Abstract:
A method for controlling the release of nuclear fission products (including Mo, Tc, Ru, Rh, and Pd) associated with spent nuclear fuel heats the spent nuclear fuel to a predetermined temperature for a predetermined period of time. The predetermined temperature is sufficiently high to diffuse the nuclear fission products within the spent nuclear fuel and sufficiently low to avoid the release of volatile fission products from within the fuel. The predetermined period of time is sufficiently long to cause an optimal degree of phase redistribution of the nuclear fission products within the spent nuclear fuel. The product of the process is spent nuclear fuel characterized by separation of the nuclear fission products into discrete Mo-Tc-Ru-Rh-Pd phases within the spent nuclear fuel. The Mo-Tc-Ru-Rh-Pd phases make the spent nuclear fuel safer for long-term disposal in geologic repositories.
Abstract:
In a method of fabricating a channel box for use in a nuclear reactor, Zr-alloy sheet material is formed into a tubular channel box. The method includes solution heat treatment of the Zr-alloy sheet material including quenching from a temperature at which .beta.-phase is present. After the solution heat treatment, portions of the Zr-alloy sheet are thinned relative to other portions by a non-stressing thinning process, such as chemical etching in a bath. The corrosion resistance imparted by heat treatment is retained, and the heat treatment itself is easily performed on material of uniform thickness.
Abstract:
A method of producing enhanced radial texture in zirconium alloy tubing suitable for use in forming cladding for nuclear fuel rods is provided. The tubing production method described herein employs a combination of mechanical expansion and heat treatment steps in the final stage of tubing formation to produce a single peak radial texture in the tubing, thereby imparting enhanced resistance to pellet-cladding-interaction to the finished tubing. The tubing is preferably processed to a diameter within less than about 10 to 20% of the desired final diameter, annealed, and expanded less than about 10 to 20% to the desired final diameter, thereby producing a unique radial texture in the finished tubing. In an alternative method, the finally expanded tubing is subjected to a final recrystallization anneal to produce a significantly enhanced split radial texture.
Abstract:
An implantation method for the improvement of the corrosion resistance and hydrogen absorption resistance of zirconium alloys in a light water nuclear reactor environment includes the steps of sputtering a layer of hafnium ions onto a zirconium alloy and the implanting the hafnium ions with xenon doses of 3.times.10.sup.16 ions/cm.sup.2.
Abstract:
For manufacturing zirconium alloy plates, more particularly for forming grids for holding nuclear fuel elements, a strip is obtained by hot rolling, then cold rolling, with a high cold hammering rate, then the strip is subjected to reheating for removing the tension at a temperature lower than the recrystallization temperature. Plates are cut out in the transverse direction of the strip.
Abstract:
The zirconium cladding of a coolant-displacement rod of a nuclear reactor is precollapsed in the zirconium oxide stack of pellets which supports the cladding. Current is conducted through the cladding in an atmosphere at reduced pressure containing residual oxygen, to heat the cladding to a temperature at which its yield strength is reduced. Then, while the rod remains at this temperature, it is subjected to isostatic pressure which collapses the cladding uniformly. The formation, by reason of exposure to neutron flux, of a long unsupported gap in the cladding which might be collapsed under the pressure of the coolant is precluded. In addition, the rod retains its symmetry. The outer surface of the cladding is oxidized, facilitating the movement of the rod into its thimbles of the core and improving the resistances of the cladding to reaction with the coolant.
Abstract:
High tensile strength, creep and corrosion resistant zirconium alloys containing 7.0-10.0 wt % aluminum, 0-3 wt % in total of one or more elements selected from the group consisting of magnesium, tin, chromium, iron, carbon, silicon, yttrium, niobium, molybdenum and beryllium, the balance zirconium and incidental impurities, are produced by annealing cast alloys at a temperature below about 992.degree. C. for a period of time sufficient to produce alloys having a substantially continuous matrix of the ordered intermetallic compound Zr.sub.3 Al. The alloys may initially be hot worked at temperatures about 1000.degree. C., while in the .beta.Zr-Zr.sub.2 Al two phase region, prior to annealing. Preferred alloys contain 7.5-9.5 wt % aluminum, the balance zirconium and incidental impurities.
Abstract:
High tensile strength, creep and corrosion resistant zirconium alloys containing 7.0-10.0 wt% aluminum, 0-3 wt% in total of one or more elements selected from the group consisting of magnesium, tin, chromium, iron, carbon, silicon, yttrium, niobium, molybdenum and beryllium, the balance zirconium and incidental impurities, are produced by annealing cast alloys at a temperature below about 992.degree. C for a period of time sufficient to produce alloys having a substantially continuous matrix of the ordered intermetallic compound Zr.sub.3 Al. The alloys may initially be hot worked at temperatures above about 1000.degree. C, while in the .beta.Zr-Zr.sub.2 Al two phase region, prior to annealing. Preferred alloys contain 7.5-9.5% aluminum, the balance zirconium and incidental impurities.