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公开(公告)号:US06710138B2
公开(公告)日:2004-03-23
申请号:US10342897
申请日:2003-01-15
Applicant: Walter H Ohrbom , John W. Rehfuss
Inventor: Walter H Ohrbom , John W. Rehfuss
IPC: C08F830
CPC classification number: C08G18/285 , C09D201/025
Abstract: The instant invention provides carbamate functional polymers and/or oligomers and coating compositions containing such which have improved levels of nonvolatile solids yet demonstrate good sprayability and etch resistance. The carbamate functional polymers and/or oligomers of the invention comprise the polymerization reaction product of (a) a polymer or oligomer comprising a plurality of functional groups reactive with an active hydrogen group, and (b) a monomeric compound of the formula: wherein at least one of Y and Z is an active hydrogen containing group and the other is a primary carbamate group, and R is of the formula: —(L)n—R′ wherein L is a linking group of one or more carbons containing heteratoms selected from the group consisting of O, N, and mixtures thereof, R′ is an alkyl group free of heteratoms and selected from the group consisting of branched alkyl groups having from 5 to 30 carbons, straight chain alkyl groups of more than 2 carbons, and mixtures thereof, and n is a number from 0 to 1.
Abstract translation: 本发明提供了含有这样的氨基甲酸酯官能聚合物和/或低聚物和涂料组合物,其具有改进的非挥发性固体含量,但表现出良好的喷涂性和耐蚀刻性。 本发明的氨基甲酸酯官能聚合物和/或低聚物包含(a)包含多个与活性氢基团反应的官能团的聚合物或低聚物的聚合反应产物,和(b)下式的单体化合物:其中在 Y和Z中的至少一个是含氢活性基团,另一个是伯氨基甲酸酯基,R是下式的化合物: - (L)nR'其中L是一个或多个含有杂原子的碳的连接基团,选自 由O,N及其混合物组成的基团,R'是不含杂原子的烷基,选自碳原子数5〜30的支链烷基,碳原子数2以上的直链烷基及其混合物 ,n为0〜1的数。
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公开(公告)号:US06649734B2
公开(公告)日:2003-11-18
申请号:US10127993
申请日:2002-04-23
Applicant: Donald Campbell , Vincent Cook , Bruce Oermann , William Bearyman
Inventor: Donald Campbell , Vincent Cook , Bruce Oermann , William Bearyman
IPC: C08G7300
CPC classification number: C09D201/025 , C08L61/32 , C09D133/14 , C09D161/20 , C09D161/34 , C09D175/04 , Y10T428/31551 , C08L2666/16
Abstract: The invention provides coating compositions having improved scratch and mar resistance. The curable coating compositions of the invention comprise a film-forming component (A) comprising one or more active hydrogen containing components (a), and one or more curing agents (b) comprising at least one aminoplast resin (bi) having from 0.5 to 3.5 moles of NH per mole of aminoplast resin (bi), a blocked acid catalyst (B) having a blocking agent which is not a tertiary amine, and a tertiary amine (C) present in an amount equal to 10 to 150% by weight of the blocking agent. The invention farther provides a method of making cured coated substrates having improved scratch and mar resistance as well as a method of making multilayer coating compositions.
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公开(公告)号:US06624279B2
公开(公告)日:2003-09-23
申请号:US10042820
申请日:2002-01-09
Applicant: Walter H. Ohrbom , David J. Law , Patricia A. Herrel
Inventor: Walter H. Ohrbom , David J. Law , Patricia A. Herrel
IPC: C08G1806
CPC classification number: C07C271/12 , C08F20/36 , C08G18/2815 , C08G18/3831 , C09D161/28 , C09D201/025 , Y10T428/31551 , Y10T428/31725 , Y10T428/31855
Abstract: The invention provides water-soluble, &bgr;-hydroxy carbamate-functional materials and coating compositions, especially waterborne coating compositions, containing the carbamate-functional materials. The invention further provide a coating prepared from the coating composition and a coated substrate, especially an automotive substrate, having the coating thereon.
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公开(公告)号:US20030171519A1
公开(公告)日:2003-09-11
申请号:US10348484
申请日:2003-03-25
Inventor: Donald H. Campbell , Walter H. Ohrbom , Joseph Borst , Michael A. Gessner , Donald L. St. Aubin , Marvin L. Green , Bruce Oermann
IPC: C08F126/02
CPC classification number: C08G18/8116 , C08F8/00 , C08F2800/20 , C08F2810/50 , C08G18/3823 , C09D201/025 , Y10T428/31551 , Y10T428/31573 , Y10T428/31645 , C08F2220/325 , C08F220/34 , C08F220/20 , C08F212/08
Abstract: The invention provides carbamate-functional resins and coating compositions incorporating said resins that have improved adhesion with respect to subsequently applied films or coatings. More particularly, the invention relates to carbamate-functional addition polymers having at least 250 grams of polymer per carbamate group which are made with less than 35 percent by weight of nonfunctional monomers, preferably with less than 20 percent by weight and most preferably from 0 to less than 10 percent by weight, based on the total weight of the polymer. The invention further provides a method of making a carbamate-functional polymer and carbamate-functional polymers made by the claimed method. Finally, the invention provides a method for improving the adhesion of a first coating composition to a subsequently applied material as well as a method of making a composite comprising a coated substrate, an adhesive composition, and a glass having at least one surface.
