Microporous plastic member such as a battery separator and process for
making same
    54.
    发明授权
    Microporous plastic member such as a battery separator and process for making same 失效
    微孔塑料部件,如电池分离器及其制造方法

    公开(公告)号:US4153760A

    公开(公告)日:1979-05-08

    申请号:US514628

    申请日:1974-10-15

    Abstract: A process for producing a microporous plastic member useful as a battery separator which comprises(a) forming a coherent dough by mixing a vinyl chloride resin with a plasticizing amount of a first solvent and with finely divided particles of a filler which contains volatilizable constituent releasable therefrom by heating and which shrinks substantially and irreversibly upon release of said volatilizable constituent therefrom, an example of which is hydrated silica;(b) forming the solvent-containing dough into a shaped member;(c) extracting the first solvent from the member before any substantial evaporation of solvent occurs by contacting it with a second solvent in a liquid bath at a temperature substantially below the boiling point of any liquid present, the second solvent being one which is capable of dissolving the first solvent without dissolving the resin and the filler, thereby deplasticizing the member by extractively removing the first solvent from the member; and(d) thereafter heating the member at an elevated temperature but below the softening point of the resin until the filler is shrunk within the member by release of its volatilizable content.

    Abstract translation: 一种制造用作电池隔板的微孔塑料构件的方法,其包括(A)通过混合具有第一溶剂的增塑剂的乙烯基氯树脂和与其可释放的易挥发性成分的填充物的精细分散的颗粒形成相互缔合的方法 通过加热,可以大幅度地收缩并释放其中的挥发性成分,这是水合二氧化硅的一个例子; (B)将包含溶剂的成分形成成型成员; (C)在通过任何液体现象的沸点以下大量温度下在液体温度下与第二溶剂接触溶解剂的任何物质之前,从成员中提取第一溶剂,第二溶剂为可溶于 解决第一种溶剂,而不会破坏树脂和填料,通过从会员中抽出第一溶剂,彻底清除会员; 和(D)在高温下加热会员,然后在树脂的强度点之下加热会员,填充物通过释放其易挥发性内容而在会员中掉落。

    Manufacture of a porous polymeric sheet
    58.
    发明授权
    Manufacture of a porous polymeric sheet 失效
    多孔聚合物薄膜的制造

    公开(公告)号:US3654066A

    公开(公告)日:1972-04-04

    申请号:US3654066D

    申请日:1969-04-25

    Applicant: KURARAY CO

    Abstract: A POROUS POLYMERIC SHEET HAVING A SPECFIC GRAVITY OF LESS THAN 0.7 AND A THICKNESS OF 0.05 TO 2.0 MM. AND CONTAINING PORES INCLINED AT AN ANGLE OF LESS THAN 80* AGAINST THE PLANE OF THE SHEET AND HAVING A LENGTH OF 0.03 TO 10 MM. A SHEET MATERIAL COMPRISING SAID POROUS POLYMERIC SHEET AND A SUBSTRATE BOUND TO THE LOWER SURFACE OF SAID POROUS POLYMERIC SHEET. SAID POROUS POLYMERIC SHEET IS PRODUCED BY IMMERSING A POLYMER SOLUTION APPLIED TO A SUPPORT INTO A COAGULATION BATH UNDER A CONDITION OF RAPID COAGULATION RAPIDLY THE UPPER PORTION OF THE SOLUTION AND TO FORM MACROPORES IN THE INNER PORTION; STRESSING THE UPPER PORTION IN TRANSVERSE DIRECTION, THAT IS, A DIRECTION PARALLEL TO THE PLANE OF THE SUPPORT, IN THE BATH TO SHIFT THE UPPER PORTION TO TRANSVERSE DIRECTION AND TO INCLINE THE PORES FORMED; TREATING FURTHER THE LAYER WITH THE BATH TO COMPLETE THE COAGULATION, THEREBY FORMING POROUS STRUCTURE CONTAINING PORES INCLINED AT AN ANGLE OF LESS THAN 80* AGAINST THE PLANE; AND PEELING OFF THE RESULTING POROUS POLYMERIC SHEET FROM THE SUPPORT.

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