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31.发明申请METHOD FOR PRODUCING BIO-FUEL THAT INTEGRATES HEAT FROM CARBON-CARBON BOND-FORMING REACTIONS TO DRIVE BIOMASS GASIFICATION REACTIONS 有权生物燃料的生物燃料的方法，其将碳 - 碳键合反应加热到驱动生物质气化反应公开(公告)号：US20120165416A1
公开(公告)日：2012-06-28
申请号：US13410330
申请日：2012-03-02
Applicant: Randy D. Cortright , James A. Dumesic
Inventor： Randy D. Cortright , James A. Dumesic
CPC classification number: C10G2/332 , C01B3/326 , C01B2203/0233 , C01B2203/0283 , C01B2203/06 , C01B2203/061 , C01B2203/062 , C01B2203/0811 , C01B2203/0838 , C01B2203/0866 , C01B2203/1047 , C01B2203/1052 , C01B2203/1064 , C01B2203/107 , C01B2203/1217 , C10G2/32 , C10G2/333 , C10G2300/1011 , Y02E50/13 , Y02E50/32 , Y02P20/52 , Y02P30/20
Abstract: A low-temperature catalytic process for converting biomass (preferably glycerol recovered from the fabrication of bio-diesel) to synthesis gas (i.e., H2/CO gas mixture) in an endothermic gasification reaction is described. The synthesis gas is used in exothermic carbon-carbon bond-forming reactions, such as Fischer-Tropsch, methanol, or dimethylether syntheses. The heat from the exothermic carbon-carbon bond-forming reaction is integrated with the endothermic gasification reaction, thus providing an energy-efficient route for producing fuels and chemicals from renewable biomass resources.
Abstract translation: 描述了在吸热气化反应中将生物质（优选从制备生物柴油回收的甘油）转化为合成气（即H 2 / CO气体混合物）的低温催化方法。 合成气用于放热碳 - 碳键形成反应，如费托，甲醇或二甲醚合成。 来自放热碳 - 碳键形成反应的热量与吸热气化反应相结合，从而为从可再生生物质资源生产燃料和化学物质提供了节能途径。
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公开(公告)号：US08053615B2
公开(公告)日：2011-11-08
申请号：US12044837
申请日：2008-03-07
Applicant: Randy D. Cortright , Paul G. Blommel
Inventor： Randy D. Cortright , Paul G. Blommel
CPC classification number: C10L1/06 , C07C1/20 , C07C2/86 , C07C29/60 , C07C45/57 , C07D307/08 , C10G3/44 , C10G3/45 , C10G3/46 , C10G3/47 , C10G3/49 , C10G3/50 , C10G3/52 , C10G2300/1011 , C10G2300/1014 , C10G2300/4006 , C10G2300/4012 , C10G2300/42 , C10G2300/807 , C10G2400/22 , C10G2400/30 , C10L1/1824 , C10L1/1857 , C10L2200/0423 , C10L2200/0469 , C10L2270/023 , C10L2290/543 , Y02P30/20
Abstract: Processes and reactor systems are provided for the conversion of oxygenated hydrocarbons to hydrocarbons, ketones and alcohols useful as liquid fuels, such as gasoline, jet fuel or diesel fuel, and industrial chemicals. The process involves the conversion of mono-oxygenated hydrocarbons, such as alcohols, ketones, aldehydes, furans, carboxylic acids, diols, triols, and/or other polyols, to C4+ hydrocarbons, alcohols and/or ketones, by condensation. The oxygenated hydrocarbons may originate from any source, but are preferably derived from biomass.
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公开(公告)号：US20110257416A1
公开(公告)日：2011-10-20
申请号：US13171715
申请日：2011-06-29
Applicant: Randy D. Cortright , Paul G. Blommel
Inventor： Randy D. Cortright , Paul G. Blommel
IPC: C07D309/04 , C10G1/00 , C07D307/06 , C07D307/08
CPC classification number: C10L1/06 , C07C1/20 , C07C2/86 , C07C29/60 , C07C45/57 , C07D307/08 , C10G3/44 , C10G3/45 , C10G3/46 , C10G3/47 , C10G3/49 , C10G3/50 , C10G3/52 , C10G2300/1011 , C10G2300/1014 , C10G2300/4006 , C10G2300/4012 , C10G2300/42 , C10G2300/807 , C10G2400/22 , C10G2400/30 , C10L1/1824 , C10L1/1857 , C10L2200/0423 , C10L2200/0469 , C10L2270/023 , C10L2290/543 , Y02P30/20
Abstract: Processes and reactor systems are provided for the conversion of oxygenated hydrocarbons to hydrocarbons, ketones, cyclic ethers and alcohols useful as liquid fuels, such as gasoline, jet fuel or diesel fuel, and industrial chemicals. The process involves the conversion of oxygenated hydrocarbons, such as alcohols, ketones, aldehydes, furans, carboxylic acids, diols, triols, and/or other polyols, to C4− hydrocarbons, cyclic ethers, alcohols and/or ketones, by condensation and/or deoxygenation. The oxygenated hydrocarbons may originate from any source, but are preferably derived from biomass.
