公开(公告)号：US20040265688A1

公开(公告)日：2004-12-30

申请号：US10487408

申请日：2004-08-13

Inventor： Hideki Arao ,  Masashi Hiromitsu ,  Takakazu Goto ,  Kazuya Tanaka ,  Akio Shimizu ,  Ryoji Morita

IPC: H01M002/02 ,  B32B015/08

CPC classification number: B32B15/082 ,  B32B7/10 ,  B32B15/08 ,  B32B15/20 ,  B32B27/18 ,  B32B27/30 ,  B32B27/308 ,  B32B27/32 ,  B32B27/42 ,  B32B2307/7242 ,  B32B2311/24 ,  B32B2361/00 ,  B32B2457/10 ,  C08K5/098 ,  C08K5/49 ,  C08K2201/008 ,  C08L61/14 ,  H01M2/0287 ,  H01M10/052 ,  Y10T428/31692 ,  C08L63/00

Abstract: The present invention relates to a laminate for battery encasement comprising aluminum foil and an inner layer, wherein a resin film layer that comprises an aminated phenol polymer (A), an acrylic polymer (B), a phosphorus compound (C), and a zirconium compound (D) lies between the aluminum foil and the inner layer. The laminate for battery encasement of the present invention is excellent in adhesiveness, gas impermeability, etc., and therefore can be suitably used as a material for encasing a secondary battery, particularly a lithium ion polymer secondary battery.

Abstract translation: 本发明涉及包含铝箔和内层的电池组合层压体，其中包含胺化苯酚聚合物（A），丙烯酸类聚合物（B），磷化合物（C）和锆的树脂膜层 化合物（D）位于铝箔和内层之间。 本发明的电池组合用层叠体的粘合性，气体不透性等优异，因此可以适合用作二次电池特别是锂离子聚合物二次电池的封装材料。

公开(公告)号：US20040253463A1

公开(公告)日：2004-12-16

申请号：US10490162

申请日：2004-03-18

Inventor： Yoji Inui ,  Naoto Mochizuki ,  Isao Masada ,  Ryuji Ishimoto ,  Hideki Umekawa ,  Hironori Honda ,  Yoshihiro Kimura

IPC: B32B027/08

CPC classification number: B32B27/08 ,  B32B27/06 ,  C08J7/047 ,  C08J2429/00 ,  C08K3/34 ,  C08K2201/008 ,  C08L29/04 ,  C08L71/02 ,  C09D129/04 ,  Y10T428/31667 ,  Y10T428/31909 ,  C08L2666/14 ,  C08L2666/54

Abstract: Provided are a gas-barrier film which is a laminate comprising a substrate layer comprising a thermoplastic resin film and a gas-barrier layer comprising a hydrolysate of a silicon alkoxide, a stratified silicate and a polyvinyl alcohol base resin, wherein a radius (Rg) of gyration of a scattering matter which is measured by light scattering in the gas-barrier layer described above is 2.4 nullm or less, and the silicon alkoxide and/or the hydrolysate thereof are present between the layers of the stratified silicate present in the above gas-barrier layer. The above film shows an excellent gas-barrier property even under such a high humidity as exceeding 90% RH.

Abstract translation: 提供一种阻气膜，其是包含由热塑性树脂膜构成的基材层和包含硅醇盐的水解物，层状硅酸盐和聚乙烯醇基础树脂的阻气层的层压体，其中半径（Rg） 在上述阻气层中通过光散射测量的散射物质的回转为2.4μm以下，硅烷醇盐和/或其水解物存在于上述气体中存在的层状硅酸盐层之间 - 屏障层。 即使在超过90％RH的高湿度下，上述膜也具有优异的阻气性。

公开(公告)号：US20040176536A1

公开(公告)日：2004-09-09

申请号：US10802718

申请日：2004-03-18

Applicant: TOYO SEIKAN KAISHA, LTD.

Inventor： Atsushi Kikuchi ,  Ikuo Komatsu ,  Toshiki Yamada ,  Yoshihiro Kitano ,  Go Saito

IPC: C08G081/00

CPC classification number: B32B27/08 ,  B32B27/18 ,  B32B27/306 ,  B32B27/34 ,  B32B27/36 ,  B32B2307/7244 ,  B32B2439/40 ,  C08F279/00 ,  C08F279/02 ,  C08K5/098 ,  C08K2201/008 ,  C08K2201/012 ,  C08L23/0861 ,  C08L51/04 ,  C08L2312/00 ,  C08L2666/24 ,  C08L2666/02 ,  C08L2666/14 ,  C08L2666/04

Abstract: A resin composition obtained by blending a thermoplastic resin that can be melt-extruded at a solubility parameter of not smaller than 9.5 with an organic oxidizing component and with a transition metal catalyst, the organic oxidizing component being a polyene having a functional group on a side chain or at a terminal thereof. The resin composition has excellent moldability and gas shut-off property. A multi-layer container having an oxygen-absorbing layer of this resin composition exhibits excellent gas-barrier property and is capable of favorably preserving the content.

