公开(公告)号：US20130109609A1

公开(公告)日：2013-05-02

申请号：US13720753

申请日：2012-12-19

Applicant: The Clorox Company

Inventor： William L. Smith ,  Evan M. Rumberger

IPC: C11D3/395

CPC classification number: C11D3/3951 ,  C11D3/10 ,  C11D3/2079 ,  C11D3/2082 ,  C11D3/33 ,  C11D3/349 ,  C11D3/3761 ,  C11D3/3776 ,  C11D3/378 ,  C11D3/3953 ,  C11D17/0039 ,  C11D17/0078

Abstract: The present invention provides a solid-layered composition having at least two parts. The first part comprises a) calcium hypochlorite, magnesium hypochlorite and mixtures thereof, b) a builder, c) a water-soluble polymer, d) an acid, and e) wherein the first part does not contain sodium hypochlorite, lithium hypochlorite, potassium hypochlorite and mixtures thereof. The second part comprises a) a functional ingredient, b) a builder or filler, and c) wherein the second part does not contain any oxidant.

Abstract translation: 本发明提供具有至少两部分的固体层组合物。 第一部分包括a）次氯酸钙，次氯酸镁及其混合物，b）助洗剂，c）水溶性聚合物，d）酸和e）其中第一部分不含次氯酸钠，次氯酸锂，钾 次氯酸盐及其混合物。 第二部分包括a）功能成分，b）助洗剂或填料，和c）其中第二部分不含任何氧化剂。

公开(公告)号：US11578231B2

公开(公告)日：2023-02-14

申请号：US16950458

申请日：2020-11-17

Applicant: THE CLOROX COMPANY

Inventor： David R. Scheuing ,  David J. Lestage ,  Carl W. Bennett ,  Mona M. Knock ,  Charles W. Scales ,  William L. Smith ,  Rui Zhang

IPC: C11D1/62 ,  C09D133/02 ,  C09D5/14 ,  A01N25/10 ,  A01N33/12 ,  A01N59/00 ,  A01N59/16 ,  C11D3/37 ,  C11D3/395

Abstract: The present invention relates to aqueous compositions of associative polyelectrolyte complexes (PECs), optionally containing surfactants, biocidal agents and/or oxidants, which can provide surface protection to treated articles including reduced soiling tendency, reduced cleaning effort and improved soil repellancy, as well as providing bacteriostatic properties to treated surfaces that thereby gain resistance to water, environmental exposure and microbial challenge. Treatment means and compositions are provided that employ associative polyelectrolyte complexes formed by combining a water soluble cationic first polyelectrolyte with a water soluble second polyelectrolyte bearing groups of opposite charge to the first polyelectrolyte under suitable mixing conditions where the one polyelectrolyte present in molar excess is added in the form of a first aqueous solution during a mixing step to a second aqueous solution comprising the oppositely charged polyelectrolyte present in molar deficiency. Also provided are means to form stable associative polyelectrolyte complexes in aqueous solutions having R values from about 0.10 to 20, including near stoichiometric R values approaching 1, being the ratio of charged groups present on the component polyelectrolytes employed.

公开(公告)号：US10968363B2

公开(公告)日：2021-04-06

申请号：US16506124

申请日：2019-07-09

Applicant: THE CLOROX COMPANY

Inventor： David R. Scheuing ,  David J. Lestage ,  Carl W. Bennett ,  Mona M. Knock ,  Charles W. Scales ,  William L. Smith ,  Rui Zhang