Abstract translation: 提供的方法和反应器系统用于将含氧烃转化为可用作液体燃料的烃，酮，环醚和醇，例如汽油，喷气燃料或柴油，以及工业化学品。 该方法涉及通过冷凝和/或其它途径将含氧烃如醇，酮，醛，呋喃，羧酸，二醇，三醇和/或其它多元醇转化成C 4烃，环醚，醇和/或酮， 或脱氧。 氧化烃可以源于任何来源，但优选来自生物质。
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公开(公告)号：US20100288975A1
公开(公告)日：2010-11-18
申请号：US11961280
申请日：2007-12-20
Applicant: Randy D. Cortright , Robert T. Rozmiarek , Charles C. Hornemann
Inventor： Randy D. Cortright , Robert T. Rozmiarek , Charles C. Hornemann
CPC classification number: B01J8/025 , B01J8/065 , B01J8/067 , B01J2208/00212 , B01J2208/00221 , B01J2208/00504 , B01J2208/0053 , B01J2208/00539 , B01J2208/00672 , B01J2208/025 , C01B3/323 , C01B2203/0233 , C01B2203/066 , C01B2203/0805 , C01B2203/0833 , C01B2203/1041 , C01B2203/1058 , C01B2203/1064 , C01B2203/107 , C01B2203/1211 , C01B2203/84 , Y02E60/324 , Y02P20/52 , Y02P30/20
Abstract: Reactor systems are provided for the catalytic conversion of liquid feedstocks to synthesis gases and other noncondensable gaseous products. The reactor systems include a heat exchange reactor configured to allow the liquid feedstock and gas product to flow concurrently in a downflow direction. The reactor systems are particularly useful for producing hydrogen and light hydrocarbons from biomass-derived oxygenated hydrocarbons using aqueous phase reforming. The generated gases may find used as a fuel source for energy generation via PEM fuel cells, solid-oxide fuel cells, internal combustion engines, or gas turbine gensets, or used in other chemical processes to produce additional products. The gaseous products may also be collected for later use or distribution.
Abstract translation: 提供反应器系统用于将液体原料催化转化成合成气体和其它不可冷凝气态产物。 反应器系统包括热交换反应器，其构造成允许液体原料和气体产物沿下流方向同时流动。 反应器系统特别适用于使用水相重整从生物质衍生的含氧烃生产氢和轻烃。 产生的气体可能被用作通过PEM燃料电池，固体氧化物燃料电池，内燃机或燃气轮机发电机组产生能量的燃料源，或用于其他化学过程以产生额外的产品。 也可以收集气体产物用于以后的使用或分配。
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公开(公告)号：US5736478A
公开(公告)日：1998-04-07
申请号：US724944
申请日：1996-10-02
Applicant: Randy D. Cortright , James A. Dumesic
Inventor： Randy D. Cortright , James A. Dumesic
Abstract: A new catalyst for the selective conversion of isobutane to isobutylene. This catalyst also could be applied to the selective dehydrogenation of other light paraffins such as propane and n-butane. The catalyst is comprised of platinum, tin, and potassium supported on K--L-zeolite. This catalyst exhibits greater than 98% selectivity for conversion of isobutane to isobutylene at isobutane conversion levels greater than 50%. In addition, this catalyst exhibits excellent stability. The preferred catalyst would have an atomic ratio of Sn to Pt greater than 1.0 as well as an atomic ratio of K to Pt greater than 1.0.
