公开(公告)号：US5162329A

公开(公告)日：1992-11-10

申请号：US704938

申请日：1991-05-23

Applicant: Oliver Wagner ,  Bernhard Zipperer ,  Norbert Goetz ,  Michael Keil ,  Eberhard Ammermann ,  Gisela Lorenz

Inventor： Oliver Wagner ,  Bernhard Zipperer ,  Norbert Goetz ,  Michael Keil ,  Eberhard Ammermann ,  Gisela Lorenz

IPC: A01N43/40 ,  C07D213/26 ,  C07D213/30 ,  C07D213/48 ,  C07D213/50 ,  C07D213/53

CPC classification number: C07D213/30 ,  A01N43/40 ,  C07D213/26 ,  C07D213/50 ,  C07D213/53

Abstract: .beta.-picoline derivatives of the formula ##STR1## where A is CR.sup.1 R.sup.2, R.sup.1 and R.sup.2 independently of each other are hydrogen, alkyl, alkenyl or alkynyl, or R.sup.1 and R.sup.2 together form a methylene chain,B is one of the groups CH.sub.2, CHOR.sup.3, CHalR.sup.4, C.dbd.O or C.dbd.N-O-R.sup.5, R.sup.3 being hydrogen, alkyl, haloalkyl, cycloalkyl, alkenyl, acyl, phenyl, benzyl or benzoyl, where the phenyl ring is substituted or unsubstituted, R.sup.4 being hydrogen, fluorine, chlorine, bromine or iodine, R.sup.5 being hydrogen, alkyl, haloalkyl, cycloalkyl, alkenyl, phenyl or benzyl, the phenyl ring being substituted or unsubstituted,Ar is a substituted or unsubstituted aryl radical,their N-oxides and plant-tolerated acid addition salts, and fungicides containing these compounds.

Abstract translation: 其中A为CR 1 R 2，R 1和R 2彼此独立地为氢，烷基，烯基或炔基，或者R 1和R 2一起形成亚甲基链，B为基团CH 2，CHOR 3之一 CH 2 R 4，C = O或C = NO-R 5，R 3为氢，烷基，卤代烷基，环烷基，烯基，酰基，苯基，苄基或苯甲酰基，其中苯环为取代或未取代的，R4为氢，氟，氯， 溴或碘，R 5为氢，烷基，卤代烷基，环烷基，烯基，苯基或苄基，苯环为取代或未取代的，Ar为取代或未取代的芳基，其N-氧化物和植物耐受酸加成盐， 含有这些化合物的杀真菌剂。

公开(公告)号：US5147645A

公开(公告)日：1992-09-15

申请号：US590690

申请日：1990-10-01

Applicant: Bernd Wolf ,  Hans Theobald ,  Winfried Zombik ,  Norbert Goetz ,  Jochen Wild ,  Albrecht Harreus ,  Peter Hofmeister ,  Christoph Kuenast ,  Jacobus J. DeKramer

Inventor： Bernd Wolf ,  Hans Theobald ,  Winfried Zombik ,  Norbert Goetz ,  Jochen Wild ,  Albrecht Harreus ,  Peter Hofmeister ,  Christoph Kuenast ,  Jacobus J. DeKramer

IPC: C07D207/325 ,  A01N43/36 ,  A01N53/00 ,  A01N53/06 ,  C07C33/20 ,  C07C33/30 ,  C07C33/46 ,  C07C33/50 ,  C07C69/007 ,  C07C69/65 ,  C07C69/734 ,  C07C69/743 ,  C07C69/747 ,  C07C229/18 ,  C07C255/36 ,  C07C255/41 ,  C07D207/32 ,  C07D207/337

CPC classification number: C07D207/337 ,  A01N43/36 ,  A01N53/00 ,  C07C255/36 ,  C07C33/20 ,  C07C33/30