IPC: C11D3/37 ,  C09D133/02 ,  C09D5/14 ,  A01N25/10 ,  A01N33/12 ,  A01N59/00 ,  A01N59/16 ,  C11D1/62 ,  C11D3/395

Abstract: The present invention relates to aqueous compositions of associative polyelectrolyte complexes (PECs), optionally containing surfactants, biocidal agents and/or oxidants, which can provide surface protection to treated articles including reduced soiling tendency, reduced cleaning effort and improved soil repellancy, as well as providing bacteriostatic properties to treated surfaces that thereby gain resistance to water, environmental exposure and microbial challenge. Treatment means and compositions are provided that employ associative polyelectrolyte complexes formed by combining a water soluble cationic first polyelectrolyte with a water soluble second polyelectrolyte bearing groups of opposite charge to the first polyelectrolyte under suitable mixing conditions where the one polyelectrolyte present in molar excess is added in the form of a first aqueous solution during a mixing step to a second aqueous solution comprising the oppositely charged polyelectrolyte present in molar deficiency. Also provided are means to form stable associative polyelectrolyte complexes in aqueous solutions having R values from about 0.10 to 20, including near stoichiometric R values approaching 1, being the ratio of charged groups present on the component polyelectrolytes employed.

公开(公告)号：US20190136163A1

公开(公告)日：2019-05-09

申请号：US16238778

申请日：2019-01-03

Applicant: THE CLOROX COMPANY

Inventor： David R. Scheuing ,  William L. Smith ,  Michael Kinsinger ,  Jared Heymann

IPC: C11D17/04 ,  C07B57/00 ,  C11D3/37 ,  A01N59/00 ,  A01N43/36 ,  A01N37/02 ,  A01N43/16 ,  C11D3/48 ,  A01N33/12 ,  B08B1/00 ,  A01N59/16

CPC classification number: C11D17/049 ,  A01N33/12 ,  A01N37/02 ,  A01N43/16 ,  A01N43/36 ,  A01N59/00 ,  A01N59/16 ,  A61L15/10 ,  A61L15/46 ,  B08B1/006 ,  C07B57/00 ,  C11D3/3723 ,  C11D3/3757 ,  C11D3/3776 ,  C11D3/378 ,  C11D3/48 ,  A01N25/10 ,  A01N25/22 ,  A01N25/24

Abstract: The present invention relates to aqueous compositions of associative polyelectrolyte complexes (PECs), optionally containing surfactants, biocidal agents and/or oxidants, which can provide a cleaning benefit and surface protection to treated articles including reduced soiling tendency, reduced cleaning effort and improved soil repellancy, as well as providing bacteriostatic properties to treated surfaces that thereby gain resistance to water, environmental exposure and microbial challenge. Treatment means and compositions are provided that employ associative polyelectrolyte complexes formed by combining a water soluble cationic first polyelectrolyte with a water soluble second polyelectrolyte bearing groups of opposite charge to the first polyelectrolyte under suitable mixing conditions and at least one oxidant selected from the group: alkaline metal salts and/or alkaline earth metal salts of hypochlorous acid, hypochlorous acid, solubilized chlorine, any source of free chlorine, acidic sodium chlorite, active chlorine generating compound and any combinations or mixtures thereof. Also provided are means to form stable associative polyelectrolyte complexes with at least one oxidant in aqueous solutions having R values from about 0.10 to 20.

公开(公告)号：US10100271B2

公开(公告)日：2018-10-16

申请号：US15945482

申请日：2018-04-04

Applicant: The Clorox Company

Inventor： Evan Rumberger ,  Marisa Macnaughtan ,  William L. Smith ,  Kelsey Kornaus

IPC: C11D3/395 ,  C11D3/50 ,  C11D17/00 ,  C11D3/12 ,  C11D1/00 ,  A01N25/34 ,  A01N59/06 ,  C11D17/06 ,  C11D3/10 ,  C11D3/04 ,  C11D3/08 ,  C11D17/04

Abstract: The invention relates to compositions, methods of use, and methods of manufacture for an intercalated bleach compound and compositions thereof. The intercalated bleach compound has the formula Mx(OCl)y(O)m(OH)n where M is an alkaline earth metal such as magnesium, calcium or mixture thereof. The values of x and y independently equal any number greater than or equal to 1 (e.g., 1, 2, 3, 4, etc.), and m and n independently equal any number greater than or equal to 0 (e.g., 0, 1, 2, 3, 4, etc.), but m and n are not both 0. In addition, the molar ratio of the alkaline earth metal (e.g., magnesium or calcium) to hypochlorite is at least 3:1. In other words, x is ≥3y. The compounds exhibit excellent stability, little or no chlorine bleach odor, exhibit excellent pH buffering characteristics, and less reactivity with organic materials as compared to alternative chlorine bleach products.

