Abstract:
The present invention is based upon the discovery that nontitanyl oxalates can enhance the catalytic functionality of titanyl oxalate catalysts. This invention provides a novel catalytic composition containing a titanyl oxalate catalyst and a metallic oxalate catalyst enhancer and optionally containing a metallic cocatalyst such as an antimony based catalyst. A synergistic relationship has been discovered between titanyl oxalate catalyst and the catalyst enhancer. A synergistic relationship has also been discovered between the titanyl oxalate catalyst, catalyst enhancer and a metallic cocatalyst such as antimony oxide or antimony triacetate. Also provided is an improved process of producing polyester by the polycondensation of polyester forming reactants in the presence of a catalytically effective amount of a polycondensation catalyst, wherein the improvement comprises utilizing, as the polycondensation catalyst, the novel catalyst composition containing a titanyl oxalate such as lithium titanyl oxalate and a catalyst enhancer such as a nontitanyl metallic oxalate like lithium oxalate and optionally containing a metallic catalyst such as antimony oxide or antimony triacetate. The improved process produces an improved polyester having lower acetaldehyde numbers and good color. The titanyl oxalate/catalyst enhancer composition can be used as a polycondensation catalyst in combination with other catalysts to achieve synergistic catalytic activity. Preferred is a combination of lithium or potassium titanyl oxalate, Li2 or K2TiO(C2O4)2, lithium or potassium oxalate, Li2 or K2(C2O4)2 with antimony oxide or antimony triacetate or antimony trisglycoxide.
Abstract:
A new method is provided for the removal of metal residue or nodules from surfaces that are target surfaces during the process of metal sputtering. A polishing bit is applied in a rotating manner to a surface on which nodules have been formed, this application removes the nodules from the target surface and prepares the surface for further processing steps.
Abstract:
A liquid phase process is provided for the preparation of 1233zd with reduced oligomer formation via the fluorination of 1230za with HF in the presence of a catalyst selected from TFA and triflic acid. The 1233zd is a known intermediate useful for preparing 245fa.
Abstract:
An azeotrope containing HF and 1233zd is provided, as are methods for separating this azeotrope from mixtures of HF and 1233zd which are HF-rich or 1233zd-rich and methods for making use of the azeotrope and separation methods to improve processes for preparing 1233zd, an intermediate used in the preparation of 245fa. 245fa is a known foam blowing agent and refrigerant.
Abstract:
A torsion pendulum apparatus and a dialometer are combined for simultaneous measurement of the internal friction and the expansion of an alloy. The combination is controlled by a programmable controller so as to conduct in-situ measurements of the internal friction and the expansion of a metal during its phase transformation or specific heat treatment. The results of the internal friction measurement and the expansion measurement can be checked and assumed by one another so that more accurate and detailed information can be obtained for the study of metal alloys.
Abstract:
This invention discloses an anti-UV plastic for automobile interior ornaments. The anti-UV plastic for automobile interior ornaments includes PC resin, ABS resin, antioxygen, pentaerythritol stearate, inorganic filler, anti-UV fiber, organic silicon resin or modified organic silicon resin. Except maintaining the properties of ABS resin and PC resin, the anti-UV plastic for automobile interior ornaments has excellent mechanical properties and thermal properties, and can reduce the maintenance cost of automobile interior ornaments caused by UV aging. In addition, the anti-UV plastic for automobile interior ornaments owns favorable machining properties, and can be machined into automobile interior ornaments of various shapes.
Abstract:
The present disclosure is related to a system and a system for displaying handwriting synchronously, and a handwriting device thereto. The handwriting device adopts a bistable display panel and includes a sensor circuitry that is used to record the handwriting contents over the panel. The sensor circuitry through the handwriting renders handwriting positions and pressure values. These sensed data is transmitted to a computer device instantly when the data of positions and pressure values are generated by the handwriting device. In the computer device, the handwriting can be synchronously displayed through a transformation from the received data to displaying positions and pressure values. Finally, in the computer device, a document recording the handwriting track over time is created. The document can be a picture, a video, or even a document with audio.
Abstract:
The present invention is directed towards a method of stabilizing thermosetting foam blends such as polyurethane poly blends containing a blowing agent with negligible (low or zero) ozone-depletion and low GWP based upon unsaturated halogenated hydroolefins in which one or more ester is added to the thermosetting foam blends. The thermosetting foam blends typically in clued: polyol(s); surfactant(s); catalyst(s); flame retardent(s); organic acid inhibitor(s)/stabilizer(s); carbon dioxide generating agent(s). The addition of the one or more esters to the thermosetting foam blends was unexpectedly found to result in blends which were stable over time and the resulted foams have a uniform cell structure with little or no foam collapse.
Abstract:
A blowing agent for thermosetting foams is disclosed. The blowing agent is a hydrofluoroolefin (HCFO), preferably HFCO-1234yf in combination with a hydrochlorofluoroolefin (HCFO) preferably one selected from HCFO-1233zd, HCFO-1223, HCFO-1233xf and mixtures thereof. The blowing agent is effective as a blowing agent in the manufacture of thermosetting foams.