Abstract: Benzyl esters of the formula I ##STR1## where R.sup.1 is methyl, ethyl, halogen, methoxy or ethoxy, R.sup.2 is alkyl, alkenyl, cycloalkyl, cycloalkenyl, bicycloalkyl, bicycloalkenyl, C.sub.1 -C.sub.5 -alkyl-substituted cycloalkyl, C.sub.1 -C.sub.5 -substituted cycloalkenyl, C.sub.1 -C.sub.5 -alkyl-substituted bicycloalkyl or C.sub.1 -C.sub.5 -alkyl-substituted bicycloalkenyl, R.sup.3 is hydrogen, cyano, C.sub.2 -C.sub.4 -alkynyl, C.sub.2 -C.sub.4 -alkenyl or C.sub.1 -C.sub.4 -alkyl, A is the carboxylate radical of an acid component typical for pyrethroids and X is hydrogen or halogen, with the proviso that R.sup.2 is not CH.sub.2 --CH.dbd.CH--B when B is hydrogen, alkyl or alkenyl and at the same time R.sup.1 is methyl or halogen, and furthermore with the proviso that R.sup.2 is not methyl when R.sup.1 is methyl, their manufacture, their use for combating pests, and precursors for manufacturing the benzyl esters.

Abstract translation: 式I的苄酯（I）其中R1是甲基，乙基，卤素，甲氧基或乙氧基，R2是烷基，烯基，环烷基，环烯基，双环烷基，双环烯基，C1-C5-烷基取代的环烷基，C1- C 5 - 取代的环烯基，C 1 -C 5 - 烷基取代的双环烷基或C 1 -C 5 - 烷基取代的双环烯基，R 3是氢，氰基，C 2 -C 4 - 炔基，C 2 -C 4 - 烯基或C 1 -C 4烷基，A是 典型的拟除虫菊酯的酸成分的羧酸酯基，X是氢或卤素，条件是当B是氢，烷基或烯基时，R2不是CH2-CH = CH-B，同时R1是甲基或卤素，以及 此外，条件是当R1是甲基时，R2不是甲基，它们的制备，它们用于防治害虫的用途和用于制备苄基酯的前体。

公开(公告)号：US5130435A

公开(公告)日：1992-07-14

申请号：US565180

申请日：1990-08-09

Applicant: Wolfgang Hoelderich ,  Norbert Goetz ,  Leopold Hupfer

Inventor： Wolfgang Hoelderich ,  Norbert Goetz ,  Leopold Hupfer

IPC: C07C41/28

CPC classification number: C07C41/28 ,  Y02P20/582

Abstract: Vinyl ethers of the formula ##STR1## wherein R.sup.1, R.sup.2 and R.sup.3 are identical to or different from one another, each being hydrogen, straight-chain or branched alkyl or alkenyl of up to 12 carbon atoms, cycloalkyl or cycloalkylene of from 5 to 8 carbon atoms, aryl, alkylaryl, alkenylaryl, aralkyl and aralkenyl of from 6 to 16 carbon atoms, halogen-substituted aryl or heterocyclyl, and in addition the radicals R.sup.1 and R.sup.2 or R.sup.1 and R.sup.3, together with the carbon atom to which they are bonded, can form a cycloalkane, cycloalkene or a heterocycle, and R.sup.4 is alkyl, alkylaryl or aralkyl, are prepared by eliminating an alcohol from an acetal/ketal of the formula ##STR2## where R.sup.1, R.sup.2, R.sup.3 and R.sup.4 are each as defined above, in the presence of a phosphate of zeolite structure and/or a precipitated phosphate of the elements B, Zr, Ce or Fe and/or phosphoric acid or boric acid on carrier material and/or acidic undoped metal oxide as catalyst, the reaction being preferably carried out in the gas phase.

