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公开(公告)号:US20230046550A1
公开(公告)日:2023-02-16
申请号:US17756363
申请日:2020-11-10
Applicant: ExxonMobil Research and Engineering Company
Inventor: James N. Coffey , Jennifer J. Austin , Madelyn Bekker , Adam P. Hamilton , Ronald G. White , Paul Hamilton
IPC: C09J123/08
Abstract: Embodiments of the present disclosure generally relate to adhesive compositions, and more particularly, to the use of polyolefin adhesive compositions for hot melt adhesive applications. In an embodiment, a composition includes a polymer, a resin, and an olefin wax. In an embodiment, an olefin wax may be a linear alpha olefin.
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公开(公告)号:US20220401922A1
公开(公告)日:2022-12-22
申请号:US17349986
申请日:2021-06-17
Applicant: ExxonMobil Research and Engineering Company
Inventor: Scott J. Weigel , Megan E. Witzke , Wesley Sattler , Brandon M. Carcuffe , Jihad M. Dakka , Ryan S. Dugan
Abstract: Tungstated zirconium catalysts for paraffin isomerization may comprise: a mixed metal oxide that is at least partially crystalline and comprises tungsten, zirconium, and a variable oxidation state metal selected from Fe, Mn, Co, Cu, Ce, Ni, and any combination thereof. The mixed metal oxide comprises about 5 wt. % to about 25 wt. % tungsten, about 40 wt. % to about 70 wt. % zirconium, and about 0.01 wt. % to about 5 wt. % variable oxidation state metal, each based on a total mass of the mixed metal oxide. The mixed metal oxide has a total surface area of about 50 m2/g or greater as measured according to ISO 9277, and at least one of the following: an ammonia uptake of about 0.05 to about 0.3 mmol/g as measured by temperature programmed adsorption/desorption, or a collidine uptake of about 100 μmol/g or greater as measured gravimetrically.
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公开(公告)号:US20220401851A1
公开(公告)日:2022-12-22
申请号:US17776423
申请日:2020-11-11
Applicant: EXXONMOBIL RESEARCH AND ENGINEERING COMPANY
Inventor: Narasimhan SUNDARAM
IPC: B01D3/14
Abstract: Systems and methods are provided for improving the operation of a divided wall column for performing distillations. The systems and methods include using a separation stage in a fluid flow pathway for transporting an enriched intermediate stream from a first side of a dividing wall to a second side of a dividing wall. By using a separation stage, the benefit of transporting an enriched intermediate stream can be achieved without requiring precise knowledge of the local concentration profile on the first side of the dividing wall.
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公开(公告)号:US20220316313A1
公开(公告)日:2022-10-06
申请号:US17702886
申请日:2022-03-24
Applicant: ExxonMobil Research and Engineering Company
Inventor: Liezhong GONG , Thomas S. COPELAND
IPC: E21B47/00
Abstract: A hybrid model for predicting corrosion in a system integrates a physics-based model developed using laboratory data and a machine-learning model developed using in-field data. Said hybrid model may be used, for example, in methods by: determining a physics-based measurement of corrosion using a physics-based model for a fluid's corrosion of a substrate based, at least in part on, lab-based measurements; determining a machine learning-based measurement of corrosion using a machine learning-based model for the fluid's corrosion of the substrate based, at least in part on, in-field-based measurements; and applying an ensemble method to the physics-based measurement of corrosion and the machine learning-based measurement of corrosion to yield an estimated measure of corrosion of the substrate. The hybrid model may be applied to corrosion mechanisms that occur in, for example, hydrocarbon transportation systems, hydrocarbon production systems, hydrocarbon refining systems, and alkylation systems.
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公开(公告)号:US20220314207A9
公开(公告)日:2022-10-06
申请号:US17217782
申请日:2021-03-30
Inventor: Yuriy Román-Leshkov , Randall J. Meyer , Pedro M. Serna Merino , Mark Sullivan , Kimberly Dinh
Abstract: Catalytic compositions and sequential catalytic methods are generally described. in some embodiments, a composition comprises a first catalyst comprising a Cu-modified zeolite, and a second catalyst capable of a coupling reaction between (a) an intermediate resulting from a reaction of a reactant at the first catalyst, and (b) a co-reagent, wherein a rate of diffusion of the co-reagent within one or more cages and/or pores of the first catalyst is lower than a rate of diffusion of the intermediate within the one or more cages and/or pores of the first catalyst.