公开(公告)号：US20180223224A1

公开(公告)日：2018-08-09

申请号：US15945482

申请日：2018-04-04

Applicant: The Clorox Company

Inventor： Evan Rumberger ,  Marisa Macnaughtan ,  William L. Smith ,  Kelsey Kornaus

IPC: C11D3/395 ,  C11D17/06 ,  C11D17/00 ,  C11D3/50 ,  C11D3/12 ,  C11D3/10 ,  A01N25/34 ,  C11D3/04 ,  C11D1/00 ,  A01N59/06 ,  C11D3/08

CPC classification number: C11D3/3953 ,  A01N25/08 ,  A01N25/34 ,  A01N59/06 ,  C01B11/064 ,  C01B11/066 ,  C11D1/00 ,  C11D3/04 ,  C11D3/042 ,  C11D3/044 ,  C11D3/046 ,  C11D3/08 ,  C11D3/10 ,  C11D3/12 ,  C11D3/1213 ,  C11D3/3757 ,  C11D3/3956 ,  C11D3/50 ,  C11D17/0073 ,  C11D17/041 ,  C11D17/06

Abstract: The invention relates to compositions, methods of use, and methods of manufacture for an intercalated bleach compound and compositions thereof. The intercalated bleach compound has the formula Mx(OCl)y(O)m(OH)n where M is an alkaline earth metal such as magnesium, calcium or mixture thereof. The values of x and y independently equal any number greater than or equal to 1 (e.g., 1, 2, 3, 4, etc.), and m and n independently equal any number greater than or equal to 0 (e.g., 0, 1, 2, 3, 4, etc.), but m and n are not both 0. In addition, the molar ratio of the alkaline earth metal (e.g., magnesium or calcium) to hypochlorite is at least 3:1. In other words, x is ≥3y. The compounds exhibit excellent stability, little or no chlorine bleach odor, exhibit excellent pH buffering characteristics, and less reactivity with organic materials as compared to alternative chlorine bleach products.

公开(公告)号：US20180023044A1

公开(公告)日：2018-01-25

申请号：US15721367

申请日：2017-09-29

Applicant: THE CLOROX COMPANY

Inventor： David R. Scheuing ,  William L. Smith ,  Michael Kinsinger ,  Jared Heymann

IPC: C11D17/04 ,  A01N33/12 ,  C11D3/37 ,  C07B57/00 ,  B08B1/00 ,  A01N59/16 ,  A01N59/00 ,  A01N43/36 ,  A01N43/16 ,  C11D3/48 ,  A01N37/02 ,  A61L15/46 ,  A61L15/10

CPC classification number: C11D17/049 ,  A01N33/12 ,  A01N37/02 ,  A01N43/16 ,  A01N43/36 ,  A01N59/00 ,  A01N59/16 ,  A61L15/10 ,  A61L15/46 ,  B08B1/006 ,  C07B57/00 ,  C11D3/3723 ,  C11D3/3757 ,  C11D3/3776 ,  C11D3/378 ,  C11D3/48 ,  A01N25/10 ,  A01N25/22 ,  A01N25/24

