公开(公告)号：US06846882B2

公开(公告)日：2005-01-25

申请号：US10239053

申请日：2001-03-27

Applicant: Matthias Kroner ,  Johannes Perner ,  Karl-Heinz Büchner ,  Jochen Wild ,  Jürgen Pfister

Inventor： Matthias Kroner ,  Johannes Perner ,  Karl-Heinz Büchner ,  Jochen Wild ,  Jürgen Pfister

IPC: C08G81/02 ,  C04B24/26 ,  C08F8/14 ,  C08F8/30

CPC classification number: C04B24/2658 ,  C04B2103/408 ,  C08G81/025

Abstract: Polymers containing acid groups are modified by reaction of (a) polymers which comprise at least 5% by weight of a copolymerized monoethylenically unsaturated monomer containing acid groups, have molar masses of from 200 to 100,000 and are obtainable by free-radical polymerization of monoethylenically unsaturated acids in aqueous solution in the presence or absence of other monoethylenically unsaturated monomers and in the presence of at least 4% by weight, based on the monomers used in the polymerization, of a water-soluble sulfur compound in which the sulfur is in the oxidation state +4, with (b) polyalkylene glycols which are end-capped at one end, alkylpolyalkylene glycol amines or mixtures thereof, or mixtures of at least one of the two compounds specified with up to 30% by weight, based on the mixtures, of ammonia, amines, alcohols, hydroxycarboxylic acids or aminocarboxylic acids at up to 250° C.

Abstract translation: 含有酸基的聚合物通过（a）包含至少5重量％的含酸基团的共聚单烯属不饱和单体的聚合物的反应进行改性，摩尔质量为200至100,000，可通过单烯键不饱和的自由基聚合获得 在存在或不存在其它单烯键式不饱和单体的情况下，在基于聚合中使用的单体的至少4重量％存在下，在水溶液中的硫在其中氧化的水溶性硫化合物 状态+4，其中（b）在一端被封端的聚亚烷基二醇，烷基聚亚烷基二醇胺或其混合物，或基于混合物，至多30重量％指定的两种化合物中的至少一种的混合物， 的氨，胺，醇，羟基羧酸或至多250℃的氨基羧酸

公开(公告)号：US06172028B2

公开(公告)日：2001-01-09

申请号：US09155410

申请日：1998-09-28

Applicant: Richard Baur ,  Werner Bertleff ,  Birgit Potthoff-Karl ,  Beate Ehle ,  Matthias Kroner ,  Gunnar Schornick

Inventor： Richard Baur ,  Werner Bertleff ,  Birgit Potthoff-Karl ,  Beate Ehle ,  Matthias Kroner ,  Gunnar Schornick

IPC: C11D330

CPC classification number: C11D1/40 ,  C11D3/3761 ,  C11D7/08 ,  C11D7/3209

Abstract: A mixture comprising (a) from 0.1 to 99% by weight of at least one polycarboxylate having at least 3 carboxyls, (b) from 0.1 to 99% by weight of at least one amine having a pKa value of more than 9, and (c) from 0.1 to 99% by weight of at least one acid selected from the group consisting of mineral acids and organic acids having one or two carboxyls and not more than 10 carbons, with the proviso that the mixture contains less than 24% by weight of triphosphates, is used in detergent and rinse aid formulations.

Abstract translation: 包含（a）0.1至99重量％的至少一种具有至少3个羧基的聚羧酸酯，（b）0.1至99重量％的至少一种pKa值大于9的胺和（ c）0.1至99重量％的至少一种选自无机酸和具有一个或两个羧基且不超过10个碳的有机酸的酸，条件是混合物含有小于24重量％ 的三磷酸盐，用于洗涤剂和漂洗助剂配方中。

公开(公告)号：US5574113A

公开(公告)日：1996-11-12

申请号：US513859

申请日：1995-09-13

Applicant: Matthias Kroner ,  Gunnar Schornick ,  Walter Denzinger ,  Richard Baur ,  Alexander Kud ,  Birgit Potthoff-Karl ,  Volker Schwendemann

Inventor： Matthias Kroner ,  Gunnar Schornick ,  Walter Denzinger ,  Richard Baur ,  Alexander Kud ,  Birgit Potthoff-Karl ,  Volker Schwendemann