Abstract translation: 用于将异丁烷选择性转化为异丁烯的新型催化剂。 该催化剂也可用于其它轻链烷烃如丙烷和正丁烷的选择性脱氢。 催化剂由负载在K-L-沸石上的铂，锡和钾组成。 在异丁烷转化率大于50％时，该催化剂显示出大于98％的异丁烷转化为异丁烯的选择性。 此外，该催化剂表现出优异的稳定性。 优选的催化剂的Sn与Pt的原子比大于1.0，K与Pt的原子比大于1.0。
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Patent Agency Ranking
公开(公告)号：US08642813B2
公开(公告)日：2014-02-04
申请号：US13339994
申请日：2011-12-29
Applicant: Ming Qiao , Randy D. Cortright , John Kania , Elizabeth Woods
Inventor： Ming Qiao , Randy D. Cortright , John Kania , Elizabeth Woods
IPC: C07C321/00 , C07C27/00 , C07C35/08 , B01J21/20 , C01B15/024
CPC classification number: C13K1/02 , B01J20/34 , B01J23/462 , B01J23/464 , B01J23/52 , B01J23/6527 , B01J23/687 , C07B63/00 , C07C29/132 , C08B30/12 , C10G1/06 , C10G1/065 , C10G3/42 , C10G3/47 , C10G2300/1011 , C10G2300/1014 , C10G2300/44 , C10G2300/805 , C10G2400/30 , C13K13/00 , Y02P30/20 , Y02P30/42
Abstract: The present invention provides methods, reactor systems, and catalysts for converting in a continuous process biomass to less complex oxygenated compounds for use in downstream processes to produce biofuels and chemicals. The invention includes methods of converting the components of biomass, such as hemicellulose, cellulose and lignin, to water-soluble materials, including lignocellulosic derivatives, cellulosic derivatives, hemicellulosic derivatives, carbohydrates, starches, polysaccharides, disaccharides, monosaccharides, sugars, sugar alcohols, alditols, polyols, diols, alcohols, ketones, cyclic ethers, esters, carboxylic acids, aldehydes, and mixtures thereof, using hydrogen and a heterogeneous liquefaction catalyst.
Abstract translation: 本发明提供了用于将连续过程生物质转化为较不复杂的含氧化合物的方法，反应器系统和催化剂，以用于生产生物燃料和化学品的下游工艺。 本发明包括将生物质组分如半纤维素，纤维素和木质素转化成水溶性材料的方法，包括木质纤维素衍生物，纤维素衍生物，半纤维素衍生物，碳水化合物，淀粉，多糖，二糖，单糖，糖，糖醇， 醇，多元醇，二醇，醇，酮，环醚，酯，羧酸，醛及其混合物，使用氢气和非均相液化催化剂。
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公开(公告)号：US20120283478A1
公开(公告)日：2012-11-08
申请号：US13491749
申请日：2012-06-08
Applicant: Randy D. Cortright
Inventor： Randy D. Cortright
IPC: C07C27/04
CPC classification number: C07C27/06 , B01J23/8906 , C01B3/323 , C01B2203/0233 , C01B2203/06 , C01B2203/1047 , C01B2203/1052 , C01B2203/1058 , C01B2203/1064 , C01B2203/107 , C01B2203/1076 , C01B2203/1211 , C01B2203/1217 , C07C29/60 , Y02P20/52 , C07C31/205
Abstract: Disclosed are methods for generating propylene glycol, ethylene glycol and other polyols, diols, ketones, aldehydes, carboxylic acids and alcohols from biomass using hydrogen produced from the biomass. The methods involve reacting a portion of an aqueous stream of a biomass feedstock solution over a catalyst under aqueous phase reforming conditions to produce hydrogen, and then reacting the hydrogen and the aqueous feedstock solution over a catalyst to produce propylene glycol, ethylene glycol and the other polyols, diols, ketones, aldehydes, carboxylic acids and alcohols. The disclosed methods can be run at lower temperatures and pressures, and allows for the production of oxygenated hydrocarbons without the need for hydrogen from an external source.