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公开(公告)号:US20220305456A1
公开(公告)日:2022-09-29
申请号:US17607168
申请日:2020-05-26
Applicant: ExxonMobil Research and Engineering Company
Inventor: Joseph M. Falkowski , Yogesh V. Joshi , Mary S. Abdulkarim , Simon C. Weston
Abstract: Metal-organic framework materials (MOFs) are highly porous entities comprising a multidentate organic ligand coordinated to multiple metal centers, typically as a coordination polymer. Some highly porous MOFs lack stability at ambient conditions. MOFs having ambient condition stability may comprise a plurality of metal clusters (M4O clusters, M=a metal), and a plurality of 4-(1H-pyrazol-4-yl)benzoate ligands coordinated to the plurality of metal clusters to define an at least partially crystalline network structure having a plurality of internal pores. Methods for synthesizing these MOFs may comprise combining a metal source, such as a preformed metal cluster, with 4-(1H-pyrazol-4-yl)benzoic acid, and reacting the preformed metal cluster with the 4-(1H-pyrazol-4-yl)benzoic acid to form a MOF having an at least partially crystalline network structure with a plurality of internal pores defined therein and comprising a plurality of metal clusters coordinated to a multidentate organic ligand comprising 4-(1H-pyrazol-4-yl)benzoate.
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公开(公告)号:US20220299951A1
公开(公告)日:2022-09-22
申请号:US17697167
申请日:2022-03-17
Applicant: ExxonMobil Research and Engineering Company
Inventor: Jitendra V. KADAM , George A. KHOURY , Clayton R. CARR , Trevor S. POTTORF , Onur ONEL , Victoria G. YAO
Abstract: Methods for building models that estimate compositional properties of a process may include (a) receiving data relating to a process; (b) cleaning the data by identifying and removing outlying data points from the data; and conditioning the data; (c) identifying inferential model parameters comprising a parameter selected from the group consisting of: a compositional property of the process as a model output that is not part of the data, operational constraints of the process, interactions between process variables of the chemical process, and any combination thereof; (d) building one or more inferential models based on the cleaned data and the inferential model parameters; and (e) outputting the one or more models and the corresponding validation metric.
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公开(公告)号:US11364479B2
公开(公告)日:2022-06-21
申请号:US16287152
申请日:2019-02-27
Applicant: ExxonMobil Research and Engineering Company
Inventor: Joseph M. Falkowski , Mobae Afeworki , David C. Calabro , Yi Du , Himanshu Gupta , Simon C. Weston
IPC: B01J20/22 , B01D53/04 , C01B37/00 , B01J20/30 , C01B39/02 , C07C7/13 , C10G25/03 , B01D53/02 , C10G25/00 , C01B39/00
Abstract: Disclosed are zeolitic imidazolate framework (ZIF) compositions in which at least a portion of the ligands in its shell have been exchanged with other ligands, and methods of making such shell-ligand-exchanged ZIFs. Also disclosed is the use of such shell-ligand-exchanged ZIFs in hydrocarbon separation processes.
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公开(公告)号:US20220173421A1
公开(公告)日:2022-06-02
申请号:US17677363
申请日:2022-02-22
Inventor: Jonathan Rosen , Heather A. Elsen , Gabor Kiss , William A. Lamberti , William C. Horn , Anding Zhang , Timothy C. Geary , Adam Franco , Abdelkader Hilmi
IPC: H01M8/14 , H01M8/0202 , H01M8/0289 , H01M8/04276 , H01M8/04858 , H01M8/0612
Abstract: An elevated target amount of electrolyte is used to initially fill a molten carbonate fuel cell that is operated under carbon capture conditions. The increased target electrolyte fill level can be achieved in part by adding additional electrolyte to the cathode collector prior to start of operation. The increased target electrolyte fill level can provide improved fuel cell performance and lifetime when operating a molten carbonate fuel cell at high current density with a low-CO2 content cathode input stream and/or when operating a molten carbonate fuel cell at high CO2 utilization.
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公开(公告)号:US20220169624A1
公开(公告)日:2022-06-02
申请号:US17597888
申请日:2020-06-30
Applicant: ExxonMobil Research and Engineering Company
Inventor: Kun Wang , Timothy D. Shaffer
IPC: C07D301/19
Abstract: Processes and systems for producing olefin epoxides with three or more carbon atoms by oxidation of the corresponding branched hydrocarbons using oxygen are disclosed. An example process for producing olefin epoxides may include oxidizing a branched alkane to produce at least an organic hydroperoxide. The example process may further include epoxidizing a branched alkene by a catalytic reaction with least a portion of the organic hydroperoxide to produce at least an olefin epoxide and an alcohol. The example process may further include converting at least a portion of the alcohol to either additional branched alkane and/or additional branched alkene.
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