌入的敏感性增加; 和(iii)与相应的高岭土组矿物相比增加的剥离形态。

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