Abstract: The present invention relates to aqueous compositions of associative polyelectrolyte complexes (PECs), optionally containing surfactants, biocidal agents and/or oxidants, which can provide a cleaning benefit and surface protection to treated articles including reduced soiling tendency, reduced cleaning effort and improved soil repellency, as well as providing bacteriostatic properties to treated surfaces that thereby gain resistance to water, environmental exposure and microbial challenge. Treatment means and compositions are provided that employ associative polyelectrolyte complexes formed by combining a water soluble cationic first polyelectrolyte with a water soluble second polyelectrolyte bearing groups of opposite charge to the first polyelectrolyte under suitable mixing conditions and at least one oxidant selected from the group: alkaline metal salts and/or alkaline earth metal salts of hypochlorous acid, hypochlorous acid, solubilized chlorine, any source of free chlorine, acidic sodium chlorite, active chlorine generating compound and any combinations or mixtures thereof. Also provided are means to form stable associative polyelectrolyte complexes with at least one oxidant in aqueous solutions having R values from about 0.10 to 20.

公开(公告)号：US09796872B2

公开(公告)日：2017-10-24

申请号：US15005366

申请日：2016-01-25

Applicant: THE CLOROX COMPANY

Inventor： David R. Scheuing ,  David J. Lestage ,  Carl W. Bennett ,  Mona M. Knock ,  Charles W. Scales ,  William L. Smith ,  Rui Zhang

IPC: C11D1/62 ,  C09D133/02 ,  C09D5/14 ,  A01N25/10 ,  A01N33/12 ,  A01N59/00 ,  A01N59/16 ,  C11D3/37 ,  C11D3/395

CPC classification number: C09D133/02 ,  A01N25/10 ,  A01N33/12 ,  A01N59/00 ,  A01N59/16 ,  C09D5/14 ,  C11D1/62 ,  C11D3/3769 ,  C11D3/3953

Abstract: The present invention relates to aqueous compositions of associative polyelectrolyte complexes (PECs), optionally containing surfactants, biocidal agents and/or oxidants, which can provide surface protection to treated articles including reduced soiling tendency, reduced cleaning effort and improved soil repellancy, as well as providing bacteriostatic properties to treated surfaces that thereby gain resistance to water, environmental exposure and microbial challenge. Treatment means and compositions are provided that employ associative polyelectrolyte complexes formed by combining a water soluble cationic first polyelectrolyte with a water soluble second polyelectrolyte bearing groups of opposite charge to the first polyelectrolyte under suitable mixing conditions where the one polyelectrolyte present in molar excess is added in the form of a first aqueous solution during a mixing step to a second aqueous solution comprising the oppositely charged polyelectrolyte present in molar deficiency. Also provided are means to form stable associative polyelectrolyte complexes in aqueous solutions having R values from about 0.10 to 20, including near stoichiometric R values approaching 1, being the ratio of charged groups present on the component polyelectrolytes employed.

公开(公告)号：US09663747B2

公开(公告)日：2017-05-30

申请号：US15285428

申请日：2016-10-04

Applicant: THE CLOROX COMPANY

Inventor： David R. Scheuing ,  Thomas F. Fahlen ,  Jared Heymann ,  Mike Kinsinger ,  William Ouellette ,  William L. Smith

IPC: C11D3/48 ,  C11D7/00 ,  C09D5/14 ,  C09D7/00 ,  C11D3/37 ,  C11D3/00 ,  B01J45/00 ,  C09D147/00 ,  C09D5/16 ,  C09D133/02 ,  A01N25/10

CPC classification number: C09D147/00 ,  A01N25/10 ,  A01N33/12 ,  A01N59/00 ,  B01J45/00 ,  C09D5/14 ,  C09D5/1662 ,  C09D7/001 ,  C09D7/002 ,  C09D7/20 ,  C09D7/43 ,  C09D133/00 ,  C09D133/02 ,  C09D139/00 ,  C11D3/0036 ,  C11D3/227 ,  C11D3/3723 ,  C11D3/3757 ,  C11D3/3765 ,  C11D3/3769 ,  C11D3/3773 ,  C11D3/3776 ,  C11D3/378 ,  C11D3/3942 ,  C11D3/3947 ,  C11D3/3953 ,  C11D3/3956 ,  C11D3/48

