公开(公告)号：US20150349258A1

公开(公告)日：2015-12-03

申请号：US14722409

申请日：2015-05-27

Applicant: PHILLIPS 66 COMPANY

Inventor： Kathy Woody ,  Hui Huang ,  Ting He

IPC: H01L51/00 ,  C08G75/06

CPC classification number: H01L51/0036 ,  H01L51/0043 ,  H01L51/4253 ,  Y02E10/549

Abstract: A polymer having two different sets of repeat units consisting essentially of: Additionally, in the polymer R1 can be selected from the group consisting of alkyl group, alkoxy group, aryl groups and combinations thereof. In the polymer, n and m can be greater than 1.In the polymer, x and y can be different from each other and independently selected from the group consisting of: an alkoxy group, a substituted alkoxy group, an aryl group, an alkyl group, a substituted alkyl group, where y=1-3, where y=0-12, where R2 is selected from the group consisting of H, alkyl groups, and aryl groups, where R3 is selected from the group consisting of H, alkyl groups, and aryl groups, where R4 and R5 are independently selected from the group consisting of H, alkyl groups, and aryl groups, —NR6R7 where R6 and R7 are independently selected from the group consisting of H, alkyl groups, and aryl groups.

Abstract translation: 具有两个不同组的重复单元的聚合物，其基本上由以下组成：另外，在聚合物R1中可以选自烷基，烷氧基，芳基及其组合。 在聚合物中，n和m可以大于1.在聚合物中，x和y可以彼此不同并且独立地选自：烷氧基，取代的烷氧基，芳基，烷基 基团，取代的烷基，其中y = 1-3，其中y = 0-12，其中R 2选自H，烷基和芳基，其中R 3选自H， 烷基和芳基，其中R 4和R 5独立地选自H，烷基和芳基，-NR 6 R 7，其中R 6和R 7独立地选自H，烷基和芳基 。

公开(公告)号：US20150344608A1

公开(公告)日：2015-12-03

申请号：US14722864

申请日：2015-05-27

Applicant: PHILLIPS 66 COMPANY ,  SOLARMER ENERGY, INC.

Inventor： Wei Wang ,  Jun Yang ,  Chenjun Shi ,  Christopher Daeffler ,  Janice Hawkins ,  Yue Wu ,  Ting He ,  Hui Huang ,  Amit Palkar ,  Kathy Woody ,  Joe Bullock

IPC: C08F228/06 ,  H01L51/00

CPC classification number: C08F228/06 ,  H01L51/0036 ,  H01L51/0043 ,  Y02E10/549

Abstract: A polymer having two different sets of repeat units consisting essentially of: In this polymer, R1, R2, R3 and R4 can be independently selected from the group consisting of alkyl group, alkoxy group, aryl groups and combinations thereof. Also the combination of R1, R2, R3 and R4 are not all identical and n and o are greater than 1.

Abstract translation: 具有两个不同组的重复单元的聚合物基本上由以下组成：在该聚合物中，R 1，R 2，R 3和R 4可以独立地选自烷基，烷氧基，芳基及其组合。 R1，R2，R3和R4的组合也不完全相同，n和o大于1。

公开(公告)号：US20140151657A1

公开(公告)日：2014-06-05

申请号：US14084358

申请日：2013-11-19

Applicant: Solarmer Energy, Inc. ,  Phillips 66 Company

Inventor： Wei Wang ,  Chenjun Shi ,  Ruby Chen ,  Jun Yang ,  Yue Wu ,  Hui Huang ,  Kathy Woody ,  Joe Bullock ,  Amit Palkar ,  Ting He

IPC: H01L51/42

CPC classification number: H01L51/0043 ,  H01L51/0036 ,  H01L51/0047 ,  H01L51/4253 ,  Y02E10/549