IPC: B01F17/00 ,  B01F17/52 ,  C08F8/14 ,  C08F8/30 ,  C08F8/44 ,  C08G69/10 ,  C08G73/06 ,  C08G73/10 ,  C11D3/37 ,  C08F20/62 ,  C08F20/66

CPC classification number: C11D3/3719 ,  B01F17/005 ,  C08F8/44 ,  C08G69/10 ,  C08G73/0611 ,  C08G73/1092 ,  C08F2800/20

Abstract: Polycocondensates based on aspartic acid which are obtainable by condensing aspartic acid in the presence of polymers containing carboxyl groups, which contain at least 10 mol % of a monoethylenically unsaturated carboxylic acid in copolymerized form and have a molecular weight of at least 300, in the weight ratio from 1,000:1 to 2:1, processes for preparing the polycocondensates and use of the polycocondensates in the form of the free acid groups or in a form neutralized with ammonia, amines, alkali metal or alkaline earth metal bases as an additive to detergents and cleaners, as scale inhibitors or as dispersants for finely divided solids are described.

Abstract translation: PCT No.PCT / EP94 / 00660 Sec。 371日期1995年9月13日 102（e）日期1995年9月13日PCT 1994年3月5日PCT公布。 公开号WO94 / 21695 日期1994年9月29日基于天冬氨酸的多缩合物，其可通过在含有羧基的聚合物存在下将天冬氨酸缩合而获得，所述聚合物含有至少10摩尔％的共聚形式的单烯键式不饱和羧酸并且分子量至少为 300，重量比为1,000:1至2:1，制备聚缩聚物的方法和使用游离酸基形式的聚缩聚物或以氨，胺，碱金属或碱土金属碱中和的形式 作为洗涤剂和清洁剂的添加剂，作为阻垢剂或用于细碎固体的分散剂。

公开(公告)号：US5548036A

公开(公告)日：1996-08-20

申请号：US464624

申请日：1995-06-26

Applicant: Matthias Kroner ,  Heinrich Hartmann ,  Gunnar Schornick ,  Richard Baur ,  Birgit Potthoff-Karl ,  Volker Schwendemann ,  Alexander Kud

Inventor： Matthias Kroner ,  Heinrich Hartmann ,  Gunnar Schornick ,  Richard Baur ,  Birgit Potthoff-Karl ,  Volker Schwendemann ,  Alexander Kud

IPC: B01F17/00 ,  B01F17/52 ,  C08G69/10 ,  C08G73/00 ,  C08G73/06 ,  C08G73/10 ,  C09B67/46 ,  C09D17/00 ,  C11D3/37 ,  C86G69/08 ,  C86G69/10 ,  C86G73/06 ,  C86G73/10

CPC classification number: C11D3/3719 ,  B01F17/005 ,  C08G69/10 ,  C08G73/0611 ,  C08G73/1092 ,  C09B67/0085 ,  C09D17/00

Abstract: Process for the preparation of polymers of aspartic acid by reacting (a) maleic anhydride and (b) ammonia and/or primary or secondary amines without diluent in the (a):(b) molar ratio of 1:0.1 to 1:3 to give monoamides of maleic acid, fumaric acid or their ammonium salts at up to 100.degree. C. and subsequent condensation of the reaction products, with or without compounds capable of cocondensation, at above 100.degree. C. and, where appropriate, hydrolysis of the condensates and use of the polymers as scale inhibitor, as dispersants for pigments and as additive to detergents and cleaners.

Abstract translation: PCT No.PCT / EP93 / 03641 Sec。 371日期：1995年6月26日 102（e）日期1995年6月26日PCT提交1993年12月21日PCT公布。 第WO94 / 15993号公报 日期1994年7月21日通过（a）马来酸酐和（b）在（a）:( b）摩尔比为1:0.1的氨基和/或不含稀释剂的氨和/或伯胺或仲胺反应制备天冬氨酸的聚合物的方法 至1：3，以在高达100℃下得到马来酸，富马酸或其铵盐的单酰胺，随后在100℃以上反应产物，有或没有能够缩聚的化合物缩合，并且在适当的情况下 缩合物的水解和聚合物作为阻垢剂的使用，作为颜料的分散剂和作为洗涤剂和清洁剂的添加剂。