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公开(公告)号:US20030166813A1
公开(公告)日:2003-09-04
申请号:US10391839
申请日:2003-03-19
Inventor: Walter H. Ohrbom , Patricia A. Herrel
IPC: C08F226/00
CPC classification number: C07C271/12 , C08F20/36 , C09D201/025
Abstract: The null-hydroxy carbamate, ethylenically unsaturated monomer of the invention can be polymerized as a homopolymer or copolymerized with other monomers. The polymerization can be carried out in an aqueous medium. The null-hydroxy carbamate monomer is polymerized to form water-soluble homopolymers or, if polymerized as a mixture with one or more comonomers, copolymers that are soluble, emulsifiable, or dispersible in water. The null-hydroxy carbamate monomer can be used as a replacement monomer for acrylamide.
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公开(公告)号:US06583212B2
公开(公告)日:2003-06-24
申请号:US10015095
申请日:2001-12-11
Applicant: Joseph P. Borst , Sergio E Balatan , Walter H. Ohrbom , Robert D. Weise , Davide J. Law
Inventor: Joseph P. Borst , Sergio E Balatan , Walter H. Ohrbom , Robert D. Weise , Davide J. Law
IPC: C08J302
CPC classification number: C09D5/027 , C08J3/03 , C09D201/025
Abstract: The invention provides curable coating compositions comprising an aqueous dispersion comprising a stabilizing resin (P1) and a compound (P2) comprising functional groups reactable with a crosslinking agent. Compound (P2) is dispersed into stabilizing resin (P1). The coating compositions of the invention may further comprise an optional crosslinking agent (P3) which may or may not be dispersed into stabilizing resin (P1). In a particularly preferred embodiment, both the stabilizing resin (P1) and compound (P2) will comprise functional groups which are carbamate or are convertible to carbamate.
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公开(公告)号:US06531560B1
公开(公告)日:2003-03-11
申请号:US09677063
申请日:2000-09-29
Applicant: Donald H. Campbell , Walter H. Ohrbom , Joseph Borst , Michael A. Gessner , Donald L. St. Aubin , Marvin L. Green , Bruce E. Oermann
Inventor: Donald H. Campbell , Walter H. Ohrbom , Joseph Borst , Michael A. Gessner , Donald L. St. Aubin , Marvin L. Green , Bruce E. Oermann
IPC: C08F12602
CPC classification number: C08G18/8116 , C08F8/00 , C08F2800/20 , C08F2810/50 , C08G18/3823 , C09D201/025 , Y10T428/31551 , Y10T428/31573 , Y10T428/31645 , C08F2220/325 , C08F220/34 , C08F220/20 , C08F212/08
Abstract: The invention provides carbamate-functional resins and coating compositions incorporating said resins that have improved adhesion with respect to subsequently applied films or coatings. More particularly, the invention relates to carbamate-functional addition polymers having at least 250 grams of polymer per carbamate group which are made with less than 35 percent by weight of nonfunctional monomers, preferably with less than 20 percent by weight and most preferably from 0 to less than 10 percent by weight, based on the total weight of the polymer. The invention further provides a method of making a carbamate-functional polymer and carbamate-functional polymers made by the claimed method. Finally, the invention provides a method for improving the adhesion of a first coating composition to a subsequently applied material as well as a method of making a composite comprising a coated substrate, an adhesive composition, and a glass having at least one surface.
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公开(公告)号:US20020193509A1
公开(公告)日:2002-12-19
申请号:US09829829
申请日:2001-04-10
Inventor: Gregory G. Menovcik , Michele L. Stauffer , Mark West , Sergio E. Balatan , James A. Laugal
IPC: C08K003/00
CPC classification number: C09D167/00 , C08G18/3831 , C08G18/6229 , C08G18/807 , C09D133/062 , C09D175/04 , C09D201/025 , C08L2666/14 , C08L2666/16
Abstract: The coating composition of the invention includes a polymer, especially an acrylic polymer, having hydroxyl and/or primary carbamate functionality; a water-miscible organic solvent; a low hydrogen bonding oxygenated solvent; and water that is emulsified in the organic phase. The coating composition of the invention may be a clearcoat coating composition, preferably an automotive clearcoat coating composition. The invention further provides an article, such as an automotive vehicle, having a surface coated with a coating derived from the coating composition of the invention, particularly a composite coating having a basecoat layer and a clearcoat layer, and a method of producing such a coating on a substrate, particularly as a basecoat/clearcoat composite coating, with the coating composition of the invention preferably being at least the clearcoat of the composite coating. The coating composition of the invention provides especially low volatile organic content, with significant reductions of 25% or more from comparable previous coating compositions.
