公开(公告)号：US08845931B2

公开(公告)日：2014-09-30

申请号：US13279394

申请日：2011-10-24

Applicant: Jiang-Jen Lin ,  Ying-Nan Chan ,  Wei-Li Lin

Inventor： Jiang-Jen Lin ,  Ying-Nan Chan ,  Wei-Li Lin

IPC: H01B1/02 ,  H01B1/22 ,  B05D5/12

CPC classification number: B05D5/12 ,  B82Y30/00 ,  C09D5/24 ,  H01B1/22 ,  Y10T428/249921

Abstract: A method for preparing a nanometal-polymer composite conductive film includes the steps of (1) mixing a metal oxide with a polymer solution; (2) coating a substrate with a solution resulting from step (1), followed by drying the resultant solution to form a film; (3) performing thermal treatment on the film formed in step (2); and (4) sintering the film thermally treated in step (3). The method dispenses with any reducing agent or dispersing agent but allows nanometallic particles to be formed in situ and thereby reduces surface resistance of the polymer film efficiently.

Abstract translation: 制备纳米金属 - 聚合物复合导电膜的方法包括以下步骤：（1）将金属氧化物与聚合物溶液混合; （2）用步骤（1）得到的溶液涂布基材，然后干燥所得溶液以形成薄膜; （3）对在步骤（2）中形成的膜进行热处理; 和（4）烧结步骤（3）中热处理的薄膜。 该方法分配任何还原剂或分散剂，但允许在原位形成纳米金属颗粒，从而有效降低聚合物膜的表面电阻。

公开(公告)号：US08663381B2

公开(公告)日：2014-03-04

申请号：US12218871

申请日：2008-07-18

Applicant: Jiang-Jen Lin ,  Yi-Fen Lan ,  Yen-Chi Hsu

Inventor： Jiang-Jen Lin ,  Yi-Fen Lan ,  Yen-Chi Hsu

IPC: C04B14/04

CPC classification number: C09B67/0007 ,  C08K3/346 ,  C08K2201/016 ,  C09B67/0002 ,  C09D7/61 ,  C09D7/80 ,  C09D17/002 ,  C09D17/003

Abstract: A pigment is dispersed in a solvent by mixing the pigment nanoparticles with clay in a layered or platelet form and mixing the resultant mixture with the solvent. The method is based on geometric inhomogeneity and mutually exclusive aggregation. The layered or platelet clay having a high aspect ratio is provided to hinder aggregation of the pigment nanoparticles. The pigment nanoparticles can be stably dispersed in a matrix containing an organic solvent and water without aggregation again.

Abstract translation: 通过将颜料纳米颗粒与粘土以分层或片状形式混合将颜料分散在溶剂中，并将所得混合物与溶剂混合。 该方法基于几何不均匀性和互斥聚合。 提供具有高纵横比的层状或血小板粘土以阻碍颜料纳米颗粒的聚集。 颜料纳米颗粒可以稳定地分散在含有有机溶剂和水的基质中，而不再聚集。

公开(公告)号：US08647513B2

公开(公告)日：2014-02-11

申请号：US13039335

申请日：2011-03-03

Applicant: Jiang-Jen Lin ,  Ru-Siou Hsu

Inventor： Jiang-Jen Lin ,  Ru-Siou Hsu

IPC: C02F1/28

CPC classification number: C02F1/281 ,  B01D17/0202 ,  B01J20/10 ,  B01J20/12 ,  B01J20/3204 ,  B01J20/3272 ,  C02F1/285 ,  C02F1/288 ,  C02F1/681 ,  C02F2001/425 ,  C02F2101/32 ,  C10G25/003 ,  C10G33/04

Abstract: The present invention provides a method for collecting oil with a modified clay. By mixing the modified clay and oil, the oil can be adsorbed to the clay. The modified clay is obtained by intercalating a hydrophobic polymer such as acidified poly(oxyalkylene)-amine into layered silicate clay, mica or talc to enlarge the interlayer space. The modified clay thus becomes hydrophobic and adsorption to the oil is promoted.

