Recovery of uranium from wet process phosphoric acid by liquid-solid ion
exchange
    72.
    发明授权
    Recovery of uranium from wet process phosphoric acid by liquid-solid ion exchange 失效
    通过液固离子交换从湿法磷酸中回收铀

    公开(公告)号:US4599221A

    公开(公告)日:1986-07-08

    申请号:US579544

    申请日:1984-02-13

    CPC classification number: C22B60/0265

    Abstract: Recovery of uranium from crude wet process phosphoric acid (WPA) by cation exchange using as cation exchanger a resin comprising active amino phosphonic or hydroxy phosphonic groups linked to a matrix. The operational steps comprise reduction of uranium in the WPA to the tetravalent state, contacting the WPA with the cation exchange resin to load the latter with tetravalent uranium, displacing Fe.sup.+2 from the resin, washing the resin with aqueous ammonia, eluting the resin with a carbonate-bicarbonate solution and precipitating uranium from the eluate.

    Abstract translation: 通过阳离子交换使用粗制湿法磷酸(WPA)回收铀,使用与基体连接的活性氨基膦酸或羟基膦酸基团的树脂。 操作步骤包括将WPA中的铀还原成四价态,使WPA与阳离子交换树脂接触,将其与四价铀负载,从树脂中取代Fe + 2,用氨水洗涤树脂,用树脂洗脱树脂 碳酸盐 - 碳酸氢盐溶液,并从洗脱液中沉淀出铀。

    Vinyl substituted cyclic polyethers and addition polymers thereof
    78.
    发明授权
    Vinyl substituted cyclic polyethers and addition polymers thereof 失效
    乙烯基取代的环状聚醚及其加成聚合物

    公开(公告)号:US4331785A

    公开(公告)日:1982-05-25

    申请号:US107813

    申请日:1979-12-28

    Abstract: Compounds represented by the formula ##STR1## and addition polymers thereof where m is an integer from 2 to about 10, X- is chlorine, hydroxy, carboxy or-AC-R).dbd.CH.sub.2-R is hydrogen or methyl, -R' is an ethylene or propylene group and-AC-R).dbd.CH.sub.2is one of ##STR2## These compounds and their addition polymers form complexes with alkali metal or alkaline earth metal salts and permit the concentration of aqueous solutions of said salts. For example, a compound of the formula ##STR3## is polymerized with an azobis(isobutyronitrile) catalyst to form addition polymers of the repeating unit ##STR4## When cross-linked, rendering it water-insoluble, such an addition polymer concentrates an aqueous solution of sodium chloride when contacted with same at about 0.degree. C.

    Abstract translation: 式中的化合物及其加成聚合物,其中m为2-约10的整数,X-为氯,羟基,羧基或-AC-R)= CH 2 -R为氢或甲基,-R'为 乙烯或丙烯基和-AC-R)= CH 2是这些化合物及其加成聚合物与碱金属或碱土金属盐形成络合物并允许浓缩所述盐的水溶液。 例如,将式(IMAGE)化合物与偶氮双(异丁腈)催化剂聚合以形成重复单元的加成聚合物。当交联时,使其不溶于水,这种加成聚合物将水溶液 的氯化钠在约0℃下与其接触

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