Abstract translation: 本发明的涂料组合物包括具有羟基和/或伯氨基甲酸酯官能团的聚合物,特别是丙烯酸聚合物; 水混溶性有机溶剂; 低氢键氧合溶剂; 和在有机相中乳化的水。 本发明的涂料组合物可以是透明涂料组合物,优选汽车透明涂料组合物。 本发明还提供了一种具有涂覆有由本发明的涂料组合物衍生的涂层的表面的汽车的制品,特别是具有底涂层和透明涂层的复合涂层,以及制备这种涂层的方法 在基材上,特别是作为底涂层/透明涂层复合涂层,本发明的涂料组合物优选至少为复合涂层的透明涂层。 本发明的涂料组合物提供特别低的挥发性有机物含量,与可比较的涂料组合物相比显着减少25%或更多。
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公开(公告)号:US20020169249A1
公开(公告)日:2002-11-14
申请号:US10015095
申请日:2001-12-11
Inventor: Joseph P. Borst , Sergio E. Balatan , Walter H. Ohrbom , Robert D. Weise , Davide J. Law
IPC: C08K003/20
CPC classification number: C09D5/027 , C08J3/03 , C09D201/025
Abstract: The invention provides curable coating compositions comprising an aqueous dispersion comprising a stabilizing resin (P1) and a compound (P2) comprising functional groups reactable with a crosslinking agent. Compound (P2) is dispersed into stabilizing resin (P1). The coating compositions of the invention may further comprise an optional crosslinking agent (P3) which may or may not be dispersed into stabilizing resin (P1). In a particularly preferred embodiment, both the stabilizing resin (P1) and compound (P2) will comprise functional groups which are carbamate or are convertible to carbamate.
Abstract translation: 本发明提供了包含包含稳定树脂(P1)的水分散体和包含可与交联剂反应的官能团的化合物(P2)的可固化涂料组合物。 化合物(P2)分散在稳定树脂(P1)中。 本发明的涂料组合物可以进一步包含任选的交联剂(P3),其可以分散在稳定树脂(P1)中或不分散到稳定树脂(P1)中。 在特别优选的实施方案中,稳定树脂(P1)和化合物(P2)都将包含氨基甲酸酯或可转化为氨基甲酸酯的官能团。
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公开(公告)号:US20020147279A1
公开(公告)日:2002-10-10
申请号:US09731328
申请日:2000-12-06
Inventor: Walter H. Ohrbom , John W. Rehfuss
IPC: C08F008/32 , C08F026/02 , C08K005/205
CPC classification number: C08G18/285 , C09D201/025
Abstract: The instant invention provides carbamate functional polymers and/or oligomers and coating compositions containing such which have improved levels of nonvolatile solids yet demonstrate good sprayability and etch resistance. The carbamate functional polymers and/or oligomers of the invention comprise the polymerization reaction product of (a) a polymer or oligomer comprising a plurality of functional groups reactive with an active hydrogen group, and (b) a monomeric compound of the formula: 1 wherein at least one of Y and Z is an active hydrogen containing group and the other is a primary carbamate group, and R is of the formula: null(L)nnullRnull wherein L is a linking group of one or more carbons containing heteratoms selected from the group consisting of O, N, and mixtures thereof, Rnull is an alkyl group free of heteratoms and selected from the group consisting of branched alkyl groups having from 5 to 30 carbons, straight chain alkyl groups of more than 2 carbons, and mixtures thereof, and n is a number from 0 to 1.
Abstract translation: 本发明提供了含有这样的氨基甲酸酯官能聚合物和/或低聚物和涂料组合物,其具有改进的非挥发性固体含量,但表现出良好的喷涂性和耐蚀刻性。 本发明的氨基甲酸酯官能聚合物和/或低聚物包含(a)包含多个与活性氢基团反应的官能团的聚合物或低聚物的聚合反应产物,和(b)下式的单体化合物:其中在 Y和Z中的至少一个是含氢活性基团,另一个是伯氨基甲酸酯基,R是下式的化合物: - (L)nR'其中L是一个或多个含有杂原子的碳的连接基团,选自 由O,N及其混合物组成的基团,R'是不含杂原子的烷基,选自碳原子数5〜30的支链烷基,碳原子数2以上的直链烷基及其混合物 ,n为0〜1的数。
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