Abstract translation: 式中，R 1，R 2和R 3彼此相同或不同的乙烯基醚，各自为氢，直至12个碳原子的直链或支链烷基或烯基，5至8的环烷基或亚环烷基 碳原子，芳基，烷基芳基，烯基芳基，芳烷基和具有6至16个碳原子的芳烯基，卤素取代的芳基或杂环基，此外基团R 1和R 2或R 1和R 3与它们所键合的碳原子一起 可以形成环烷烃，环烯烃或杂环，并且R 4是烷基，烷基芳基或芳烷基，通过从式（I）的缩醛/缩酮中除去醇来制备，其中R 1，R 2，R 3和R 4各自如上所定义 在载体材料和/或酸性未掺杂的金属氧化物作为催化剂的沸石结构的磷酸盐和/或元素B，Zr，Ce或Fe和/或磷酸或硼酸的沉淀磷酸盐存在下，反应为 优选在气相中进行。

公开(公告)号：US5101061A

公开(公告)日：1992-03-31

申请号：US520459

申请日：1990-05-08

Applicant: Bernd Wolf ,  Hans Theobald ,  Norbert Goetz

Inventor： Bernd Wolf ,  Hans Theobald ,  Norbert Goetz

IPC: C07C29/136 ,  C07C25/02 ,  C07C25/18 ,  C07C25/22 ,  C07C25/24 ,  C07C27/00 ,  C07C29/16 ,  C07C33/20 ,  C07C33/22 ,  C07C33/30 ,  C07C33/34 ,  C07C33/46 ,  C07C33/50 ,  C07C35/21 ,  C07C35/50 ,  C07C45/00 ,  C07C45/44 ,  C07C47/542 ,  C07C47/546 ,  C07C47/548 ,  C07C47/55 ,  C07C67/00 ,  C07C255/50

CPC classification number: C07C33/34 ,  C07C25/02 ,  C07C25/18 ,  C07C25/22 ,  C07C25/24 ,  C07C255/50 ,  C07C33/20 ,  C07C33/30 ,  C07C33/46 ,  C07C33/50 ,  C07C45/44 ,  C07C47/542 ,  C07C47/546 ,  C07C47/548 ,  C07C47/55 ,  C07C2101/02 ,  C07C2101/08 ,  C07C2101/10 ,  C07C2101/14 ,  C07C2101/16 ,  C07C2101/18 ,  C07C2102/42

Abstract: Novel benzonitriles, benzaldehydes and benzyl alcohols of the formula I ##STR1## where R.sup.1 is methyl or ethyl, R.sup.2 is alkyl, alkenyl, cycloalkyl, cycloalkenyl, bicycloalkyl, bicycloalkenyl, or C.sub.1 -C.sub.5 -alkyl-substituted cycloalkyl, cycloalkenyl, bicycloalkyl or bicycloalkenyl, X is hydrogen, chlorine or fluorine and Z is --CN, CHO or ##STR2## where R.sup.3 is hydrogen, cyano, C.sub.2 -C.sub.4 -alkynyl, C.sub.2 -C.sub.4 -alkenyl or C.sub.1 -C.sub.4 -alkyl, with the proviso that R.sup.2 is not --CH.sub.2 -CH.dbd.CH--B when B is hydrogen, alkyl or alkenyl and at the same time R.sup.1 is methyl and Z is ##STR3## and with the proviso that R.sup.2 is not methyl or ethyl when R.sup.1 is methyl and at the same time Z is ##STR4## and further more with the proviso that R.sup.2 is not methyl when R.sup.1 is methyl or ethyl and at the same time Z is --CN or --CHO.

公开(公告)号：US5085686A

公开(公告)日：1992-02-04

申请号：US537129

申请日：1990-06-13

Applicant: Uwe J. Vogelbacher ,  Karl Eicken ,  Joachim Rheinheimer ,  Norbert Goetz ,  Albrecht Harreus ,  Gerhard Paul ,  Karl-Otto Westphalen ,  Bruno Wuerzer

Inventor： Uwe J. Vogelbacher ,  Karl Eicken ,  Joachim Rheinheimer ,  Norbert Goetz ,  Albrecht Harreus ,  Gerhard Paul ,  Karl-Otto Westphalen ,  Bruno Wuerzer