Abstract translation: 本发明提供一种用改性粘土收集油的方法。 通过混合改性粘土和油，油可以吸附到粘土上。 改性粘土是通过将层状硅酸盐粘土，云母或滑石中的疏水性聚合物如酸化的聚（氧化烯） - 胺嵌入而获得的，以扩大层间空间。 因此，改性粘土变得疏水，促进了对油的吸附。

公开(公告)号：US20130062577A1

公开(公告)日：2013-03-14

申请号：US13310837

申请日：2011-12-05

Applicant: JIANG-JEN LIN ,  CHAO-PO HSU

Inventor： JIANG-JEN LIN ,  CHAO-PO HSU

IPC: H01B1/24 ,  B82Y30/00

CPC classification number: B82Y30/00 ,  H01B1/24

Abstract: A carbon nanotube suspension includes a plurality of carbon nanotubes and a block copolymer dispersant which are evenly distributed in a solvent, wherein the block copolymer includes a hydrophobic block and a functional group block, such that the carbon nanotubes react with the functional group block to form covalent bonds directly without undergoing chemical modification. The carbon nanotube suspension is effective in preparing a superhydrophobic film without undergoing chemical modification or the presence of a fluorine-containing compound. The superhydrophobic film thus prepared is of a tough stable structure and remains superhydrophobic when subjected to lengthy immersion treatment, exposure to a strong acid-base environment, or physical abrasion and polishing.

Abstract translation: 碳纳米管悬浮液包括均匀分布在溶剂中的多个碳纳米管和嵌段共聚物分散剂，其中嵌段共聚物包括疏水嵌段和官能团嵌段，使得碳纳米管与官能团嵌段反应形成 直接进行共价键而不进行化学修饰。 碳纳米管悬浮液在不经历化学改性或含氟化合物的存在下制备超疏水膜是有效的。 如此制备的超疏水膜具有坚韧的稳定结构，当经受长时间的浸渍处理，暴露于强酸碱环境或物理磨损和抛光时，其保持超疏水性。

公开(公告)号：US08252342B2

公开(公告)日：2012-08-28

申请号：US12826533

申请日：2010-06-29

Applicant: Jiang-Jen Lin ,  Yueh-Hsien Wu

Inventor： Jiang-Jen Lin ,  Yueh-Hsien Wu

IPC: A01N59/16 ,  A01N59/06 ,  A01N59/00 ,  C01B33/26 ,  A61K33/38

CPC classification number: B22F9/24 ,  B22F1/007 ,  C01B33/40 ,  C22C29/005

Abstract: A method for producing a complex of metallic nanoparticles and inorganic clay and an organic promoter, wherein the organic promoter is ethanolamine, for example, monoethanolamine (MEA), diethanolamine (DEA) or triethanolamine (TEA). The metallic nanoparticles produced by this method can be stably and uniformly dispersed without adding other reducing agent or dispersant.

Abstract translation: 一种制备金属纳米粒子和无机粘土和有机促进剂的络合物的方法，其中有机促进剂是乙醇胺，例如单乙醇胺（MEA），二乙醇胺（DEA）或三乙醇胺（TEA）。 通过该方法制备的金属纳米颗粒可以稳定均匀地分散而不添加其它还原剂或分散剂。

公开(公告)号：US20120065053A1

公开(公告)日：2012-03-15

申请号：US13300585

申请日：2011-11-20

Applicant: Jiang-Jen Lin ,  Yen-Chi Hsu ,  Ming-Li Chiang ,  Chien-Chia Chu

Inventor： Jiang-Jen Lin ,  Yen-Chi Hsu ,  Ming-Li Chiang ,  Chien-Chia Chu

IPC: B01J31/26 ,  C08K3/22 ,  B01J31/28 ,  B01J31/38 ,  B01J21/06 ,  C08G73/02 ,  B01J31/06 ,  B82Y30/00

CPC classification number: B01F17/0007 ,  B01F17/005

Abstract: The present invention discloses an inorganic/organic mixed component (I/O) dispersant and applications thereof, which is primarily applied to dispersing nanoparticles of metal oxides. The I/O dispersant of the present invention can be a composite of inorganic clay and an organic surfactant, a composite of inorganic clay and polyoxyalkylene-amine, or a composite of inorganic clay, polyisobutylene succinic anhydride (PIB-SA) and hydrochloric acid salt or tetraalkyl quaternary salt of polyoxyalkylene-amine, or fatty amines. By mixing with the I/O dispersant of the present invention, nanoparticles of a metal oxide can be uniformly dispersed without aggregation particularly at high solid content. The dispersion has a lower viscosity and is relatively stable in storage even at high temperature.