Abstract translation: 公开了从生物质产生的氢从生物质产生丙二醇，乙二醇和其它多元醇，二醇，酮，醛，羧酸和醇的方法。 所述方法包括在水相重整条件下使生物质原料溶液的一部分水流在催化剂上反应以产生氢，然后使氢和原料水溶液在催化剂上反应以产生丙二醇，乙二醇和其它 多元醇，二醇，酮，醛，羧酸和醇。 所公开的方法可以在较低的温度和压力下运行，并允许生产含氧烃，而不需要来自外部来源的氢。
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公开(公告)号：US20110245542A1
公开(公告)日：2011-10-06
申请号：US13163412
申请日：2011-06-17
Applicant: Randy D. Cortright , Paul G. Blommel
Inventor： Randy D. Cortright , Paul G. Blommel
CPC classification number: C10L1/06 , C07C1/20 , C07C2/86 , C07C29/60 , C07C45/57 , C07D307/08 , C10G3/44 , C10G3/45 , C10G3/46 , C10G3/47 , C10G3/49 , C10G3/50 , C10G3/52 , C10G2300/1011 , C10G2300/1014 , C10G2300/4006 , C10G2300/4012 , C10G2300/42 , C10G2300/807 , C10G2400/22 , C10G2400/30 , C10L1/1824 , C10L1/1857 , C10L2200/0423 , C10L2200/0469 , C10L2270/023 , C10L2290/543 , Y02P30/20
Abstract: Processes and reactor systems are provided for the conversion of oxygenated hydrocarbons to hydrocarbons, ketones and alcohols useful as liquid fuels, such as gasoline, jet fuel or diesel fuel, and industrial chemicals. The process involves the conversion of mono-oxygenated hydrocarbons, such as alcohols, ketones, aldehydes, furans, carboxylic acids, diols, triols, and/or other polyols, to C4+ hydrocarbons, alcohols and/or ketones, by condensation. The oxygenated hydrocarbons may originate from any source, but are preferably derived from biomass.
Abstract translation: 提供的方法和反应器系统用于将含氧烃转化为可用作液体燃料的烃，酮和醇，例如汽油，喷气燃料或柴油，以及工业化学品。 该方法包括通过缩合将单氧化烃如醇，酮，醛，呋喃，羧酸，二醇，三醇和/或其它多元醇转化成C4 +烃，醇和/或酮。 氧化烃可以源于任何来源，但优选来自生物质。
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39.发明申请公开(公告)号：US20110009614A1
公开(公告)日：2011-01-13
申请号：US12827827
申请日：2010-06-30
Applicant: Paul George Blommel , Elizabeth M. Woods , Michael J. Werner , Aaron James Imrie , Randy D. Cortright
Inventor： Paul George Blommel , Elizabeth M. Woods , Michael J. Werner , Aaron James Imrie , Randy D. Cortright
CPC classification number: B01J38/10 , C07C29/132 , Y02P20/584 , C07C31/26
Abstract: Processes and reactor systems are provided for the conversion of sugars to sugar alcohols using a hydrogenation catalyst, which includes apparatus and method for in-line regeneration of the hydrogenation catalyst to remove carbonaceous deposits.
Abstract translation: 提供了使用氢化催化剂将糖转化为糖醇的方法和反应器系统，其包括用于氢化催化剂的在线再生以除去碳质沉积物的装置和方法。
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公开(公告)号：US20100280275A1
公开(公告)日：2010-11-04
申请号：US12834306
申请日：2010-07-12
Applicant: Randy D. Cortright
Inventor： Randy D. Cortright
CPC classification number: C07C27/06 , B01J23/8906 , C01B3/323 , C01B2203/0233 , C01B2203/06 , C01B2203/1047 , C01B2203/1052 , C01B2203/1058 , C01B2203/1064 , C01B2203/107 , C01B2203/1076 , C01B2203/1211 , C01B2203/1217 , C07C29/60 , Y02P20/52 , C07C31/205
Abstract: Disclosed are methods for generating propylene glycol, ethylene glycol and other polyols, diols, ketones, aldehydes, carboxylic acids and alcohols from biomass using hydrogen produced from the biomass. The methods involve reacting a portion of an aqueous stream of a biomass feedstock solution over a catalyst under aqueous phase reforming conditions to produce hydrogen, and then reacting the hydrogen and the aqueous feedstock solution over a catalyst to produce propylene glycol, ethylene glycal and the other polyols, diols, ketones, aldehydes, carboxylic acids and alcohols. The disclosed methods can be run at lower temperatures and pressures, and allows for the production of oxygenated hydrocarbons without the need for hydrogen from an external source.
Abstract translation: 公开了从生物质产生的氢从生物质产生丙二醇，乙二醇和其它多元醇，二醇，酮，醛，羧酸和醇的方法。 所述方法包括在水相重整条件下使生物质原料溶液的一部分水流在催化剂上反应以产生氢，然后使氢和原料水溶液在催化剂上反应以产生丙二醇，乙二醇和其它 多元醇，二醇，酮，醛，羧酸和醇。 所公开的方法可以在较低的温度和压力下运行，并允许生产含氧烃，而不需要来自外部来源的氢。
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