Abstract: The invention relates to compositions and methods of treatment employing compositions comprising polyelectrolyte complexes. The compositions include a water-soluble first polyelectrolyte bearing a net cationic charge or capable of developing a net cationic charge and a water-soluble second polyelectrolyte bearing a net anionic charge or capable of developing a net anionic charge. The total polyelectrolyte concentration of the first solution is at least 110 millimolar. The composition is free of coacervates, precipitates, latex particles, synthetic block copolymers, silicone copolymers, cross-linked poly(acrylic) and cross-linked water-soluble polyelectrolyte. The composition may be a concentrate, to be diluted prior to use to treat a surface.

公开(公告)号：US09593299B2

公开(公告)日：2017-03-14

申请号：US15269085

申请日：2016-09-19

Applicant: THE CLOROX COMPANY

Inventor： David R. Scheuing ,  William L. Smith ,  Michael Kinsinger ,  Jared Heymann

IPC: C07B57/00 ,  A01N33/12 ,  C11D17/04 ,  A01N59/00 ,  A01N59/16 ,  B08B1/00 ,  C11D3/37 ,  C11D3/48 ,  A61L15/10 ,  A61L15/46

CPC classification number: C11D17/049 ,  A01N33/12 ,  A01N37/02 ,  A01N43/16 ,  A01N43/36 ,  A01N59/00 ,  A01N59/16 ,  A61L15/10 ,  A61L15/46 ,  B08B1/006 ,  C07B57/00 ,  C11D3/3723 ,  C11D3/3757 ,  C11D3/3776 ,  C11D3/378 ,  C11D3/48 ,  A01N25/10 ,  A01N25/22 ,  A01N25/24

Abstract: The present invention relates to aqueous compositions of associative polyelectrolyte complexes (PECs), optionally containing surfactants, biocidal agents and/or oxidants, which can provide a cleaning benefit and surface protection to treated articles including reduced soiling tendency, reduced cleaning effort and improved soil repellancy, as well as providing bacteriostatic properties to treated surfaces that thereby gain resistance to water, environmental exposure and microbial challenge. Treatment means and compositions are provided that employ associative polyelectrolyte complexes formed by combining a water soluble cationic first polyelectrolyte with a water soluble second polyelectrolyte bearing groups of opposite charge to the first polyelectrolyte under suitable mixing conditions and at least one oxidant selected from the group: alkaline metal salts and/or alkaline earth metal salts of hypochlorous acid, hypochlorous acid, solubilized chlorine, any source of free chlorine, acidic sodium chlorite, active chlorine generating compound and any combinations or mixtures thereof. Also provided are means to form stable associative polyelectrolyte complexes with at least one oxidant in aqueous solutions having R values from about 0.10 to 20.

Abstract translation: 本发明涉及可选地含有表面活性剂，杀生物剂和/或氧化剂的缔合聚电解质复合物（PEC）的含水组合物，其可以为处理物品提供清洁效果和表面保护，包括减少污染趋势，降低清洁力和改善防污性 ，以及为处理的表面提供抑菌性能，从而获得对水的耐受性，环境暴露和微生物挑战。 提供了处理装置和组合物，其使用通过在适合的混合条件下将水溶性阳离子第一聚电解质与带有相反电荷的水溶性第二聚电解质带入基团的第一聚电解质组合形成的缔合聚电解质复合物和至少一种选自以下的氧化剂：碱 次氯酸，次氯酸，溶解氯，任何游离氯源，酸性亚氯酸钠，活性氯产生化合物的金属盐和/或碱土金属盐及其任何组合或混合物。 还提供了在水溶液中形成具有约0.10至20的R值的至少一种氧化剂的稳定的缔合聚电解质络合物的方法。