公开(公告)号：US09540465B2

公开(公告)日：2017-01-10

申请号：US14255076

申请日：2014-04-17

Applicant: Chevron Phillips Chemical Company LP

Inventor： Jeffrey F. Greco ,  Qing Yang ,  Tony R. Crain

IPC: C08F110/02 ,  C08F4/6592 ,  C08F210/16 ,  C08F10/02 ,  C08L23/08 ,  B01J31/22 ,  C08F4/659

CPC classification number: C08F110/02 ,  B01J31/2295 ,  B01J2531/46 ,  B01J2531/48 ,  C07F17/00 ,  C08F4/65904 ,  C08F4/65908 ,  C08F4/65912 ,  C08F4/65916 ,  C08F4/65927 ,  C08F10/02 ,  C08F210/16 ,  C08L23/0815 ,  C08F4/025 ,  C08F2500/09 ,  C08F210/14 ,  C08F2500/12 ,  C08F2500/08 ,  C08F2500/03 ,  C08F2500/04 ,  C08F2500/02 ,  C08F2500/07

Abstract: Disclosed herein are catalyst compositions containing boron bridged, cyclopentadienyl-indenyl metallocene compounds with an alkenyl substituent. These catalyst compositions can be used for the polymerization of olefins. For example, ethylene homopolymers produced using these catalyst compositions can be characterized by a density less than 0.97 g/cm3 and a melt index greater than 50 g/10 min.

Abstract translation: 本文公开了含有桥连的具有烯基取代基的环戊二烯基 - 茚基金属茂化合物的催化剂组合物。 这些催化剂组合物可用于烯烃的聚合。 例如，使用这些催化剂组合物制备的乙烯均聚物的特征可以是密度小于0.97g / cm 3，熔体指数大于50g / 10min。

公开(公告)号：US20160304644A1

公开(公告)日：2016-10-20

申请号：US15193195

申请日：2016-06-27

Applicant: Chevron Phillips Chemical Company LP

Inventor： Mark L. Hlavinka ,  Errun Ding ,  Paul DesLauriers ,  Yongwoo Inn ,  Lili Cui ,  Qing Yang ,  Ashish M. Sukhadia ,  Guylaine St. Jean ,  Richard M. Buck

IPC: C08F210/16

CPC classification number: C08F210/16 ,  C08F4/65904 ,  C08F4/65912 ,  C08F4/65916 ,  C08F4/6592 ,  C08F4/65922 ,  C08F4/65925 ,  C08F4/65927 ,  C08F4/69 ,  C08F210/02 ,  C08J5/00 ,  C08J2323/08 ,  C08L23/0815 ,  C08F210/14 ,  C08F2500/04 ,  C08F2500/08 ,  C08F2500/12

Abstract: Disclosed herein are polymerization processes for the production of olefin polymers. These polymerization processes can employ a catalyst system containing two or three metallocene components, resulting in ethylene-based copolymers that can have a medium density and improved stress crack resistance.

公开(公告)号：US09371407B2

公开(公告)日：2016-06-21

申请号：US14870361

申请日：2015-09-30

Applicant: Chevron Phillips Chemical Company LP

Inventor： Qing Yang ,  Max P. McDaniel ,  Tony R. Crain ,  Youlu Yu ,  Yongwoo Inn

IPC: C08F4/653 ,  C08F4/6592 ,  C08L23/00 ,  C08F110/02 ,  C08L23/08 ,  C08F4/659 ,  C08F210/00 ,  C08F210/16

CPC classification number: C08F110/02 ,  C08F4/65904 ,  C08F4/65912 ,  C08F4/65916 ,  C08F4/6592 ,  C08F4/65925 ,  C08F4/65927 ,  C08F210/00 ,  C08F210/16 ,  C08L23/00 ,  C08L23/0815 ,  C08L2314/06 ,  Y10S526/943 ,  C08F2500/04 ,  C08F2500/12 ,  C08F2500/24 ,  C08F2500/05 ,  C08F210/14 ,  C08L23/06

Abstract: Disclosed herein are polymerization processes for the production of olefin polymers. These polymerization processes use a catalyst system containing three metallocene components, often resulting in polymers having a reverse comonomer distribution and a broad and non-bimodal molecular weight distribution.