Abstract translation: 将可溶性参数为9.5以上的可熔融挤出的热塑性树脂与有机氧化成分和过渡金属催化剂混合而获得的树脂组合物，有机氧化成分为侧面具有官能团的多烯 链或其末端。 树脂组合物具有优异的成型性和气体切断性。 具有该树脂组合物的氧吸收层的多层容器具有优异的阻气性，能够有利地保持该含量。

公开(公告)号：US06777479B1

公开(公告)日：2004-08-17

申请号：US09630517

申请日：2000-08-02

Applicant: Linda Gail Bernard ,  Horst Clauberg ,  Michael John Cyr ,  John Walker Gilmer ,  Jeffrey Todd Owens ,  Mark Edward Stewart ,  Sam Richard Turner ,  Shriram Bagrodia ,  James Christopher Matayabas, Jr.

Inventor： Linda Gail Bernard ,  Horst Clauberg ,  Michael John Cyr ,  John Walker Gilmer ,  Jeffrey Todd Owens ,  Mark Edward Stewart ,  Sam Richard Turner ,  Shriram Bagrodia ,  James Christopher Matayabas, Jr.

IPC: C08K334

CPC classification number: B82Y30/00 ,  C08J5/005 ,  C08J2377/00 ,  C08K3/34 ,  C08K7/00 ,  C08K2201/008 ,  C08L77/00

Abstract: Polymer composite materials comprising of least one polymer resin and platelet particles from at least one layered silicate material uniformly dispersed in the resin and articles prepared from the polymer composite materials. The polymer composite contains at least one polyamide resin, at least one oxygen scavenging system, and at least one layered silicate material. These polymer composite materials are especially useful for manufacturing clear polyester bottles and polyester film that are recyclable have improved active gas barrier properties to oxygen, and have improved passive barrier properties to carbon dioxide and other gases. The polymer composite materials can be used in relatively minor amounts as either a blend or a coextruded thin layer with virgin or post consumer recycled polyesters and related copolymners.

Abstract translation: 包含至少一种聚合物树脂的聚合物复合材料和均匀分散在树脂中的至少一种层状硅酸盐材料的片晶颗粒和由聚合物复合材料制备的制品。 聚合物复合材料含有至少一种聚酰胺树脂，至少一种除氧系统和至少一种层状硅酸盐材料。 这些聚合物复合材料特别可用于制造可再循环的透明聚酯瓶和聚酯膜，其具有改善的对氧的活性气体阻隔性能，并且具有改善的对二氧化碳和其它气体的被动阻挡性能。 聚合物复合材料可以以相对小的量用作共混物或共挤出的薄层，其具有原始或消费后的再生聚酯和相关共聚物。

公开(公告)号：US20040048986A1

公开(公告)日：2004-03-11

申请号：US10639514

申请日：2003-08-13

Applicant: Kuraray, Co., Ltd.

Inventor： Hiroyuki Shimo ,  Nobuhiro Hata

IPC: C08L063/00

CPC classification number: C08L23/08 ,  C08K5/0016 ,  C08K2201/008 ,  C08L29/04 ,  C08L77/00 ,  C08L2666/20 ,  C08L2666/14

Abstract: Disclosed herein is a resin composition which comprises (A) an ethylene-vinyl alcohol copolymer having an ethylene content of 20-70 mol %, (B) a polyamide resin, and (C) a hydrophobic plasticizer which satisfies the condition specified by equation (1) below, with the amounts of components (A), (B), and (C) being 55-97 parts by weight, 3-45 parts by weight, and 0.1-30 parts by weight, respectively, on the basis of 100 parts by weight of the total amount of components (A) and (B). 15nullnullCH(A)null1/2nullSP(C)null22nullnull(1) where CH(A) denotes the ethylene content (mol %) in the ethylene-vinyl alcohol copolymer as component (A), and SP(C) denotes the solubility parameter of the hydrophobic plasticizer as component (C), which is calculated from Fedors equation. The resin composition can be formed into film or sheet superior in gas barrier properties readily by heat stretching without cracking and local thickness variation.

