公开(公告)号：US20210249605A1

公开(公告)日：2021-08-12

申请号：US17238450

申请日：2021-04-23

Applicant: PHILLIPS 66 COMPANY

Inventor： Hualong Pan ,  Kathy Woody ,  Brian Worfolk ,  Taeshik Earmme

IPC: H01L51/00 ,  C08G61/12

Abstract: A random copolymer comprising the monomer units A, B and C. In this random copolymer A comprises B comprises and C comprises an aryl group. Additionally, R1 R2, R3 and R4 are side chains independently selected from the group consisting of: H, Cl, F, CN, alkyl, alkoxy, alkylthio, ester, ketone and aryl groups. X1 and X2 are independently selected from the group consisting of: H, Cl, F, CN, alkyl, alkoxy, ester, ketone, amide and aryl groups.

公开(公告)号：US20210238344A1

公开(公告)日：2021-08-05

申请号：US17238533

申请日：2021-04-23

Applicant: PHILLIPS 66 COMPANY

Inventor： Hualong Pan ,  Kathy Woody ,  Brian Worfolk ,  Taeshik Earmme

IPC: C08G61/12

Abstract: A random copolymer comprising the monomer units A and B. In this random copolymer A comprises and B comprises Additionally, R1 R2, R3 and R4 are side chains independently selected from the group consisting of: H, Cl, F, CN, alkyl, alkoxy, alkylthio, ester, ketone and aryl groups. X1 and X2 are identical and selected from the group consisting of: H, Cl, F, CN, alkyl, alkoxy, ester, ketone, amide and aryl groups.

公开(公告)号：US10787537B2

公开(公告)日：2020-09-29

申请号：US16253992

申请日：2019-01-22

Applicant: PHILLIPS 66 COMPANY

Inventor： Joe Bullock ,  Brian Worfolk ,  Taeshik Earmme ,  Hualong Pan ,  Kathy Woody

IPC: C08G61/12 ,  H01L51/00 ,  H01L51/42

Abstract: A method of coupling and 5,5-Y-3,3′-difluoro-2,2′-bithiophene to produce wherein X can be any known compound capable of coupling with the Y-difluorothiophene and Y is selected from the group consisting of Br, a stannyl group, a boronic ester and a H.

公开(公告)号：US10358444B2

公开(公告)日：2019-07-23

申请号：US15644186

申请日：2017-07-07

Applicant: PHILLIPS 66 COMPANY

Inventor： Hualong Pan ,  Kathy Woody ,  Brian Worfolk ,  Taeshik Earmme

IPC: C07D417/14 ,  C07D285/14 ,  H01L51/00 ,  H01L51/42

Abstract: A molecular complex comprising wherein X1 and X2 are independently selected from the group consisting of: H, Cl, F, CN, alkyl, alkoxy, ester, ketone, amide and aryl groups; R1, R2, R1′ and R2′ are side chains independently selected from the group consisting of: H, Cl, F, CN, alkyl, alkoxy, alkylthio, ester, ketone and aryl groups; G is an aryl group; and wherein the thiophene groups are unsymmetrical.

公开(公告)号：US10312448B2

公开(公告)日：2019-06-04

申请号：US15245648

申请日：2016-08-24

Applicant: PHILLIPS 66 COMPANY

Inventor： Joseph Bullock ,  Brian Worfolk

IPC: H01L51/00 ,  H01L51/42 ,  C01B32/152 ,  C01B32/156 ,  C07C231/02 ,  C07C233/22 ,  C07C233/40

Abstract: A process of dissolving in a solvent to produce a first mixture. To the first mixture a reagent is added to produce a second mixture. A H—N—R′—R″ is then added to the second mixture to produce a third mixture. The third mixture is then refluxed to produce

公开(公告)号：US10099963B2

公开(公告)日：2018-10-16

申请号：US15245676

申请日：2016-08-24

Applicant: PHILLIPS 66 COMPANY

Inventor： Brian Worfolk ,  Nneka Uguru Eboagwu

IPC: H01B1/08 ,  C04B35/00 ,  C04B35/457 ,  C04B35/453 ,  H01L51/00 ,  H01L51/42

Abstract: A reaction comprising an organic Zn precursor in the amounts of (1−y), an organic Sn precursor in the amounts of y and a base in the amount of (1−y). The product produced from the reaction is (SnOx)yZnO(1−y).

公开(公告)号：US09905769B2

公开(公告)日：2018-02-27

申请号：US15245939

申请日：2016-08-24

Applicant: PHILLIPS 66 COMPANY

Inventor： Joseph Bullock ,  Brian Worfolk

IPC: C07C69/76 ,  H01L51/00 ,  C07C213/02 ,  C07C213/08 ,  C07C219/10 ,  H01L51/42

CPC classification number: H01L51/0047 ,  C07C209/12 ,  C07C209/68 ,  C07C213/02 ,  C07C213/06 ,  C07C213/08 ,  C07C219/10 ,  C07C2604/00 ,  H01L51/0003 ,  H01L51/4253 ,  C07C219/14 ,  C07C211/63

Abstract: A process of dissolving [6,6]-phenyl-C60-butyric-N-2-dimethylaminoethyl ester in a solvent to produce a first mixture. A reagent is added to the first mixture to produce a second mixture. The second mixture is then refluxed to produce [6,6]-phenyl-C60-butyric-N-2-trimethylammonium ethyl ester iodide.