公开(公告)号：US09353202B2

公开(公告)日：2016-05-31

申请号：US14724362

申请日：2015-05-28

Applicant: Chevron Phillips Chemical Company LP

Inventor： Albert P. Masino ,  Randall S. Muninger ,  Max P. McDaniel ,  Eric D. Schwerdtfeger ,  Qing Yang ,  Graham R. Lief

IPC: C08F4/649 ,  C08F4/6592 ,  C08F10/00 ,  C08F110/02 ,  B01J4/02 ,  B01J19/24 ,  B01J19/00 ,  C08F210/16 ,  C08F4/659

CPC classification number: C08F110/02 ,  B01J4/02 ,  B01J19/0006 ,  B01J19/2455 ,  B01J2204/002 ,  B01J2219/00164 ,  B01J2219/00247 ,  B01J2219/24 ,  C08F4/649 ,  C08F4/65912 ,  C08F4/65916 ,  C08F4/6592 ,  C08F4/65927 ,  C08F210/16 ,  C08F2410/02 ,  C08F2/005 ,  C08F4/65925 ,  C08F210/14

Abstract: A catalyst composition may include a precontacted mixture of an olefin polymerization catalyst and an agent including an ammonium salt. The catalyst activity of the catalyst composition in the presence of water may be greater than if no ammonium salt were present in the catalyst composition. The ammonium salt may include a tetraalkylammonium salt, and the olefin polymerization catalyst may include a metallocene compound.

公开(公告)号：US09284389B2

公开(公告)日：2016-03-15

申请号：US14445793

申请日：2014-07-29

Applicant: Chevron Phillips Chemical Company LP

Inventor： Guylaine St. Jean ,  Qing Yang ,  J. Todd Lanier

IPC: C08F10/14

CPC classification number: C08F10/14 ,  C08F4/65916 ,  C08F4/65925 ,  C08F4/65927 ,  C08L23/0815 ,  C08L2203/16 ,  C08L2205/025 ,  C08L2314/06 ,  C08F210/16 ,  C08F4/65904 ,  C08F210/14 ,  C08F2500/05 ,  C08F2500/12 ,  C08F2500/17 ,  C08F2500/04 ,  C08F2500/07 ,  C08F2500/26

Abstract: A bimodal polyethylene copolymer comprising a lower molecular weight (LMW) component and a higher molecular weight (HMW) component, the copolymer having a z-average molecular weight (Mz) of from about 1,000 kg/mol to about 2,500 kg/mol, a weight fraction of the LMW component (LMW fr.) of from about 0.60 to 0.85, a ratio of a weight average molecular weight (Mw) of the HMW component (HMW Mw) to a Mw of the LMW component (LMW Mw) of from about 14 to about 25, a zero shear viscosity (η0) of from about 5×105 Pa-s to about 1×107 Pa-s and a HMW Mw of from about 800 kg/mol to about 1,500 kg/mol.

Abstract translation: 包含较低分子量（LMW）组分和较高分子量（HMW）组分的双峰聚乙烯共聚物，所述共聚物的z-平均分子量（Mz）为约1,000kg / mol至约2,500kg / mol， LMW组分的重量分数（LMW fr。）为约0.60至0.85，HMW组分的重均分子量（Mw）与LMW组分的Mw（LMW Mw）之比为 约14至约25，零剪切粘度（＆eegr.0）为约5×10 5 Pa至约1×10 7 Pa·s，HMW Mw为约800kg / mol至约1,500kg / mol。

公开(公告)号：US09273170B2

公开(公告)日：2016-03-01

申请号：US14205422

申请日：2014-03-12

Applicant: Chevron Phillips Chemical Company LP

Inventor： Mark L. Hlavinka ,  Qing Yang ,  Yongwoo Inn ,  William M. Whitte ,  John R. Rathman ,  Steven J. Secora ,  Daniel G. Hert

