公开(公告)号：US4629656A

公开(公告)日：1986-12-16

申请号：US733407

申请日：1985-05-13

Applicant: Giulio Alberti ,  Umberto Costantino

Inventor： Giulio Alberti ,  Umberto Costantino

IPC: B01D53/22 ,  B01D71/02 ,  B01J39/08 ,  B01J39/10 ,  B01J39/12 ,  B01J47/12 ,  C01B25/37 ,  C01G28/02 ,  C01B25/00 ,  C08K1/02

CPC classification number: C01B25/372 ,  B01J39/085 ,  B01J39/12 ,  B01J47/12 ,  C01B25/37 ,  C01G28/02 ,  Y10T428/31504

Abstract: Ion exchange inorganic films made up of alpha-type or gamma-type layered structure insoluble acid salts of tetravalent metals or their salt forms, or their intercalated forms or their organic derivatives containing polar groups. A process for the preparation of said films.

Abstract translation: 由α型或γ型层状结构的四价金属或其盐形式的不溶性酸盐或它们的插层形式或其含极性基团的有机衍生物构成的离子交换无机膜。 一种制备所述薄膜的方法。

公开(公告)号：US3850835A

公开(公告)日：1974-11-26

申请号：US19680571

申请日：1971-11-08

Applicant: CCI LIFE SYSTEMS INC

Inventor： MARANTZ LAURENCE BOYD ,  MORNA CLIFFORD MATTHEW

IPC: B01J39/02 ,  B01J39/10 ,  B01J39/12 ,  C01G25/02 ,  C02B1/44

CPC classification number: B01J39/12 ,  B01J39/02 ,  B01J39/10 ,  C01G25/02 ,  C01P2004/61

Abstract: A method of producing zirconium hydrous oxide ion exchangers by adding zirconium compound in granular form to a reagent which fixes the shape of the initial zirconium compound particles by converting the zirconium compound to insoluble zirconium hydrous oxide ion exchangers.

Abstract translation: 通过将锆化合物以粒状形式添加到通过将锆化合物转化成不溶性氧化锆离子交换剂来固定初始锆化合物颗粒的形状的试剂的方法来生产含氧化锆离子交换剂的方法。

公开(公告)号：US3522187A

公开(公告)日：1970-07-28

申请号：US3522187D

申请日：1967-06-05

Applicant: KRAUS KURT A ,  JAMES S JOHNSON JR ,  HAROLD O PHILLIPS

Inventor： KRAUS KURT A

IPC: B01J39/10 ,  C09K3/00

CPC classification number: B01J39/10

公开(公告)号：US3499537A

公开(公告)日：1970-03-10

申请号：US3499537D

申请日：1967-07-24

Applicant: MC DONNELL DOUGLAS CORP

Inventor： BITTLES JAMES A

IPC: B01J39/10 ,  B01J41/10 ,  C08J5/22 ,  B01D39/14 ,  C01G31/00

CPC classification number: C08J5/22 ,  B01J39/10 ,  B01J41/10

公开(公告)号：US20250034675A1

公开(公告)日：2025-01-30

申请号：US18225373

申请日：2023-07-24

Applicant: PAVEL KUDRYAVTSEV ,  Nikolai Kudriavtsev

Inventor： PAVEL KUDRYAVTSEV ,  Nikolai Kudriavtsev

IPC: C22B3/42 ,  B01J39/02 ,  B01J39/10 ,  C22B26/12

Abstract: A method of manufacturing an inorganic ion exchanger for the selective extraction of lithium from lithium-containing natural and technological brines is performed by interacting at least one soluble niobium(V) compound with an acid that contains at least one iron(III) compound, thus forming an electrolyte that contains a hydrated niobium(V) oxide and a hydrated iron(III) oxide, which co-precipitate and form a precipitate of a mixed hydrated niobium(V) and iron(III) oxide. The precipitate is washed, an excess of the electrolyte is removed, and the product is granulated with subsequent conversion into a lithium form, which is calcined and is converted to an H-form of the inorganic ion exchanger by treating thereof with an acid solution. the addition of Fe3+ ions contained in the iron(III) compound to the sorbent composition allows obtaining inorganic ion-exchange sorbents with a specific structure, which provides high selectivity, especially for lithium ions.

公开(公告)号：US11964876B2

公开(公告)日：2024-04-23

申请号：US17673624

申请日：2022-02-16

Applicant: Lilac Solutions, Inc.

Inventor： David Henry Snydacker ,  Amos Indranada ,  Alysia Lukito

IPC: C01D15/06 ,  B01J39/02 ,  B01J39/05 ,  B01J39/10 ,  B01J39/20 ,  B01J47/011 ,  B01J47/04 ,  B01J49/53

CPC classification number: C01D15/06 ,  B01J39/02 ,  B01J39/05 ,  B01J39/10 ,  B01J39/20 ,  B01J47/011 ,  B01J47/04 ,  B01J49/53

Abstract: The present invention relates to recovery of lithium from liquid resources to produce lithium solutions while limiting impurity precipitation in the lithium solutions.

