Abstract:
A hydrogen generating part is provided for reacting water and a raw material composed of carbon and hydrogen atoms to generate hydrogen gas, a raw material supply part is provided for supplying a raw material to the hydrogen generating part, a water supply part is provided for supplying water to the hydrogen generating part, a catalyst combustion part is provided, an air supply part is provided for supplying air to the catalyst combustion part, a path switching part is provided for switching raw material supply paths between the raw material supply part and the hydrogen generating part, a bypass path is provided for supplying a raw material to the catalyst combustion part from the path switching part, and a combustion gas path is provided for supplying combustion gas after the catalyst combustion part to the hydrogen generating part. The control part switches the path switching part, and the inside of the hydrogen generating part is replaced with combustion gas after the catalyst combustion part.
Abstract:
An improved singlet delta oxygen generator (SOG) and method of its use are disclosed. The improved SOG is compact and scalable, capable of operating in a zero-gravity or low gravity environment, requires no gaseous diluent or buffer gas, and is capable of operating at pressures as high as one atmosphere. The improved SOG also efficiently utilizes the reactants and produces a O2(1null) stream that is largely free of chlorine and water vapor contamination and therefore does not require a BHP regeneration system or a water vapor trap. When used as part of a COIL system, the SOG may be part of a plenum that directly feeds the laser's nozzle. The close proximity of the SOG to the laser cavity allows operation of the SOG at higher pressures without significant depletion of available O2(1null) through collisional deactivation.
Abstract:
A fuel reforming system, comprising a reformer (8) which generates reformate gas containing hydrogen, a carbon monoxide oxidizer (9) containing a carbon monoxide oxidation catalyst which removes carbon monoxide contained in the reformate gas by a shift reaction and a preferential oxidation reaction, and supplies reformate gas from which the carbon monoxide has been removed to the fuel cell (17), and a cooling device (12) which cools the heat liberated by the shift reaction and preferential oxidation reaction in the carbon monoxide oxidizer (9) by a coolant. The controller (31) determines whether the carbon monoxide oxidizer (9) is in a marginal operation state where a processing performance of the carbon monoxide oxidation catalyst has reached its limit, and performs an avoidance processing to avoid the marginal operation state of the carbon monoxide oxidation catalyst.
Abstract:
A tube reactor (2) for performing exothermic gas phase reactions comprising a reaction tube bundle (8), that extends in a sealed manner between two tube end plates (4, 6), that carries a reaction gas and is surrounded by a heat carrier inside a surrounding reactor shell (10). The tube reactor also includes a cowl (18, 20) that spans the respective tube plates (4, 6) and is connected to a gas inlet and a gas discharge line, respectively. Inside the cowl (18) on the gas inlet side adjacent to a first gas supply chamber (28), connected to the inside of the reaction tubes (16), is located a separately fed second gas supply chamber (30) with its own tube end plate (32) that is connected to separate gas supply tubes (34) suitable for a second reaction gas. The separate gas supply tubes reach into the gas inlet end or reach to directly before the gas inlet ends of the reaction tubes (16). This avoids early admixing of an explosion-critical reactant into the reaction gas stream using relatively simple and practical means of construction, which in turn improves the ability to load the reaction gas stream with this reactant.
Abstract:
A reactor for evaporating liquid feed and reacting said feed in the presence of catalyst to make product comprises a housing having at least one inlet and at least one outlet and encasing an evaporation zone and a reaction zone, an injector passing through the inlet and having an orifice in the evaporation zone for introducing a liquid feed, an insert containing packing for vaporizing the liquid feed where the packing is in the evaporation zone, a receptacle for retaining catalyst in the reaction zone and at least one heater associated with at least a portion of the reactor, wherein the injector orifice and the packing define a gap between the orifice and the packing sufficiently small to interfere with the formation of a drop at the orifice.
Abstract:
The invention relates to a system for supplying at least two components of a gas producing system of a fuel cell installation, especially the stages of a multi-stage reformation process, with an evaporated and/or superheated hydrocarbon or a hydrocarbon/water mixture. The inventive system comprises at least two heat exchangers that have one zone for the media and one zone for the supply of thermal energy each. The heat exchangers are associated with one of the components each, the zone used for the supply of thermal energy to the at least two heat exchangers being connected in tandem. Alternatively, the inventive system comprises a heat exchanger and downstream of the media zone thereof a valve device which supplies the evaporated and/or superheated volume flow to at least one respective section of pipes that leads to one of the at least two components, respectively.
Abstract:
Diesel fuels or blending stocks having excellent lubricity, oxidative stability and high cetane number are directly produced from synthesis gas over activated carbon supported cobalt based Fischer-Tropsch catalyst under the condition of temperature within the range of 120 to 400null C., reaction pressure within the range of 0.5 to 10.0 MPa, volume hourly space velocity of a mixture of hydrogen and carbon monoxide within the range of 100 to 5000, the mole ratio of hydrogen to carbon monoxide within the range of 1 to 4. Diesel fuels containing at least 95 wt % paraffins with an iso to normal ratio of about 0.03 to 0.3,
Abstract:
An improved process for the causticisation of Bayer liquors in an alumina refinery, the process including the steps of reacting lime with aluminate ions in a Bayer liquor within a primary reactor under controlled conditions of low to moderate temperature (between 70-80null C.) and agitation, to form substantially only a hydrocalumite species and hydroxyl ions; and a secondary reactor wherein the hydrocalumite species formed is subjected to heating in contact with a Bayer liquor under controlled conditions so as to cause the hydrocalumite species to react with the liquor to form calcium carbonate, aluminate ions and hydroxyl ions, whereby a causticised Bayer liquor is obtained and wherein the efficiency of lime utilization is substantially increased and/or alumina losses are minimized.
Abstract:
A system for purifying a cumene hydroperoxide cleavage product mixture comprises a cumene hydroperoxide cleavage product mixture feed containing impurities in fluid communication with an aqueous alkaline solution feed; the cumene hydroperoxide cleavage product mixture and aqueous alkaline solution feeds in fluid communication with a neutralization drum having a aqueous salt phase outlet; a aqueous salt phase feed containing impurities in fluid communication with a decomposer reactor having an oxidized aqueous salt phase outlet; an oxidizing agent feed in fluid communication with the aqueous salt phase feed containing the impurities prior to the decomposer reactor; and an oxidized aqueous salt phase feed containing water-soluble oxidized derivatives of the impurities in fluid communication with the cumene hydroperoxide cleavage product mixture prior to the neutralization drum.
Abstract:
A process for producing branched olefins from a mixed linear olefin/paraffin isomerisation feed comprising linear olefins having at least 7 carbon atoms in 5-50% w comprising in a first stage skeletally isomerising linear olefins in the isomerisation feed and in a second stage separating branched and linear molecules wherein branched molecules are substantially olefinic and linear molecules are olefinic and/or paraffinic; novel stages and combinations thereof; apparatus therefor; use of catalysts and the like therein; and use of branched olefins obtained thereby.