IPC: C08L23/08 ,  C08F4/653 ,  C08F4/6592 ,  C08F210/16 ,  C08F4/659

CPC classification number: C08F210/16 ,  C08F4/65904 ,  C08F4/65916 ,  C08L23/0815 ,  C08F210/14 ,  C08F2500/07 ,  C08F2500/17 ,  C08F2500/12 ,  C08F2500/13 ,  C08F2500/05 ,  C08F4/65927 ,  C08F4/65925

Abstract: Disclosed herein are ethylene-based polymers having a density greater than 0.945 g/cm3, a high load melt index less than 25 g/10 min, a peak molecular weight ranging from 52,000 to 132,000 g/mol, and an environmental stress crack resistance of at least 250 hours. These polymers have the processability of chromium-based resins, but with improved impact strength and stress crack resistance, and can be used in large-part blow molding applications.

Abstract translation: 本文公开了具有密度大于0.945g / cm 3，高负荷熔融指数小于25g / 10min，峰值分子量为52,000至132,000g / mol的乙烯基聚合物和环境应力开裂抗性 至少250小时。 这些聚合物具有铬基树脂的加工性，但具有改善的冲击强度和抗应力开裂性，并且可用于大部分吹塑应用。

公开(公告)号：US09273159B2

公开(公告)日：2016-03-01

申请号：US14493384

申请日：2014-09-23

Applicant: Chevron Phillips Chemical Company LP

Inventor： Errun Ding ,  Qing Yang ,  Youlu Yu ,  Lloyd W. Guatney ,  Jim B. Askew

IPC: C08F4/642 ,  C08F4/653 ,  C08F4/6592 ,  C08F210/16 ,  C08F4/76 ,  C08F4/659 ,  C08F10/02 ,  C08F10/00 ,  C08L23/00 ,  C08L23/04 ,  C08L23/10

CPC classification number: C08F4/76 ,  C08F4/52 ,  C08F4/65904 ,  C08F4/65908 ,  C08F4/65912 ,  C08F4/65916 ,  C08F4/6592 ,  C08F4/65925 ,  C08F4/65927 ,  C08F10/00 ,  C08F10/02 ,  C08L23/00 ,  C08L23/04 ,  C08L23/10 ,  C08F110/02 ,  C08F2500/04 ,  C08F2500/12 ,  C08F210/16 ,  C08F210/14 ,  C08F2500/03

Abstract: Disclosed herein are polymerization processes for the production of olefin polymers. These polymerization processes can use a dual catalyst system containing a zirconium or hafnium based metallocene compound and a titanium based half-metallocene compound containing an indenyl group.

Abstract translation: 本文公开了用于生产烯烃聚合物的聚合方法。 这些聚合方法可以使用含有锆或铪基茂金属化合物和含有茚基的钛基半茂金属化合物的双重催化剂体系。

公开(公告)号：US20160053035A1

公开(公告)日：2016-02-25

申请号：US14859638

申请日：2015-09-21

Applicant: Chevron Phillips Chemical Company LP

Inventor： Vivek Rohatgi ,  Jeffrey F. Greco ,  Yongwoo Inn ,  Qing Yang ,  Alfred E. Brown, JR.

IPC: C08F210/16

CPC classification number: C08F210/16 ,  C08F10/08 ,  C08F10/14 ,  C08F2500/05 ,  C08F2500/07 ,  C08F2500/12 ,  C08F4/65927 ,  C08F4/65904 ,  C08F4/65925 ,  C08F210/14 ,  C08F2500/17 ,  C08F2500/13

Abstract: Disclosed herein are ethylene-based polymers having a higher molecular weight component and a lower molecular weight component, and characterized by a density greater than 0.945 g/cm3, a melt index less than 1.5 g/10 min, and a ratio of high load melt index to melt index ranging from 40 to 175. These polymers have the processability of chromium-based resins, but with improved stiffness and stress crack resistance, and can be used in blow molding and other end-use applications.