公开(公告)号：US20180026194A1

公开(公告)日：2018-01-25

申请号：US15644230

申请日：2017-07-07

Applicant: PHILLIPS 66 COMPANY

Inventor： Hualong Pan ,  Kathy Woody ,  Brian Worfolk ,  Taeshik Earmme

IPC: H01L51/00 ,  C08G61/12

Abstract: A molecular complex comprising wherein X1 and X2 are independently selected from the group consisting of: H, Cl, F, CN, alkyl, alkoxy, ester, ketone, amide and aryl groups; R1, R2, R1′ and R2′ are side chains independently selected from the group consisting of: H, Cl, F, CN, alkyl, alkoxy, alkylthio, ester, ketone and aryl groups; R3 are selected from the group consisting of alkyl group, alkoxy group, aryl groups and combinations thereof; and wherein the thiophene groups are unsymmetrical.

公开(公告)号：US20180022718A1

公开(公告)日：2018-01-25

申请号：US15644186

申请日：2017-07-07

Applicant: PHILLIPS 66 COMPANY

Inventor： Hualong Pan ,  Kathy Woody ,  Brian Worfolk ,  Taeshik Earmme

IPC: C07D285/14 ,  H01L51/00

CPC classification number: C07D417/14 ,  C07D285/14 ,  H01L51/0036 ,  H01L51/0047 ,  H01L51/4253 ,  Y02E10/549

Abstract: A molecular complex comprising wherein X1 and X2 are independently selected from the group consisting of: H, Cl, F, CN, alkyl, alkoxy, ester, ketone, amide and aryl groups; R1, R2, R1′ and R2′ are side chains independently selected from the group consisting of: H, Cl, F, CN, alkyl, alkoxy, alkylthio, ester, ketone and aryl groups; G is an aryl group; and wherein the thiophene groups are unsymmetrical.

公开(公告)号：US20180022717A1

公开(公告)日：2018-01-25

申请号：US15644153

申请日：2017-07-07

Applicant: PHILLIPS 66 COMPANY

Inventor： Hualong Pan ,  Kathy Woody ,  Brian Worfolk ,  Taeshik Earmme

IPC: C07D285/14 ,  C07D495/04 ,  H01L51/00 ,  C07D417/14

CPC classification number: C07D285/14 ,  C07D417/14 ,  C07D495/04 ,  H01L51/0036 ,  H01L51/0043 ,  H01L51/0047 ,  H01L51/4253

Abstract: A method of forming a molecular complex. The method proceeds by reacting 5-chloro-2,1,3-benzothiadiazole with N-bromosuccinimide to produce 4,7-dibromo-5-chlorobenzo[c][1,2,5]thiadiazole. 4,7-dibromo-5-chlorobenzo[c][1,2,5]thiadiazole is then reacted with trimethyl[4-(2-octyldodecyl)thiophen-2-yl]stannane to produce 5-chloro-4,7-bis(4-(2-octyldodecyl)thiophen-2-yl)benzo[c][1,2,5]thiadiazole. 4, 7-bis(5-bromo-4-(2-octyldodecyl)thiophen-2-yl)-5-chlorobenzo[c][1,2,5]thiadiazole is subsequently synthesized from 5-chloro-4,7-bis(4-(2-octyldodecyl)thiophen-2-yl)benzo[c][1,2,5]thiadiazole. 4,7-bis(5-bromo-4-(2-octyldodecyl)thiophen-2-yl)-5-chlorobenzo[c][1,2,5]thiadiazole with tributyl(thiophen-2-yl)stannane is then reacted to produce 4-bromo-5,6-difluoro-7-(thiophen-2-yl)benzo[c][1,2,5]thiadiazole. This is followed by reacting 4,7-dibromo-5-chloro-2,1,3-benzothiadiazole with tributyl(thiophen-2-yl)stannane to produce 4-bromo-5-chloro-7-(thiophen-2-yl)benzo[c][1,2,5]thiadiazole. trimethyl[4-(2-octyldodecyl)thiophen-2-yl]stannane is then reacted with and 4-bromo-5-chloro-7-(thiophen-2-yl)benzo[c][1,2,5]thiadiazole to produce 5-chloro-4-(4-(2-octyldodecyl)thiophen-2-yl)-7-(thiophen-2-yl)benzo[c][1,2,5]thiadiazole. 5-chloro-4-(4-(2-octyldodecyl)thiophen-2-yl)-7-(thiophen-2-yl)benzo[c][1,2,5]thiadiazole is then reacted with N-bromosuccinimide to produce the co-monomer 4-(5-bromo-4-(2-octyldodecyl)thiophen-2-yl)-7-(5-bromothiophen-2-yl)-5-chlorobenzo[c][1,2,5]thiadiazole. A group can then be coupled to 4-(5-bromo-4-(2-octyldodecyl)thiophen-2-yl)-7-(5-bromothiophen-2-yl)-5-chlorobenzo[c][1,2,5]thiadiazole to produce a molecular complex.