Abstract translation: 本发明公开了一种树脂组合物，其包含（A）乙烯含量为20-70摩尔％的乙烯 - 乙烯醇共聚物，（B）聚酰胺树脂和（C）满足由式 1），组分（A），（B）和（C）的量分别为55-97重量份，3-45重量份和0.1-30重量份，基于 组分（A）和（B）的总量100重量份。 其中CH（A）表示作为组分（A）的乙烯 - 乙烯醇共聚物中的乙烯含量（摩尔％），其中CH（A） ，SP（C）表示作为组分（C）的疏水性增塑剂的溶解度参数，其由Fedors方程计算。 树脂组合物可以通过热拉伸容易地形成具有阻气性优异的膜或片，而不会产生裂纹和局部厚度变化。

公开(公告)号：US06426135B1

公开(公告)日：2002-07-30

申请号：US09489476

申请日：2000-01-21

Applicant: Kozo Kotani ,  Toshio Kawakita ,  Taiichi Sakaya ,  Toshiya Kuroda

Inventor： Kozo Kotani ,  Toshio Kawakita ,  Taiichi Sakaya ,  Toshiya Kuroda

IPC: B32B516

CPC classification number: C08J7/045 ,  B32B27/06 ,  B32B27/18 ,  C08K3/346 ,  C08K2201/008 ,  C08K2201/016 ,  Y10S428/91 ,  Y10T428/1352 ,  Y10T428/25 ,  Y10T428/251 ,  Y10T428/252 ,  Y10T428/256 ,  Y10T428/259 ,  Y10T428/31913 ,  Y10T428/31928 ,  Y10T428/31935

Abstract: A resin composition comprising: a polyvinyl alcohol; and an inorganic laminar compound having an aspect ratio of not less than 50 and not more than 5000, which has a volume ratio of (inorganic laminar compound/polyvinyl alcohol) in the range of (5/95) to (30/70); and a laminate or laminate film comprising, as at least a portion thereof, a layer or portion (1) comprising such a resin composition. The resin composition, laminate or laminate film may exhibit a good gas barrier property while substantially retaining a good film strength.

Abstract translation: 一种树脂组合物，其包含：聚乙烯醇; 和（5/95）〜（30/70）范围内的（无机层状化合物/聚乙烯醇）的体积比为50以上5000以下的无机层状化合物。 以及包含其至少一部分的包含这种树脂组合物的层或部分（1）的层压体或层压膜。 树脂组合物，层压体或层压膜可以表现出良好的阻气性，同时基本上保持良好的膜强度。

公开(公告)号：US06319575B1

公开(公告)日：2001-11-20

申请号：US09552573

申请日：2000-04-19

Applicant: Masahiko Takashima ,  Koji Yamamoto ,  Hisashi Shimazaki

Inventor： Masahiko Takashima ,  Koji Yamamoto ,  Hisashi Shimazaki

IPC: B01J1500

CPC classification number: C08K5/092 ,  C08G69/48 ,  C08K2201/008 ,  C08L67/02 ,  C08L77/00 ,  Y10T428/1352

Abstract: A polyester resin composition is produced by melt-kneading a mixture comprising a polyamide resin and a polyester resin, and a tricarboxylic acid compound. The polyamide resin is a polymerization product of a diamine component containing 70 mol % or more of m-xylylenediamine and a dicarboxylic acid component containing 70 mol % or more of adipic acid. The polyester resin is a polymerization product of a dicarboxylic acid component containing 70 mol % or more of an aromatic dicarboxylic acid and a diol component containing 70 mol % or more of an aliphatic diol. The incorporation of a tricarboxylic acid compound such as aromatic tricarboxylic acids and their anhydrides improves transparency and whitening resistance at moisture absorbing of films, sheets and thin-wall hollow containers without deteriorating their gas barrier properties.

Abstract translation: 通过将包含聚酰胺树脂和聚酯树脂的混合物和三羧酸化合物熔融捏合来制造聚酯树脂组合物。 聚酰胺树脂是含有70摩尔％以上的间苯二甲胺和含有70摩尔％以上的己二酸的二羧酸成分的二胺成分的聚合物。 聚酯树脂是含有70摩尔％以上的芳香族二羧酸和含有70摩尔％以上的脂肪族二醇的二醇成分的二羧酸成分的聚合物。 三羧酸化合物如芳族三羧酸及其酸酐的引入提高了薄膜，片材和薄壁中空容器吸湿性时的透明性和耐白化性，而不会降低其阻气性。

公开(公告)号：US5925702A

公开(公告)日：1999-07-20

申请号：US5252

申请日：1998-01-09

Applicant: Kenneth Carl Hecker ,  Richard Robinson Smith

Inventor： Kenneth Carl Hecker ,  Richard Robinson Smith

IPC: B60C1/00 ,  B60C5/14 ,  B60C5/16 ,  C08K3/34 ,  C08K7/00 ,  C08L9/06 ,  C08J5/10

CPC classification number: C08K3/34 ,  B60C1/0008 ,  B60C5/14 ,  B60C5/16 ,  C08K3/346 ,  C08K7/00 ,  C08L9/06 ,  C08K2201/008 ,  C08L2205/02 ,  Y10S152/16

