Sulfur and nitrogen containing hydrocarbons and process of using same in
separating desired ions from solutions thereof
    61.
    发明授权
    Sulfur and nitrogen containing hydrocarbons and process of using same in separating desired ions from solutions thereof 失效
    含硫和氮的烃和使用它们从其溶液中分离所需离子的方法

    公开(公告)号:US5084430A

    公开(公告)日:1992-01-28

    申请号:US542013

    申请日:1990-06-22

    Abstract: Compositions of matter are disclosed comprising nitrogen containing hydrocarbons which are modified with at least one of the elements selected from the group consisting of sulfur, phosphorus an arsenic, with the modified hydrocarbons being covalently bonded to trialkoxysilane. These modified hydrocarbons are further covalently bonded to a solid inorganic support such as silica to form a solid complexing agent. The complexing agents are particularly useful in a process of removing and/or concentrating certain ions, such as noble metal ions and other transition metal ions, from solutions thereof admixed with other ions by forming a complex of the desired ion(s) with the complexing agent. The solution preferably flow through a column packed with the complexing agent to form the complex of the desired ion(s). The desired ion(s) are recovered from the column by subsequently flowing a receiving liquid through the column, wherein the receiving liquid is adapted to break the complex and receive ion(s) in solution in the receiving liquid. The receiving ion(s) can then be separated from the receiving liquid if so desired.

    Abstract translation: 公开了一种物质组合物,其包含含有烃的烃,其用选自硫,磷和砷中的至少一种元素进行改性,所述改性烃与三烷氧基硅烷共价键合。 这些改性烃进一步共价键合到固体无机载体如二氧化硅上以形成固体络合剂。 络合剂特别可用于从与其它离子混合的溶液中除去和/或浓缩某些离子(例如贵金属离子和其它过渡金属离子)的方法,通过将所需离子的络合物与络合物 代理商 溶液优选流过填充有络合剂的柱以形成所需离子的络合物。 通过随后使接收液体流过色谱柱,从柱中回收所需的离子,其中接收液体适于破坏复合物并在接收液体中的溶液中接收离子。 如果需要,接收离子然后可以与接收液体分离。

    Process for preparing high purity hydrogen peroxide
    62.
    发明授权
    Process for preparing high purity hydrogen peroxide 失效
    制备高纯度过氧化氢的方法

    公开(公告)号:US5055286A

    公开(公告)日:1991-10-08

    申请号:US207176

    申请日:1988-06-15

    CPC classification number: C01B15/013 C01B15/0135

    Abstract: Metal ions contained in hydrogen peroxide can be removed efficiently, safely and inexpensively by contacting hydrogen peroxide to be purified with an anion exchange resin with a chelating agent adsorbed therein.

    Abstract translation: 通过将待纯化的过氧化氢与阴离子交换树脂与吸附的螯合剂接触,可以有效,安全且廉价地除去过氧化氢中所含的金属离子。

    Agarose-polyaldehyde beads and their biological application affinity
chromatography, hemoperfusion, cell separation, etc.
    67.
    发明授权
    Agarose-polyaldehyde beads and their biological application affinity chromatography, hemoperfusion, cell separation, etc. 失效
    琼脂糖 - 多醛珠及其生物应用亲和层析,血液灌注,细胞分离等

    公开(公告)号:US4732811A

    公开(公告)日:1988-03-22

    申请号:US921963

    申请日:1986-10-22

    Applicant: Shlomo Margel

    Inventor: Shlomo Margel

    Abstract: There are provided magnetic and non-magnetic agarose and agar polyaldehyde beads with diameters ranging from 40 microns up to 1 cm, and processes for the synthesis of such beads. The polyaldehyde compounds e.g. polyacrolein, polymethacrolein or polyglutaraldehyde, were used as microspheres or as powders. The agarose-polyaldehyde beads are capable of covalently binding in a single step, through their aldehyde groups, compounds containing primary amino groups of thiol groups, such as proteins, antibodies, enzymes and drugs. The beads are useful for various biological applications e.g. affinity chromatography, hemoperfusion, ion exchange resins, cell labeling, diagnostic purposes and cell separation.

    Abstract translation: 提供直径范围从40微米至1厘米的磁性和非磁性琼脂糖和琼脂聚醛珠,以及用于合成这种珠的方法。 多醛化合物例如 聚丙烯醛,聚甲基丙烯醛或聚戊二醛用作微球或粉末。 琼脂糖 - 多醛珠能够在单一步骤中通过其醛基,含有硫醇基团的伯氨基,例如蛋白质,抗体,酶和药物的化合物共价结合。 珠可用于各种生物应用,例如 亲和层析,血液灌注,离子交换树脂,细胞标记,诊断目的和细胞分离。

    1,3 Disubstituted aromatic cyclohexane imides
    69.
    发明授权
    1,3 Disubstituted aromatic cyclohexane imides 失效
    1,3-二取代芳族环己烷酰亚胺

    公开(公告)号:US4698425A

    公开(公告)日:1987-10-06

    申请号:US634053

    申请日:1984-07-24

    Applicant: Julius Rebek

    Inventor: Julius Rebek

    Abstract: The compounds of the invention comprise the condensation product, as well as derivatives thereof, of two equivalents of a trimethyl cyclohexane-anhydride acid chloride derivative with one equivalent of an aromatic diamine. The scope of the invention includes the method of using the compounds of the invention as chelating agents for metals, metal ions or ions of metal complexes. In a preferred embodiment of the invention the binding moieties of the cyclohexane derivatives are rigidly held opposite each other, by restricting their rotation about the N-C aryl bonds, in order to more effectively bind the metals or the ions.

    Abstract translation: 本发明的化合物包含两当量的三甲基环己烷 - 酐酰氯衍生物与一当量芳族二胺的缩合产物及其衍生物。 本发明的范围包括使用本发明化合物作为金属,金属离子或金属络合物离子的螯合剂的方法。 在本发明的优选实施方案中,环己烷衍生物的结合部分通过限制它们围绕N-C芳基的旋转而被牢固地保持相对,以便更有效地结合金属或离子。

    Traveling bed ion exchange contact apparatus and process employing same
    70.
    发明授权
    Traveling bed ion exchange contact apparatus and process employing same 失效
    旅行床离子交换接触装置及其使用方法

    公开(公告)号:US4661258A

    公开(公告)日:1987-04-28

    申请号:US514919

    申请日:1983-07-18

    Inventor: Gary C. Phillips

    CPC classification number: B01J47/10 B01J45/00

    Abstract: A technique for contacting a fluid with an ion exchange resin which comprises flowing the contacting fluid through a moving bed of ion exchange resin in a direction essentially perpendicular to the direction of flow of said ion exchange resin bed.

    Abstract translation: 一种用于使流体与离子交换树脂接触的技术,其包括使接触流体沿着离子交换树脂床的流动方向基本垂直的方向流过离子交换树脂的移动床。

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