公开(公告)号：US20240123436A1

公开(公告)日：2024-04-18

申请号：US17956656

申请日：2022-09-29

Applicant: Pavel Kudryavtsev ,  Nikolai Kudriavtsev ,  Iiiya Kudryavtsev

Inventor： Pavel Kudryavtsev ,  Nikolai Kudriavtsev ,  Iiiya Kudryavtsev

IPC: B01J39/10 ,  B01J39/02 ,  B01J49/53 ,  C01D15/00 ,  C01G45/12 ,  C22B3/42 ,  C22B26/12

CPC classification number: B01J39/10 ,  B01J39/02 ,  B01J49/53 ,  C01D15/00 ,  C01G45/1221 ,  C22B3/42 ,  C22B26/12 ,  C01P2002/50

Abstract: The proposed method relates to producing inorganic sorbents for extracting lithium from lithium-containing natural and industrial brines. The method consists of a plurality of sequential steps, which include contacting a mixture of a soluble manganese (II) salt and aluminum (III) salt with an alkali solution in the presence of an alkali metal permanganate to obtain a precipitate of a mixed hydrated manganese (III), manganese (IV), and aluminum (III) oxide. After multiple reactions and conversions of intermediate products of the mixed hydrated manganese (III), manganese (IV), and aluminum (III) oxide, the final product is obtained as an ion exchanger in the H-form of high selectivity to lithium.

公开(公告)号：US20230234848A1

公开(公告)日：2023-07-27

申请号：US17918978

申请日：2021-04-16

Applicant: RECION TECHNOLOGIES, INC.

Inventor： Salman SAFARIMOHSENABAD ,  Daniel S. ALESSI

IPC: C01B25/30 ,  C01D15/02 ,  C01D15/08 ,  B01J39/02 ,  B01J39/10 ,  B01J49/53 ,  C22B26/12 ,  C22B3/42 ,  B01D15/36 ,  B01D15/20 ,  B01D15/42 ,  C25B1/14 ,  C25B1/16

CPC classification number: C01B25/306 ,  C01B25/303 ,  C01D15/02 ,  C01D15/08 ,  B01J39/02 ,  B01J39/10 ,  B01J49/53 ,  C22B26/12 ,  C22B3/42 ,  B01D15/362 ,  B01D15/203 ,  B01D15/426 ,  C25B1/14 ,  C25B1/16 ,  C01P2006/80

Abstract: A method of producing lithium phosphate from a lithium source includes the step of (a) concentrating the lithium to produce a lithium concentrate, with an ion exchange sorbent, and (b) reacting the lithium concentrate with phosphate anions to produce lithium phosphate. The lithium phosphate may then be converted to lithium hydroxide or lithium 5 carbonate by reaction with calcium hydroxide or by electrolysis.

公开(公告)号：US11638916B1

公开(公告)日：2023-05-02

申请号：US17959086

申请日：2022-10-03

Applicant: Clayton McMonigle Jones

Inventor： Clayton McMonigle Jones

IPC: B01J47/06 ,  B01J39/04 ,  B01J39/02 ,  B01J39/20 ,  B01J39/10 ,  C02F1/42 ,  C02F1/48 ,  C02F1/00 ,  C01D15/00 ,  C02F101/10

Abstract: Improvements in a lithium-ion extraction apparatus to extract lithium-ion from water and more specifically salt or brine water. The extraction of lithium-ion utilizing electromagnetic separation into a sorbent shortens the extraction time and minimizes environmental impact. The sorbent is typically a polymer that is in solution with the brine where direct contact with the brine water with the sorbent extracts lithium-ions. The fixed and magnetic field magnetic field increases the absorption in the sorbent by energizing the sorbent. The sorbent is in the form of porous beads that have selective lithium-ion affinity in a continuous solid-phase extraction process. The lithium-ion extraction apparatus includes fluid flow, agitation, pressure, and temperature control of the brine solution. The flow rate alters and controls the dwell time that the brine solution is in proximity to the electromagnets.

公开(公告)号：US11358875B2

公开(公告)日：2022-06-14

申请号：US17364530

申请日：2021-06-30

Applicant: Lilac Solutions, Inc.

Inventor： David Henry Snydacker ,  Amos Indranada ,  Alysia Lukito

IPC: C01D15/06 ,  B01J39/05 ,  B01J39/20 ,  B01J47/04 ,  B01J39/10 ,  B01J49/53 ,  B01J47/011 ,  B01J39/02

Abstract: The present invention relates to recovery of lithium from liquid resources to produce lithium solutions while limiting impurity precipitation in the lithium solutions.