公开(公告)号：US5374681A

公开(公告)日：1994-12-20

申请号：US177388

申请日：1994-01-05

Applicant: Matthias Kroner ,  Heinrich Hartmann ,  Richard Baur ,  Volker Schwendemann ,  Hans-Ulrich Jaeger ,  Johannes Perner

Inventor： Matthias Kroner ,  Heinrich Hartmann ,  Richard Baur ,  Volker Schwendemann ,  Hans-Ulrich Jaeger ,  Johannes Perner

IPC: C08G2/00 ,  C08G65/34 ,  C08L59/00 ,  C11D3/37 ,  C08L29/02 ,  C08G67/02

CPC classification number: C08G65/34 ,  C11D3/3711

Abstract: Polyacetals useful as reduced-phosphate or phosphate-free detergent and cleaner additives are obtainable by cationically initiated polyaddition of(a) divinyl ethers and(b) dihydroxy compounds and also, optionally,(c) monohydroxy compoundsand have K values of from 8 to 100.

Abstract translation: 用作还原磷酸盐或无磷酸盐洗涤剂和清洁剂添加剂的聚缩醛可以通过（a）二乙烯基醚和（b）二羟基化合物以及任选的（c）单羟基化合物的阳离子引发的加聚获得，并且具有从8到 100。

公开(公告)号：US5260396A

公开(公告)日：1993-11-09

申请号：US970246

申请日：1992-11-02

Applicant: Matthias Kroner ,  Heinrich Hartmann ,  Ekhard Winkler ,  Juergen Steinmetz ,  Thomas Anstock

Inventor： Matthias Kroner ,  Heinrich Hartmann ,  Ekhard Winkler ,  Juergen Steinmetz ,  Thomas Anstock

IPC: A61F13/15 ,  A61L15/22 ,  A61L15/32 ,  C08F289/00 ,  C09D151/02 ,  D06M15/15 ,  D06N3/12 ,  D21H19/16 ,  D21H21/16 ,  C08H89/00 ,  B32B7/00 ,  B32B27/00

CPC classification number: D21H21/16 ,  A61L15/225 ,  A61L15/32 ,  C08F289/00 ,  C09D151/02 ,  D06M15/15 ,  D06N3/12 ,  D21H19/16 ,  A61F13/15252 ,  A61F2013/5145 ,  Y10S428/911 ,  Y10T428/31768 ,  Y10T428/31775 ,  Y10T442/2246

Abstract: Water resistant films and coatings are prepared by treating films or coatings of water soluble or dispersible grafted proteins prepared with monoethylenically unsaturated monomers at above 40.degree. C. and/or with at least one compound which is a hardener for proteins, and are useful as compostable packaging materials or as outer layers of diapers.

Abstract translation: 通过处理在40℃以上用单烯属不饱和单体制备的水溶性或可分散的接枝蛋白质的膜或涂层和/或至少一种化合物来制备耐水膜和涂层，所述化合物是蛋白质的硬化剂，并且可用作可堆肥的 包装材料或尿布外层。

公开(公告)号：US5208075A

公开(公告)日：1993-05-04

申请号：US888139

申请日：1992-05-26

Applicant: Matthias Kroner ,  Manfred Niessner ,  Heinrich Hartmann ,  Dieter Voelker ,  Juergen Hartmann ,  Holger Schoepke

Inventor： Matthias Kroner ,  Manfred Niessner ,  Heinrich Hartmann ,  Dieter Voelker ,  Juergen Hartmann ,  Holger Schoepke

IPC: D06M15/15

CPC classification number: D06M15/15 ,  D06M2200/40

Abstract: Water-soluble or water-dispersible grafts of proteins with monoethylenically unsaturated monomers are used as sizing agents for staple fiber and filament yarns.

