公开(公告)号：US5319124A

公开(公告)日：1994-06-07

申请号：US023303

申请日：1993-02-26

Applicant: Erich Wolters ,  Heinz Landscheidt ,  Alexander Klausener ,  Lothar Puppe

Inventor： Erich Wolters ,  Heinz Landscheidt ,  Alexander Klausener ,  Lothar Puppe

IPC: B01J21/16 ,  C07C68/00 ,  C07C69/96

CPC classification number: C07C68/00 ,  Y02P20/582

Abstract: Dialkyl carbonates can be prepared by the reaction of carbon monoxide with alkyl nitrites in a continuous gas phase reaction, using a platinum metal catalyst on an amorphous alumosilicate having a content of 30-80 atom% Al, based on the sum of Al and Si, as a support, which catalyst may optionally comprise additional material of a compound of antimony, bismuth, aluminium, copper, vanadium, niobium, tantalum, tin, iron, cobalt, nickel or a mixture of a plurality of these, and hydrogen halide being added in the course of the reaction intermittently or continuously. In this reaction, the dialkyl carbonates are formed with almost quantitative selectivity; the corresponding dialkyl oxalates cannot be detected in most cases.

Abstract translation: 碳酸二烷基酯可以通过一氧化碳与亚硝酸烷基酯在连续气相反应中的反应来制备，使用铂金属催化剂，其含量为30-80原子％Al的无定形铝硅酸盐，基于Al和Si的总和， 作为载体，该催化剂可以任选地包含锑，铋，铝，铜，钒，铌，钽，锡，铁，钴，镍或其中多个的混合物和添加的卤化氢的化合物的附加材料 在反应过程中间歇或连续。 在该反应中，以几乎定量的选择性形成碳酸二烷基酯; 在大多数情况下不能检测到相应的草酸二烷基酯。

公开(公告)号：US5068434A

公开(公告)日：1991-11-26

申请号：US301929

申请日：1989-01-25

Applicant: Gunter Klug ,  Hans-Josef Buysch ,  Lothar Puppe

Inventor： Gunter Klug ,  Hans-Josef Buysch ,  Lothar Puppe

IPC: B01J29/06 ,  B01J29/40 ,  B01J29/80 ,  C07B61/00 ,  C07C67/00 ,  C07C209/00 ,  C07C209/14 ,  C07C209/18 ,  C07C211/48 ,  C07C211/52 ,  C07C213/02 ,  C07C217/84

CPC classification number: C07C209/18

Abstract: N-alkylated anilines can be prepared by reaction of anilines with lower alcohols or dialkyl ethers at elevated temperature and in the presence of zeolite catalysts of the pentasil type containing protons and having an SiO.sub.2 /Al.sub.2 O.sub.3 ratio of at least 60.

Abstract translation: N-烷基化苯胺可以通过苯胺与低级醇或二烷基醚在升高的温度下反应，并且在含有质子的五元素类型的沸石催化剂存在下，SiO 2 / Al 2 O 3的比例至少为60来制备。

公开(公告)号：US5030770A

公开(公告)日：1991-07-09

申请号：US375751

申请日：1989-07-05

Applicant: Peter Wimmer ,  Hans-Josef Buysch ,  Lothar Puppe

Inventor： Peter Wimmer ,  Hans-Josef Buysch ,  Lothar Puppe

IPC: B01J29/06 ,  C07B61/00 ,  C07C37/14 ,  C07C39/06

CPC classification number: C07C37/14

Abstract: Thymol can be prepared by reaction of m-cresol with propene at elevated temperature and at atmospheric to superatmospheric pressure by using wide- and medium-pored zeolites which have a pore diameter of at least 5 .ANG. as heterogeneous catalysts.