Abstract translation: 本文公开了具有较高分子量组分和较低分子量组分的乙烯基聚合物，其特征在于密度大于0.945g / cm 3，熔体指数小于1.5g / 10min，高负载熔体 熔体指数指数范围从40至175.这些聚合物具有铬基树脂的加工性，但具有改善的刚度和抗应力开裂性，并且可用于吹塑和其它终端应用。

公开(公告)号：US20150322184A1

公开(公告)日：2015-11-12

申请号：US14278303

申请日：2014-05-15

Applicant: Chevron Phillips Chemical Company LP

Inventor： Mark L. Hlavinka ,  Guylaine St. Jean ,  Qing Yang ,  Deloris R. Gagan

IPC: C08F210/14 ,  B65D81/34 ,  C08J5/18

CPC classification number: C08F210/14 ,  B65D81/34 ,  B65D2581/34 ,  C08F4/65912 ,  C08F4/65916 ,  C08J5/18 ,  C08J2323/08 ,  Y10T428/1352 ,  C08F210/16 ,  C08F2500/17 ,  C08F2500/26 ,  C08F2500/10 ,  C08F110/02 ,  C08F4/65927 ,  C08F4/65925

Abstract: A metallocene-catalyzed polyethylene copolymer having a zero shear viscosity (ηo) of from about 1×102 Pa-s to about 5×103 Pa-s and a ratio of a z-average molecular weight to a number average molecular weight (Mz/Mn) of from about 4 to about 15, and when tested in accordance with ASTM F1249 displays a moisture vapor transmission rate of less than or equal to about 0.9 g-mil/100 in2/day. A metallocene-catalyzed polyethylene copolymer which when tested in accordance with ASTM F1249 has a moisture vapor transmission rate (MVTR) that is decreased by at least 5% when compared to an MVTR determined in accordance with ASTM F1249 of an otherwise similar metallocene-catalyzed polyethylene homopolymer.

Abstract translation: 具有约1×102Pa·s至约5×10 3 Pa·s的零剪切粘度（＆eegr o）的茂金属催化的聚乙烯共聚物和z-平均分子量与数均分子量的比（ Mz / Mn）为约4至约15，并且当根据ASTM F1249测试时，显示小于或等于约0.9g-mil / 100in2 /天的水蒸汽透过率。 茂金属催化的聚乙烯共聚物当根据ASTM F1249测试时具有与根据ASTM F1249测定的另一种类似的茂金属催化聚乙烯的MVTR相比降低至少5％的水蒸汽透过率（MVTR） 均聚物

公开(公告)号：US20150175726A1

公开(公告)日：2015-06-25

申请号：US14639582

申请日：2015-03-05

Applicant: Chevron Phillips Chemical Company LP

Inventor： Max P. McDaniel ,  Ashish M. Sukhadia ,  Errun Ding ,  Chung Ching Tso ,  Albert P. Masino ,  Qing Yang ,  Lloyd W. Guatney ,  Guylaine St. Jean ,  Daniel G. Hert

IPC: C08F210/16 ,  C08J5/18

CPC classification number: C08F210/16 ,  C08F4/65916 ,  C08F4/65925 ,  C08F4/65927 ,  C08F210/14 ,  C08F2410/02 ,  C08F2500/05 ,  C08F2500/08 ,  C08F2500/09 ,  C08F2500/12 ,  C08J5/18 ,  C08J2323/08 ,  C08L23/0815 ,  C08L2205/02 ,  C08L2205/025 ,  C08L2314/06 ,  C08F4/65904 ,  C08F2500/04 ,  C08F2500/07 ,  C08F2500/26

Abstract: Disclosed herein are broad molecular weight distribution olefin polymers having densities in the 0.895 to 0.930 g/cm3 range, and with improved impact and tear resistance. These polymers can have a ratio of Mw/Mn in the 8 to 35 range, a high load melt index in the 4 to 50 range, less than about 0.008 LCB per 1000 total carbon atoms, and a reverse comonomer distribution.

Abstract translation: 本文公开了具有在0.895至0.930g / cm 3范围内的密度并具有改善的耐冲击性和抗撕裂性的宽分子量分布烯烃聚合物。 这些聚合物可以具有8至35范围内的Mw / Mn比，4至50范围内的高负荷熔体指数，每1000个总碳原子小于约0.008LCB，反向共聚单体分布。