Abstract: Compositions, synthesis and applications for furan, thiophene and selenophene derivatized benzo[1,2-b:3,4-b′]dithiophene(BDT)-thienothiophene (BDT-TT) based polymers, namely, poly[(4,8-bis(5-(2-ethyhexyl)selenophen-2-yl)-benzo[1,2-b;4,5-b′]dithiophene)-2,6-diyl-alt-(4-(2-ethylhexanoyl)-3-fluorothieno[3,4-b]thiophene)-2-6-diyl (CS-15), poly[(4,8-bis(5-(2-ethyhexyl)selenophen-2-yl)-benzo[1,2-b;4,5-b′]dithiophene)-2,6-diyl-alt-(4-(2-ethylhexyl)-3-fluorothieno[3,4-b]thiophene)-2-carboxylate-2-6-diyl (CS-16), poly[(4,8-bis(5-(2-ethyhexyl)furan-2-yl)-benzo[1,2-b;4,5-b′]dithiophene)-2,6-diyl-alt-(4-(2-ethylhexyl)-3-fluorothieno[3,4-b]thiophene)-2-carboxylate-2-6-diyl (CS-18) and poly[(4,8-bis(5-hexylfuran-2-yl)-benzo[1,2-b;4,5-b′]dithiophene)-2,6-diyl-alt-(4-(2-ethylhexanoyl)-3-fluorothieno[3,4-b]thiophene)-2-6-diyl (CS-24) are disclosed. Further, an organic solar cell constructed of a derivatized benzo[1,2-b:3,4-b′]dithiophene(BDT)-thienothiophene (BDT-TT) based polymer is discussed.

Abstract translation: 呋喃，噻吩和硒吩衍生的苯并[1,2-b：3,4-b']二噻吩（BDT） - 噻吩并噻吩（BDT-TT）基聚合物的组合物，合成和应用，即聚[（4,8- （5-（2-乙基己基）硒吩-2-基） - 苯并[1,2-b; 4,5-b']二噻吩）-2,6-二基-alt-（4-（2-乙基己酰基） -3-氟噻吩并[3,4-b]噻吩）-2-6-二基（CS-15），聚[（4,8-双（5-（2-乙基己基）硒吩-2-基） 1,2-b; 4,5-b']二噻吩）-2,6-二基-alt-（4-（2-乙基己基）-3-氟噻吩并[3,4-b]噻吩） （CS-16），聚[（4,8-双（5-（2-乙基己基）呋喃-2-基） - 苯并[1,2-b; 4,5-b']二噻吩 ）-2,6-二基-2-（4-（2-乙基己基）-3-氟噻吩并[3,4-b]噻吩）-2-羧酸酯-2,6-二基（CS-18）和聚[ 4,5-双（5-己基呋喃-2-基） - 苯并[1,2-b; 4,5-b']二噻吩）-2,6-二基-alt-（4-（2-乙基己酰基） 公开了3-氟噻吩并[3,4-b]噻吩）-2-6-二基（CS-24）。 此外，讨论了由衍生化的苯并[1,2-b：3,4-b']二噻吩（BDT） - 噻吩并噻吩（BDT-TT）基聚合物构成的有机太阳能电池。

公开(公告)号：US11716895B2

公开(公告)日：2023-08-01

申请号：US17238430

申请日：2021-04-23

Applicant: PHILLIPS 66 COMPANY

Inventor： Hualong Pan ,  Kathy Woody ,  Brian Worfolk ,  Taeshik Earmme

IPC: H10K85/10 ,  C08G61/12 ,  H10K30/30

CPC classification number: H10K85/113 ,  C08G61/123 ,  C08G61/126 ,  H10K85/151 ,  C08G2261/122 ,  C08G2261/124 ,  C08G2261/146 ,  C08G2261/149 ,  C08G2261/1412 ,  C08G2261/1424 ,  C08G2261/314 ,  C08G2261/3223 ,  C08G2261/3243 ,  C08G2261/3246 ,  C08G2261/414 ,  C08G2261/91 ,  H10K30/30 ,  Y02E10/549

Abstract: A random copolymer comprising the monomer units A, B and C. In this random copolymer A comprises




B comprises





and C comprises an aryl group. Additionally, R1, R2, R3 and R4 are side chains independently selected from the group consisting of: H, Cl, F, CN, alkyl, alkoxy, alkylthio, ester, ketone and aryl groups. X1 and X2 are independently selected from the group consisting of: H, Cl, F, CN, alkyl, alkoxy, ester, ketone, amide and aryl groups.

公开(公告)号：US11702413B2

公开(公告)日：2023-07-18

申请号：US17002805

申请日：2020-08-26

Applicant: PHILLIPS 66 COMPANY

Inventor： Hualong Pan ,  Kathy Woody ,  Brian J. Worfolk

IPC: C07D417/14

CPC classification number: C07D417/14

Abstract: A comonomer comprising:




wherein W is selected from the group consisting of: S, Se, O, and N-Q; and Q is selected from the group consisting of: a straight-chain or branched carbyl, silyl, or hydrocarbyl, a branched or cyclic alkyl with 1 to 30 atoms, a fused substituted aromatic ring, and a fused unsubstituted aromatic ring. In this comonomer, A and B are independently selected from the group consisting of: H, Br, an aryl group, and a heteroaryl group.

