Microporous material exhibiting low alkali metal content
    51.
    发明授权
    Microporous material exhibiting low alkali metal content 失效
    显示低碱金属含量的微孔材料

    公开(公告)号:US5583171A

    公开(公告)日:1996-12-10

    申请号:US221203

    申请日:1994-03-31

    Abstract: Microporous material comprising water insoluble thermoplastic organic polymer and particulate amorphous precipitated silica not only exhibits low particulate emissions during handling and use, but also has a low extactable alkali metal content. Microporous material having these characteristics is especially useful in clean rooms where electronic devices such as integrated circuits are manufactured. Such microporous material may be produced by employing amorphous precipitated silica particles having low alkali metal content as all or a substantial proportion of the amorphous precipitated silica particles constituting the microporous material.

    Abstract translation: 包含水不溶性热塑性有机聚合物和颗粒状无定形沉淀二氧化硅的微孔材料在处理和使用过程中不仅表现出低的颗粒排放,而且具有低的可交换的碱金属含量。 具有这些特性的微孔材料在制造诸如集成电路的电子设备的洁净室中特别有用。 这样的微孔材料可以通过使用具有低碱金属含量的无定形沉淀二氧化硅颗粒作为构成微孔材料的全部或相当大比例的无定形沉淀二氧化硅颗粒来制备。

    Rigid materials having high surface area and low density
    52.
    发明授权
    Rigid materials having high surface area and low density 失效
    刚性材料表面积高,密度低

    公开(公告)号:US5328939A

    公开(公告)日:1994-07-12

    申请号:US54114

    申请日:1993-04-27

    Applicant: Tammy Smith

    Inventor: Tammy Smith

    Abstract: This invention relates to highly porous, crosslinked bodies derived from nitrogen-containing polymers, and a process of producing the porous bodies which comprises dissolving a nitrogen-containing polymer to form a gel, ionically crosslinking the gel, and covalently further crosslinking the ionically crosslinked gel body.

    Abstract translation: 本发明涉及由含氮聚合物衍生的高度多孔的交联体,以及制造多孔体的方法,该方法包括将含氮聚合物溶解以形成凝胶,使凝胶离子交联,并共价进一步交联离子交联凝胶 身体。

    Microporous sheet material, method of making and articles made therewith
    57.
    发明授权
    Microporous sheet material, method of making and articles made therewith 失效
    微孔板材,制造方法和制成的制品

    公开(公告)号:US4539256A

    公开(公告)日:1985-09-03

    申请号:US583288

    申请日:1984-02-28

    Inventor: Gene H. Shipman

    Abstract: A method of making a microporous material is provided which comprises the steps of melt blending crystallizable thermoplastic polymer with a compound which is miscible with the thermoplastic polymer at the melting temperature of the polymer but phase separates on cooling at or below the crystallization temperature of the polymer, forming a shaped article of the melt blend, cooling the shaped article to a temperature at which the polymer crystallizes to cause phase separation to occur between the thermoplastic polymer and the compound to provide an article comprising a first phase comprising particles of crystallized thermoplastic polymer in a second phase of said compound, orienting the article in at least one direction to provide a network of interconnected micropores throughout. The microporous article comprises about 30 to 80 parts by weight crystallizable thermoplastic polymer and about 70 to 20 parts by weight of the compound. The oriented article has a microporous structure characterized by a multiplicity of spaced randomly dispersed, equiaxed, non-uniform shaped particles of the thermoplastic polymer which are coated with the compound. Adjacent thermoplastic particles within the article are connected to each other by a plurality of fibrils consisting of the thermoplastic polymer. The fibrils radiate in three dimensions from each particle. The compound may be removed from the sheet article. e.g., by solvent extraction. The preferred article is a sheet material.

    Abstract translation: 提供了一种制备微孔材料的方法,其包括以下步骤:将可结晶的热塑性聚合物与在聚合物的熔融温度下与热塑性聚合物混溶的化合物熔融共混,但是在聚合物的结晶温度或低于聚合物的结晶温度下冷却时相分离 ,形成熔融共混物的成形制品,将成型制品冷却至聚合物结晶的温度,使得在热塑性聚合物和化合物之间发生相分离,以提供包含第一相的制品,该第一相包含结晶的热塑性聚合物颗粒 所述化合物的第二阶段,使制品沿至少一个方向定向以提供整个相互连接的微孔的网络。 该微孔制品包含约30至80重量份的可结晶的热塑性聚合物和约70至20重量份的该化合物。 定向制品具有微孔结构,其特征在于涂覆有化合物的多个间隔开的无规分散的等轴不均匀成型的热塑性聚合物颗粒。 制品内相邻的热塑性颗粒通过由热塑性聚合物组成的多个原纤维相互连接。 原纤维从每个颗粒三维辐射。 化合物可以从片材制品中除去。 例如通过溶剂萃取。 优选的物品是片材。

    Microporous products
    58.
    发明授权
    Microporous products 失效
    微孔产品

    公开(公告)号:US4519909A

    公开(公告)日:1985-05-28

    申请号:US97474

    申请日:1979-11-23

    Abstract: Novel microporous polymers in forms ranging from films to blocks and intricate shapes from synthetic thermoplastic polymers, such as, olefinic, condensation, and oxidation polymers, are disclosed. In one embodiment the microporous polymers are characterized by a relatively homogeneous, three-dimensional cellular structure having cells connected by pores of smaller dimension. Also disclosed are microporous polymer products which contain relatively large amounts of functionally useful liquids and behave as solids.

