Abstract:
An alteration of the traditional zinc/zinc-amalgam reduction procedure which eliminates both the hazardous mercury and dangerous hydrogen gas generation. In order to avoid the presence of water and hydrated protons in the working solution, which can oxidize Eu2+ and cause hydrogen gas production, a process utilizing methanol as the process solvent is described. While methanol presents some flammability hazard in a radiological hot cell, it can be better managed and is less of a flammability hazard than hydrogen gas generation.
Abstract:
Provided is an apparatus for recovering amines from amine-containing waste water generated in power stations, etc., and regenerating a cation exchange resin. The apparatus includes: a cation exchange resin layer capturing amines from amine-containing waste water and eluting the amines therefrom; a degassing tower degassing the eluted amines; a vacuum pump connected to the degassing tower; and a condensation and cooling tower condensing the degassed amines at a temperature of −33° C. or lower, wherein the amines captured in the cation exchange resin layer are eluted by injecting a strong acidic solution, while the resin is regenerated, and the amines eluted by the strong acidic solution is subjected to vacuum degassing and then recovered. Provided also is a method for recovering amines and regenerating a cation exchange resin using the apparatus. The apparatus and method for recovering amines and regenerating a cation exchange resin improve the quality of effluent water from power stations, etc., and increase the cost-efficiency through the recycle of amines.
Abstract:
A diamine absorbent that contains heat stable salts is regenerated using an ion exchange process wherein the concentration of heat stable salts in the feed stream provided to the cation exchange unit is limited.
Abstract:
Disclosed is a versatile multi-use high water recovery process that integrates the use of water purification membranes including reverse osmosis and nanofiltration with ion exchange water softening resins in a number of configurations that optimize operation and achieve maximum membrane permeate recoveries while eliminating the use of fresh water, sodium chloride and other chemicals needed to regenerate the IX resin. The invention provides process mobility and flexibility that enable selection of optimum process configurations and features to address variability in the Influent Water quality.
Abstract:
The present invention provides a method for purifying or softening water comprising: passing a specific volume of feedwater through at least one service column comprising a strong acid cationic exchange resin capable of binding divalent cations that are present in the feedwater, wherein the loading of the divalent cations on the resin is restricted to about 1 to 25% of the available ion exchange sites on the resin, and the total dissolved solids in the feedwater is greater than 100 mg/l; feeding the water exiting the service column to a reverse osmosis membrane or a nanofiltration membrane to produce permeate water stream and a reject water stream; and passing all or some of the volume of the reject stream corresponding the specific volume of feedwater through at least one off-line column capable of binding monovalent cations; wherein the chemical equivalent ratio of monovalent to divalent cations in the water exiting the service column is greater than 20 to 1; wherein no external source of regenerant salt is used. The inventive method allows for multiple softening/regeneration cycles so that steady state hardness leakage is achieved that is lower than obtainable with conventional ion exchange softening systems.
Abstract:
Provided is a method for high concentration cation exchange metathesis of divalent ions such as calcium with univalent ions such as sodium or potassium. Due to the difference between ionic valences between the exchanged ions, the provided process behavior is strongly dependent upon the selection of resin properties and to total solution normality. A combination of resin properties and solution normality is provided to achieve the cation exchange.
Abstract:
A method is described that relates to reducing amounts of regenerant waste or increasing the concentration of regenerant waste from ion exchange processes. A method is described that may allow a batch ion exchange process to compete on these factors with continuous or simulated continuous ion exchange processes, and/or to improve the efficiency in operation continuous or simulated continuous ion exchange processes. A specific application addressed is the treatment of water in the Coal Bed Methane Process.
Abstract:
We disclose a method of extracting an alcohol or furan from a predominantly liquid stream comprising the alcohol or furan, comprising removing cations from the predominantly liquid stream comprising the alcohol or furan, using a cation-exchange resin; removing anions from the predominantly liquid stream comprising the alcohol or furan, using an anion-exchange resin; and recovering alcohol or furan from the predominantly liquid stream comprising the alcohol or furan, using either a vapor permeation membrane, a perevaporation process, or both.
Abstract:
In the method for separating and purifying histidine from a culture containing the amino acid, the culture containing histidine and microbial cells is charged onto the top of a column filled with a carrier particle whose particle size is 350 μm or more and which has an ability to adsorb histidine and then an eluent is passed through the column whereby accomplishing the separation and purification of histidine, and preferably in the step mentioned above, a strong acid cation exchange resin is employed as a carrier particle whereby accomplishing the separation and purification of histidine.
Abstract:
A process is described wherein a surface, for example the exterior surface of a vehicle, is contacted with a cleaning composition capable of rendering the surface treated hydrophilic and then rinsed with purified rinse water. Preferably the process also involves a pre-wetting step, wherein the surface is rinsed with water prior to being contacted with the cleaning composition, and/or an additional rinsing step, wherein the surface is rinsed with unpurified water prior to rinsing with the purified rinse water.