Abstract translation: 通过使用孔径至少为5 ANGSTROM的多孔和中等沸石作为非均相催化剂，可以通过间甲酚与丙烯在升高的温度和大气压至超大气压下反应制备百里酚。

公开(公告)号：US4960943A

公开(公告)日：1990-10-02

申请号：US318088

申请日：1989-03-02

Applicant: Artur Botta ,  Hans-Josef Buysch ,  Lothar Puppe ,  Dieter Arlt

Inventor： Artur Botta ,  Hans-Josef Buysch ,  Lothar Puppe ,  Dieter Arlt

IPC: C07C45/45 ,  C07B61/00 ,  C07C45/00 ,  C07C45/46 ,  C07C49/84 ,  C07C67/00

CPC classification number: C07C49/84 ,  C07C45/46

Abstract: Phenylketones etherified in the 4-position can be prepared by reaction of aromatic ethers which have a free 4-position with acylating agents, the acylation being carried out in the presence of zeolite catalysts having pore sizes of at least 5 .ANG..

Abstract translation: 醚化4-位的苯基酮可以通过使具有游离4-位的芳族醚与酰化剂的反应制备，酰化在孔径至少为5安士的沸石催化剂的存在下进行。

公开(公告)号：US4950817A

公开(公告)日：1990-08-21

申请号：US318087

申请日：1989-03-02

Applicant: Artur Botta ,  Hans-Josef Buysch ,  Lothar Puppe

Inventor： Artur Botta ,  Hans-Josef Buysch ,  Lothar Puppe

IPC: B01J29/06 ,  B01J29/18 ,  B01J29/40 ,  B01J29/60 ,  B01J29/65 ,  B01J29/86 ,  C07B31/00 ,  C07B39/00 ,  C07B61/00 ,  C07C17/00 ,  C07C17/12 ,  C07C17/20 ,  C07C25/18 ,  C07C27/00 ,  C07C37/62 ,  C07C39/15 ,  C07C41/00 ,  C07C41/22 ,  C07C43/225 ,  C07C67/00

CPC classification number: C07C17/12

Abstract: 4,4'-dihalobiphenyls can be prepared by catalyzed halogenation of biphenyls with halogenating agents, the catalysts used being zeolites having pore sizes of at least 5 .ANG..

Abstract translation: 4,4'-二卤代联苯可以通过用卤化剂催化联苯联苯来制备，所用的催化剂是孔径至少为5安士的沸石。

公开(公告)号：US4950312A

公开(公告)日：1990-08-21

申请号：US192441

申请日：1988-05-11

Applicant: Lothar Puppe ,  Gerhard Reiss

Inventor： Lothar Puppe ,  Gerhard Reiss

IPC: B01D53/04 ,  B01D53/047 ,  B01J20/18 ,  C01B13/02 ,  C01B39/14

CPC classification number: B01D53/02 ,  B01J20/183 ,  B01D2253/108 ,  B01D2253/302 ,  B01D2253/306 ,  B01D2256/12 ,  B01D2257/102 ,  B01D2259/403 ,  B01D53/0446 ,  B01D53/047 ,  Y10S423/24 ,  Y10S95/902

Abstract: A SiO.sub.2 -bound, substantially carbonate-free, calcium-containing zeolite A granulate in which the calcium content is 0.4 to 1 mole CaO/mole Al.sub.2 O.sub.3 and a process for the production such SiO.sub.2 -bound calcium exchanged zeolite A granulate in a CO.sub.2 -free atmosphere at temperatures of 350.degree. C. to 700.degree. C. The SiO.sub.2 -bound zeolite granulate A being useful as an adsorbent in the recovery of oxygen by the pressure change adsorption process.

Abstract translation: 一种SiO 2结合的，基本上不含碳酸盐的含钙沸石A，其中钙含量为0.4〜1摩尔CaO /摩尔Al 2 O 3的颗粒，以及生产这种SiO 2结合的钙交换沸石A颗粒在无CO2的方法 气氛在350〜700℃的温度范围内。结合SiO 2的沸石颗粒A可用作吸附剂，通过压力变化吸附过程回收氧气。