Abstract: It has been unexpectedly found that certain blends of styrene-butadiene rubber and platey filler exhibit both good gas barrier properties and good tensile fatigue properties. These blends accordingly have the requisite characteristics for a tire innerliner material. They offer the advantage of being much less expensive than halobutyl rubbers which can be employed for the same purpose. The present invention more specifically discloses a pneumatic tire having an integral innerliner wherein said innerliner is comprised of a blend of (1) from about 40 phr to about 99 phr of a first styrene-butadiene rubber having a bound styrene content of about 15 percent to about 30 percent, (2) from about 1 phr to about 60 phr of a high styrene content styrene-butadiene rubber having a bound styrene content of about 40 percent to about 60 percent, and (3) from about 40 phr to about 125 phr of platey filler. The subject invention also discloses a pneumatic tire having an integral innerliner wherein said innerliner is comprised of (1) a styrene-butadiene rubber having a bound styrene content of about 15 percent to about 30 percent, and (2) from about 125 phr to about 200 phr of platey filler.

Abstract translation: 已经意外地发现，苯乙烯 - 丁二烯橡胶和板状填料的某些共混物表现出良好的阻气性和良好的拉伸疲劳特性。 因此，这些混合物对于轮胎内衬材料具有必要的特性。 它们的优点是比可以用于相同目的的卤代丁基橡胶便宜得多。 本发明更具体地公开了一种具有整体内衬的充气轮胎，其中所述内衬层由（1）约40phr至约99phr的具有约15％的结合苯乙烯含量的第一苯乙烯 - 丁二烯橡胶的混合物组成， 约30％，（2）约1phr至约60phr具有约40％至约60％的结合苯乙烯含量的高苯乙烯含量丁苯橡胶，和（3）约40phr至约125phr 的平板填料。 本发明还公开了一种具有整体内衬的充气轮胎，其中所述内衬层包括（1）具有约15％至约30％的结合苯乙烯含量的苯乙烯 - 丁二烯橡胶，和（2）约125phr至约 200phr的板状填料。

公开(公告)号：US4536425A

公开(公告)日：1985-08-20

申请号：US618699

申请日：1984-06-08

Applicant: Ihab M. Hekal

Inventor： Ihab M. Hekal

IPC: C08K3/34 ,  B65D81/00 ,  C08L67/02

CPC classification number: C08K3/34 ,  C08K2201/008 ,  C08K2201/016 ,  Y10T428/1372 ,  Y10T428/1379

Abstract: A method of preparing a polar thermoplastic resin having improved resistance to gas permeability is disclosed wherein a blend of the resin and coarse mica flakes having an average particle size of less than about 100 mesh is prepared, the blend being prepared under mixing conditions which impart a shear force to the mica flakes sufficient to delaminate the flakes into individual platelets, substantially increasing the original aspect ratio of the flakes whereby an increase in the gas barrier properties of the resin is attained greater than that attained with fine mica flakes having an average particle size greater than about 100 mesh.

Abstract translation: 公开了一种制备具有改善的耐气体渗透性的极性热塑性树脂的方法，其中制备了平均粒度小于约100目的树脂与粗云母薄片的共混物，该混合物是在混合条件下制备的， 对云母片的剪切力足以使薄片分层成单独的血小板，从而显着增加了薄片的原始纵横比，从而获得了树脂的气体阻隔性能的提高，大于具有平均粒径的细云母片 大于约100目。

公开(公告)号：US4102974A

公开(公告)日：1978-07-25

申请号：US791091

申请日：1977-04-26

Applicant: Kenneth A. Boni

Inventor： Kenneth A. Boni

IPC: C08L23/00 ,  B29C51/00 ,  B29C71/00 ,  B29C71/02 ,  B65D1/00 ,  C08K3/26 ,  C08L1/00 ,  C08L7/00 ,  C08L21/00 ,  C08L23/02 ,  C08L27/00 ,  C08L27/08 ,  C08L101/00 ,  B29D23/01

CPC classification number: C08K3/26 ,  B29C51/002 ,  C08L23/02 ,  C08L23/06 ,  C08K2201/008

Abstract: Polyolefin containers having improved gas barrier properties are prepared by forming a billet comprised of a particle mixture of a polyolefin resin, such as polyethylene, an inorganic filler such as CaCO.sub.3 and at least about 13.5% by volume of a vinylidene chloride polymer having a median particle diameter greater than 150 microns. The billet is heated to a temperature of about 25.degree. to 40.degree. F above the melting temperature of the vinylidene chloride polymer and then molded into a hollow container.

Abstract translation: 具有改善的阻气性的聚烯烃容器通过形成由聚烯烃树脂如聚乙烯，无机填料如CaCO 3和至少约13.5体积％的具有中值粒子的偏二氯乙烯聚合物的颗粒混合物组成的坯料来制备 直径大于150微米。 将坯料加热到高于偏二氯乙烯聚合物的熔融温度约25至40°F的温度，然后模制成中空容器。