    Abstract translation: 公开了从合成热塑性聚合物(例如烯烃,缩合和氧化聚合物)的薄膜到块状和复杂形状的新型微孔聚合物。 在一个实施方案中,微孔聚合物的特征在于具有通过较小尺寸的孔连接的细胞的相对均匀的三维细胞结构。 还公开了含有相对大量功能上有用的液体并表现为固体的微孔聚合物产品。

    Method for manufacturing microporous membrane
    59.
    发明授权
    Method for manufacturing microporous membrane 失效
    微多孔膜的制造方法

    公开(公告)号:US4466931A

    公开(公告)日:1984-08-21

    申请号:US405226

    申请日:1982-08-05

    Inventor: Gerald B. Tanny

    Abstract: The starting materials for the practice of the present invention are (1) one or more organic monomers or oligomers which upon irradiation very rapidly undergo a polymerization reaction to form a solid polymer; and (2) a liquid vehicle in which the one or more organic monomers or oligomers are soluble but in which the polymer formed is insoluble. For the manufacture of microporous membrane in accordance with the invention the monomers or oligomers are dissolved in the liquid vehicle, the resulting solution is formed into a thin layer, and the thin layer of the solution is then irradiated as with ultraviolet or electron beam radiation whereupon the rapid polymerization reaction immediately ensues and the polymer formed immediately segregates from the vehicle thereby resulting in microporous membrane from which the vehicle can be removed as by evaporation or washing. Because the radiation-induced polymerization reaction and the segregation of the polymer formed are so rapid, the membrane formed has cells and communications therebetween of very small dimensions thereby providing the microporous structure. Where ultraviolet radiation is used the solution also includes a photoinitiator.

    Abstract translation: 用于实施本发明的起始材料是(1)一种或多种有机单体或低聚物,其在照射时非常快速地进行聚合反应以形成固体聚合物; 和(2)一种或多种有机单体或低聚物可溶于其中形成的聚合物不溶的液态载体。 为了制造根据本发明的微多孔膜,将单体或低聚物溶解在液体载体中,将所得溶液形成为薄层,然后用紫外线或电子束辐射照射该溶液的薄层, 迅速聚合反应立即发生,形成的聚合物立即与载体分离,从而产生微孔膜,通过蒸发或洗涤可以从中除去载体。 因为辐射诱导的聚合反应和形成的聚合物的偏析如此之快,所形成的膜具有非常小尺寸的电池和通信,从而提供微孔结构。 在使用紫外线的情况下,溶液还包括光引发剂。

    Method for manufacturing a microporous film having low electrical
resistance and high durability
    60.
    发明授权
    Method for manufacturing a microporous film having low electrical resistance and high durability 失效
    具有低电阻和高耐久性的微孔膜的制造方法

    公开(公告)号:US4331622A

    公开(公告)日:1982-05-25

    申请号:US111971

    申请日:1980-01-14

    Abstract: A microporous film which comprises a matrix comprising 40 to 90 volume percent of a polyolefin having a number average molecular weight of 15,000 or more and 10 to 60 volume percent of an inorganic filler, said matrix having therein void spaces at a rate of 30 to 75 volume percent based on the volume of the film; and 2 to 20 weight percent, based on the total weight of the polyolefin and the inorganic filler, of an organic substance which is substantially insoluble in and inert to sulfuric acid and has a solubility parameter ranging from 7.3 inclusive to 8.4 exclusive; said organic substance, in its majority, adhering to the overall surface of the film including the outer surfaces of the film and the surfaces of the polyolefin walls defining said void spaces in cooperation with said inorganic filler.

    Abstract translation: 一种微孔膜,其包含基质,其包含40至90体积%的数均分子量为15,000以上且10至60体积%的无机填料的聚烯烃,所述基质具有30至75的空隙空间 体积百分比基于电影的数量; 和基于聚烯烃和无机填料的总重量的2至20重量%的基本上不溶于硫酸并且对硫酸具有惰性的有机物质,其溶解度参数范围为7.3以上8.4以下; 所述有机物质在大多数情况下,与所述无机填料配合,附着在膜的整个表面上,包括膜的外表面和限定所述空隙空间的聚烯烃壁的表面。

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