IPC: C07D249/08 ,  A01N43/54 ,  A01N43/56 ,  A01N43/653 ,  A01N43/66 ,  C07D213/55 ,  C07D213/61 ,  C07D215/14 ,  C07D215/18 ,  C07D231/12 ,  C07D231/16 ,  C07D239/52 ,  C07D239/60 ,  C07D249/04 ,  C07D249/06 ,  C07D251/16 ,  C07D251/30 ,  C07D261/08 ,  C07D261/10 ,  C07D263/32 ,  C07D277/20 ,  C07D277/30 ,  C07D277/62 ,  C07D285/12 ,  C07D333/22 ,  C07D401/12 ,  C07D403/12 ,  C07D409/12 ,  C07D413/12 ,  C07D417/12 ,  C07D521/00

CPC classification number: C07D401/12 ,  A01N43/54 ,  A01N43/56 ,  A01N43/653 ,  A01N43/66 ,  C07D239/52 ,  C07D239/60 ,  C07D251/16 ,  C07D251/30 ,  C07D403/12 ,  C07D409/12 ,  C07D413/12 ,  C07D417/12

Abstract: Salicylaldehyde derivatives and salicyclic acid derivatives of the formula I ##STR1## where A is an unsubstituted or substituted phenyl radical, an unsubstituted or substituted 5-membered heteroaromatic radical having from 2 to 4 nitrogen atoms or two nitrogen atoms and additionally one sulfur or oxygen atom or an unsubstituted or substituted thienyl, pyridyl, naphthyl, quinolyl, indazolyl or benzotriazolyl radical, X is oxygen or sulfur, and the radicals R.sup.1 and R.sup.4 have the means given in the specification, processes and intermediates for their production, and their use as herbicides and bioregulators.

Abstract translation: 式I的水杨醛衍生物和水杨酸衍生物其中A是未取代或取代的苯基，未取代或取代的具有2至4个氮原子或2个氮原子的5元杂芳族基团，另外一个硫或氧 原子或未取代或取代的噻吩基，吡啶基，萘基，喹啉基，吲唑基或苯并三唑基，X是氧或硫，并且基团R1和R4具有在其说明书，方法和中间体中给出的用于其生产的方法，并且它们用作 除草剂和生物调节剂。

公开(公告)号：US5079367A

公开(公告)日：1992-01-07

申请号：US442725

申请日：1989-11-29

Applicant: Wolfgang Hoelderich ,  Norbert Goetz ,  Gerd Fouquet

Inventor： Wolfgang Hoelderich ,  Norbert Goetz ,  Gerd Fouquet

IPC: B01J29/035 ,  B01J29/40 ,  B01J29/85 ,  B01J29/86 ,  B01J29/87 ,  B01J29/88 ,  B01J29/89 ,  C07B61/00 ,  C07D213/12

CPC classification number: C07D213/12

Abstract: Substituted pyridines of the formula ##STR1## where R.sup.1 is alkyl of 1 to 20 carbon atoms, cycloalkyl, aryl or aralkyl, are prepared by reacting a mixture of acrolein and alkanals of the formula ##STR2## with ammonia in the presence of zeolites as catalysts.

Abstract translation: 其中R 1是1至20个碳原子的烷基，环烷基，芳基或芳烷基的取代的吡啶类是通过在沸石作为催化剂存在下使式ⅩⅧ的丙烯醛和链烷的混合物与氨反应来制备的 。

公开(公告)号：US5032616A

公开(公告)日：1991-07-16

申请号：US90761

申请日：1987-08-28

Applicant: Hubert Sauter ,  Matthias Zipplies ,  Norbert Goetz ,  Eberhard Ammermann ,  Ernst-Heinrich Pommer

Inventor： Hubert Sauter ,  Matthias Zipplies ,  Norbert Goetz ,  Eberhard Ammermann ,  Ernst-Heinrich Pommer

IPC: A01N33/04 ,  A01N33/08 ,  A01N33/10 ,  A01N39/00 ,  A01N45/02 ,  A01N49/00 ,  C07C67/00 ,  C07C209/00 ,  C07C211/35 ,  C07C211/40 ,  C07C213/00 ,  C07C215/02 ,  C07C215/20 ,  C07C215/26 ,  C07C215/42 ,  C07C217/00 ,  C07C217/52 ,  C07C313/00 ,  C07C323/26 ,  C07C323/28 ,  C07C323/36