Abstract translation: 使用具有单烯属不饱和单体的蛋白质的水溶性或水分散性移植物作为短纤维和长丝纱线的上浆剂。

公开(公告)号：US4941436A

公开(公告)日：1990-07-17

申请号：US400681

申请日：1989-08-30

Applicant: Michael Beer ,  Philipp Schimko ,  August Hofbauer ,  Matthias Kroner

Inventor： Michael Beer ,  Philipp Schimko ,  August Hofbauer ,  Matthias Kroner

IPC: F01L3/12 ,  F01L3/22 ,  F01M9/10 ,  F01P3/14 ,  F01P9/00 ,  F02B3/06 ,  F02F1/24

CPC classification number: F01P3/14 ,  F01L3/22 ,  F01M9/10 ,  F01P9/00 ,  F01M9/101 ,  F02B3/06 ,  F02F2001/245

Abstract: Valve seat inserts of a four-cycle internal-combustion engine are cooled by the lubricating oil of the oil circulating system. An oil duct extending in the camshaft housing is bored in such a manner that the lubricating oil flows from the oil duct into a ring duct surrounding the valve seat inserts. By means of a projection which closes off the ring duct, a forced flow around the valve seat insert is achieved before the lubricating oil flows out of the ring duct through an opening located close to the lubricating oil inlet. From the ring duct the lubricating oil flows through a discharge pipe to the camshaft where it is sprayed on the cams.

Abstract translation: 四循环内燃机的阀座插件由油循环系统的润滑油冷却。 在凸轮轴壳体中延伸的油道以这样的方式钻孔，使得润滑油从油管道流入围绕阀座插入件的环形管道。 通过关闭环形管道的突起，在润滑油通过位于靠近润滑油入口的开口从环形管道流出之前，实现了阀座插入件周围的强制流动。 从环形管道中，润滑油通过排出管道流到凸轮轴，喷射在凸轮上。

公开(公告)号：US20110251423A1

公开(公告)日：2011-10-13

申请号：US13125408

申请日：2009-10-19

Applicant: Horst Binder ,  Matthias Kroner ,  Alexander Bayer

Inventor： Horst Binder ,  Matthias Kroner ,  Alexander Bayer

IPC: C07C265/10 ,  C07C263/00

CPC classification number: C08G18/73 ,  C07C263/18 ,  C07C263/20 ,  C07D251/34 ,  C08G18/022 ,  C08G18/1875 ,  C08G18/755 ,  C08G18/792 ,  C08G18/798 ,  C07C265/14

Abstract: The present invention relates to a process for preparing colorless polyisocyanates, in particular for reducing the color of polyisocyanates.

Abstract translation: 本发明涉及一种制备无色多异氰酸酯的方法，特别是用于降低多异氰酸酯的颜色。

公开(公告)号：US06878683B2

公开(公告)日：2005-04-12

申请号：US10297490

申请日：2001-06-06

Applicant: Peter Neumann ,  Werner Bertleff ,  Matthias Kroner ,  Bernard Mohr

Inventor： Peter Neumann ,  Werner Bertleff ,  Matthias Kroner ,  Bernard Mohr

IPC: C08F290/06 ,  C08G81/02 ,  C11D3/37 ,  C11D11/00

CPC classification number: C11D11/0082 ,  C11D3/3761

Abstract: Polymers of a poly(meth)acrylic acid main chain in which, based on the main chain, 0 to 30% by weight of the (meth)acrylic acid basic building blocks may be replaced by maleic acid (anhydride) basic building blocks, fumaric acid basic building blocks or mixtures thereof and 0 to 10% by weight of the (meth)acrylic acid basic building blocks may be replaced by other copolymerizable ethylenic basic building blocks,and C1-30-alkylpoly-C2-4-alkylene glycols, bonded to the main chain via ester groups, having an average molecular weight of from 250 to 10 000 as side chains,where, based on the polymer, 1 to 19% by weight of the main chain and 81 to 99% by weight of the side chains are present and this ratio and the average molecular weight of the side chains are chosen such that free carboxyl groups are present in the polymer,are used as controllable dispersants for detergents or cleaners or constituents thereof.

Abstract translation: 聚（甲基）丙烯酸主链的聚合物，其中以主链为基准的0〜30重量％的（甲基）丙烯酸碱性结构单元可以用马来酸（酸酐）碱性结构单元代替富马酸 酸性碱性结构单元或其混合物，和0〜10重量％的（甲基）丙烯酸碱性结构单元可以被其它可共聚的烯属碱性结构单元和C1-30烷基聚-C2-4-亚烷基二醇替代， 通过酯基，其平均分子量为250至10000作为侧链，其中基于聚合物，1至19重量％的主链和81至99重量％的侧面 链，并且该比例和侧链的平均分子量被选择为使得游离羧基存在于聚合物中，用作洗涤剂或清洁剂或其组分的可控分散剂。