公开(公告)号：US11437580B2

公开(公告)日：2022-09-06

申请号：US17002990

申请日：2020-08-26

Applicant: PHILLIPS 66 COMPANY

Inventor： Hualong Pan ,  Kathy Woody

IPC: H01L51/00 ,  H01L51/50

Abstract: A polymer comprising wherein Ar1 and Ar2 are optional and either the same or different and independently selected from an aryl group or an heteroaryl group. In this polymer, W is selected from the group consisting of: S, Se, O, and N-Q; and Q is selected from the group consisting of: a straight-chain or branched carbyl, silyl, or hydrocarbyl, a branched or cyclic alkyl with 1 to 30 atoms, a fused substituted aromatic ring, and a fused unsubstituted aromatic ring. Additionally, in the polymer, R4 and R5 are selected from the group consisting of: a straight-chain or branched carbyl, silyl, or hydrocarbyl, a branched or cyclic alkyl with 1 to 30 atoms, a fused substituted aromatic ring, and a fused unsubstituted aromatic ring; and x+y=1.

公开(公告)号：US20210253797A1

公开(公告)日：2021-08-19

申请号：US17238595

申请日：2021-04-23

Applicant: PHILLIPS 66 COMPANY

Inventor： Hualong Pan ,  Kathy Woody ,  Brian Worfolk ,  Taeshik Earmme

IPC: C08G75/06

Abstract: A random copolymer comprising the monomer unit C and at least two out of the three monomer units A, B, and D. In the random copolymer A comprises B comprises D comprises and C comprises an aryl group. Additionally, R1 R2, R3, R4, R3′, and R4′ are side chains independently selected from the group consisting of: H, Cl, F, CN, alkyl, alkoxy, alkylthio, ester, ketone and aryl groups and wherein R3 and R3′ or R4 and R4′ are not equal.

公开(公告)号：US20210242407A1

公开(公告)日：2021-08-05

申请号：US17238430

申请日：2021-04-23

Applicant: PHILLIPS 66 COMPANY

Inventor： Hualong Pan ,  Kathy Woody ,  Brian Worfolk ,  Taeshik Earmme

IPC: H01L51/00 ,  C08G61/12

Abstract: A random copolymer comprising the monomer units A, B and C. In this random copolymer A comprises B comprises and C comprises an aryl group. Additionally, R1 R2, R3 and R4 are side chains independently selected from the group consisting of: H, Cl, F, CN, alkyl, alkoxy, alkylthio, ester, ketone and aryl groups. X1 and X2 are independently selected from the group consisting of: H, Cl, F, CN, alkyl, alkoxy, ester, ketone, amide and aryl groups.

公开(公告)号：US20210066606A1

公开(公告)日：2021-03-04

申请号：US17002977

申请日：2020-08-26

Applicant: PHILLIPS 66 COMPANY

Inventor： Hualong Pan ,  Kathy Woody

IPC: H01L51/00 ,  C08G61/12

Abstract: A method of forming a polymer, the method begins by combining 4,7-bis(5-bromo-4-alkylthiophen-2-yl)-5-chloro-6-fluorobenzo[c][1,2,5]thiadiazole, [4-alkyl-5-[5-(trimethylstannyl)thiophen-2-yl]thiophen-2-yl]trimethylstannane, (3,3′-difluoro-[2,2′-bithiophene]-5,5′-diyl)bis(trimethylstannane), Pd2dba3 and P(o-tol)3 to form the polymer: In this polymer R1 and R2 are independently selected from the group consisting of a straight-chain or branched carbyl, silyl, or hydrocarbyl, a branched or cyclic alkyl with 1 to 30 atoms, a fused substituted aromatic ring, and a fused unsubstituted aromatic ring; and the ratio of x is between 0.6 to 0.8 and y is between 0.2 and 0.4.

公开(公告)号：US20210066604A1

公开(公告)日：2021-03-04

申请号：US17002827

申请日：2020-08-26

Applicant: PHILLIPS 66 COMPANY

Inventor： Hualong Pan ,  Kathy Woody ,  Brian J. Worfolk

IPC: H01L51/00 ,  C08G61/12

Abstract: An organic compound comprising: In this organic compound, W is selected from the group consisting of: S, Se, O, and N-Q; and Q is selected from the group consisting of: a straight-chain or branched carbyl, silyl, or hydrocarbyl, a branched or cyclic alkyl with 1 to 30 atoms, a fused substituted aromatic ring, and a fused unsubstituted aromatic ring. Additionally, in this organic compound Ar1 and Ar2 are independently selected from the group selected from: H, an aryl group, and a heteroaryl group.