CPC classification number: A01N49/00 ,  A01N33/04 ,  A01N33/08 ,  A01N33/10 ,  A01N39/00 ,  A01N45/02 ,  Y10T428/31649 ,  Y10T428/31652 ,  Y10T428/31678

Abstract: 4-trans-substituted cyclohexylamine derivatives of the formula ##STR1## where R.sup.1 is the group CR.sup.5 R.sup.6 R.sup.7, in which R.sup.5, R.sup.6 and R.sup.7 are hydrogen, unsubstituted or substituted alkyl, alkoxy, alkylthio or cycloalkyl, with the proviso that not more than one of the substituents R.sup.5, R.sup.6 and R.sup.7 may by hydrogen, or in which R.sup.6 and R.sup.7 together with the included carbon atom form a three-membered to six-membered carbocyclic aliphatic ring,R.sup.2 and R.sup.3 are hydrogen, alkyl, alkenyl or alkynyl or cycloalkyl or cycloalkenyl, which in turn may be substituted, with the proviso that the sum of the carbon atoms and hetero atoms (O, S and halogen) of R.sup.2 and R.sup.3 together is not less than 8,R.sup.4 is hydrogen, alkyl, cycloalkyl or alkoxy, and m is 1 to 4, and the bond is a single or a double bond,salts thereof, and their use as fungicides.

Abstract translation: 其中R1是基团CR5R6R7，其中R5，R6和R7是氢，未取代或取代的烷基，烷氧基，烷硫基或环烷基，其条件是不超过一个 取代基R 5，R 6和R 7可以是氢，或者其中R 6和R 7与所包括的碳原子一起形成三元至六元碳环脂族环，R 2和R 3是氢，烷基，烯基或炔基或环烷基或 环烯基，其又可以被取代，条件是R 2和R 3的碳原子和杂原子（O，S和卤素）之和不小于8，R4是氢，烷基，环烷基或烷氧基， m为1〜4，键为单键或双键，其盐及其作为杀真菌剂的用途。

公开(公告)号：US5017594A

公开(公告)日：1991-05-21

申请号：US376429

申请日：1989-07-07

Applicant: Rainer Seele ,  Reiner Kober ,  Norbert Goetz ,  Eberhard Ammermann ,  Gisela Lorenz

Inventor： Rainer Seele ,  Reiner Kober ,  Norbert Goetz ,  Eberhard Ammermann ,  Gisela Lorenz

IPC: A01N43/50 ,  A01N43/653 ,  C07D233/56 ,  C07D233/58 ,  C07D233/60 ,  C07D233/61 ,  C07D249/08 ,  C07D405/06 ,  C07D405/14 ,  C07D521/00

CPC classification number: C07D231/12 ,  A01N43/50 ,  A01N43/653 ,  C07D233/56 ,  C07D249/08

Abstract: 1-Halo-1-azolylpropenes and -methyloxiranes of the formula I ##STR1## where R.sup.1 and R.sup.2 are alkyl, cycloalkyl, cycloalkenyl, tetrahydropyranyl, norbornyl, pyridyl, naphthyl, biphenyl or phenyl, A is oxygen or a single bond, R.sup.3 is F, Cl or Br, X is CH or N, their plant-tolerated acid addition salts and metal complexes, and fungicides containing these compounds.

Abstract translation: 其中R 1和R 2为烷基，环烷基，环烯基，四氢吡喃基，降冰片基，吡啶基，萘基，联苯基或苯基，A为氧或单键，R3为卤素， 是F，Cl或Br，X是CH或N，它们的植物耐受的酸加成盐和金属络合物，以及含有这些化合物的杀真菌剂。

公开(公告)号：US4891451A

公开(公告)日：1990-01-02

申请号：US213589

申请日：1988-06-30

Applicant: Wolfgang Hoelderich ,  Norbert Goetz ,  Leopold Hupfer

Inventor： Wolfgang Hoelderich ,  Norbert Goetz ,  Leopold Hupfer

IPC: C07C41/28

CPC classification number: C07C41/28 ,  C07C2101/14 ,  Y02P20/582

Abstract: Vinyl ethers of the formula (I) ##STR1## where R.sup.1 to R.sup.3 are identical or different and are each hydrogen, a straight-chain or branched alkyl or alkenyl radical of not more than 12 carbon atoms, halogen-substituted alkyl, a cycloalkyl or cycloalkenyl radical of 5 to 8 carbon atoms, an aryl, alkylaryl, alkenylaryl, aralkyl or aralkenyl radical of 6 to 16 carbon atoms, halogen-substituted aryl or a heterocyclic radical and furthermore R.sup.1 and R.sup.2 or R.sup.1 and R.sup.3, together with the carbon atom to which they are bonded, may form a cycloalkane, cycloalkene or heterocyclic structure, and R.sup.4 is alkyl, alkylaryl or aralkyl, are prepared by a process in which an alcohol is eliminated from an acetal or ketal of the formula (II) ##STR2## where R.sup.1 to R.sup.4 have the above meanings, in the presence of borosilicate and/or iron silicate zeolites as catalysts.

Abstract translation: 式（I）的乙烯基醚其中R 1至R 3相同或不同并且各自为氢，不超过12个碳原子的直链或支链烷基或烯基，卤素取代的烷基， 5至8个碳原子的环烷基或环烯基，6至16个碳原子的芳基，烷基芳基，烯基芳基，芳烷基或芳烯基，卤素取代的芳基或杂环基，此外R1和R2或R1和R3连同 其键合的碳原子可以通过其中从式（II）的缩醛或缩酮中除去醇的方法制备环烷烃，环烯烃或杂环结构，并且R 4是烷基，烷基芳基或芳烷基， 在有硼硅酸盐和/或铁硅酸盐沸石作为催化剂的情况下，R1至R4具有上述含义的图像（II）。

公开(公告)号：US4812593A

公开(公告)日：1989-03-14

申请号：US82127

申请日：1987-08-06

Applicant: Wolfgang Hoelderich ,  Norbert Goetz ,  Leopold Hupfer

Inventor： Wolfgang Hoelderich ,  Norbert Goetz ,  Leopold Hupfer

IPC: C07C45/51 ,  C07C45/67 ,  C07C45/71 ,  C07C47/198 ,  C07C47/277 ,  C07C49/175 ,  C07C49/255 ,  C07C67/327 ,  C07C69/708 ,  C07C69/734 ,  C07C69/73

CPC classification number: C07C45/71 ,  C07C45/515 ,  C07C45/673 ,  C07C47/198 ,  C07C47/277 ,  C07C49/175 ,  C07C49/255 ,  C07C67/327

Abstract: Bifunctional compounds of the formula ##STR1## where R.sup.1, R.sup.2 and R.sup.3 are each alkyl of 1 to 6 carbon atoms, R.sup.2 and R.sup.3 may furthermore be hydrogen, R.sup.2 is furthermore alkoxy and R.sup.4 is hydrogen, alkyl of 1 to 6 carbon atoms or alkoxy, and a double bond may be present between carbon atoms 2 and 3, are prepared by converting a tetraalkoxyalkane or a dialkoxyalkanoate of the formulae ##STR2## where R.sup.1, R.sup.2, R.sup.3 and R.sup.4 have the above meanings, in the presence of a catalyst, such as a zeolite, in particular one of the pentasil type, and/or a phosphate and/or phosphoric acid on a carrier.

Abstract translation: 其中R 1，R 2和R 3各自为1至6个碳原子的烷基，R 2和R 3可以另外为氢，R 2为烷氧基，且R 4为氢，具有1-6个碳原子的烷基或烷氧基 ，并且碳原子2和3之间可以存在双键，通过在催化剂存在下，将式Ia，R2，R3和R4具有上述含义的四烷氧基烷烃或二烷氧基烷酸酯进行转化来制备， 例如沸石，特别是pentasil类中的一种，和/或载体上的磷酸盐和/或磷酸。