Abstract translation: 本发明公开了一种主要用于分散金属氧化物纳米颗粒的无机/有机混合组分（I / O）分散剂及其应用。 本发明的I / O分散剂可以是无机粘土和有机表面活性剂的复合物，无机粘土和聚氧化烯胺的复合物，或无机粘土，聚异丁烯琥珀酸酐（PIB-SA）和盐酸盐 或聚氧化烯 - 胺的四烷基季盐，或脂肪胺。 通过与本发明的I / O分散剂混合，金属氧化物的纳米颗粒可以均匀地分散而不聚集，特别是在高固体含量下。 分散体具有较低的粘度，即使在高温下也具有相对稳定的储存性。

公开(公告)号：US20110288239A1

公开(公告)日：2011-11-24

申请号：US13195022

申请日：2011-08-01

Applicant: Jiang-Jen Lin ,  Wei-Cheng Tsai ,  Yen-Chi Hsu ,  Wen-Hsin Chang

Inventor： Jiang-Jen Lin ,  Wei-Cheng Tsai ,  Yen-Chi Hsu ,  Wen-Hsin Chang

IPC: C08F8/32 ,  C07D403/12 ,  C08F220/08 ,  C07D307/60 ,  C07C275/24 ,  C07C235/84 ,  C07C235/78

CPC classification number: C08F26/00

Abstract: The present invention discloses a polymeric polyamine which can be produced by polymerizing polyoxyalkylene-amine and a linker. The linker can be anhydride, carboxylic acid, epoxy, isocyanate or poly(styrene-co-maleic anhydride) copolymers (SMA). The present invention also discloses a method for stabilizing the Ag nanoparticles with polymeric polyamine. The polymeric polyamine serving as a stabilizer or dispersant is mixed with a water solution of silver salt and then a reducer is provided to reduce the silver ions and form an organic or a water solution of Ag nanoparticles. Water or solvent of this solution can be further removed through a heating, freezing or decompression process, and thus solid content of the solution can be increased. The concentrated solution also can be diluted to obtain a stable dispersion without aggregation.

Abstract translation: 本发明公开了一种聚合多胺，其可通过聚合聚氧亚烷基 - 胺和连接体而制备。 接头可以是酐，羧酸，环氧，异氰酸酯或聚（苯乙烯 - 共 - 马来酸酐）共聚物（SMA）。 本发明还公开了一种用聚合多胺稳定Ag纳米颗粒的方法。 用作稳定剂或分散剂的聚合多胺与银盐水溶液混合，然后提供还原剂以还原银离子并形成Ag纳米颗粒的有机或水溶液。 该溶液的水或溶剂可以通过加热，冷冻或减压方法进一步除去，从而可以提高溶液的固体含量。 浓缩溶液也可以稀释以获得稳定的分散体而不凝聚。

公开(公告)号：US07935779B2

公开(公告)日：2011-05-03

申请号：US12044309

申请日：2008-03-07

Applicant: Shenghong A. Dai ,  Jiang-Jen Lin ,  Kuan-Liang Wei

Inventor： Shenghong A. Dai ,  Jiang-Jen Lin ,  Kuan-Liang Wei

IPC: C08G69/26 ,  C08G69/00 ,  C08G73/10

CPC classification number: C08G73/16 ,  C08G73/00 ,  C08G73/1003 ,  Y10S525/907

Abstract: Disclosed are processes for synthesizing polyimides by a sequential self-repetitive reaction between poly (aryl carbodiimide) (p-CDI) or aryl diisocyanates with dianhydrides.

Abstract translation: 公开了通过聚（芳基碳二亚胺）（p-CDI）或芳基二异氰酸酯与二酸酐之间的顺序自重反应合成聚酰亚胺的方法。

公开(公告)号：US20090149592A1

公开(公告)日：2009-06-11

申请号：US12258402

申请日：2008-10-25

Applicant: Jiang-Jen Lin ,  Yi-Lin Liao ,  Chien-Chia Chu ,  Chih-Wei Chiu

Inventor： Jiang-Jen Lin ,  Yi-Lin Liao ,  Chien-Chia Chu ,  Chih-Wei Chiu

IPC: C01B33/20 ,  C08K3/34 ,  C08K3/08

CPC classification number: B22F9/24 ,  B22F1/0022 ,  B22F2999/00 ,  B82Y30/00 ,  B22F1/0059

Abstract: The present invention provides a method for reducing metal ions (for example, silver ions) and stably dispersing metal nanoparticles by nanosilicate platelets. An organic dispersant, nanosilicate platelets and a metal ionic solution are mixed to perform a reductive reaction, wherein the organic dispersant is tri-sodium citrate dihydrate (SCD), chitosan or polyvinyl pyrrolidone (PVP), to produce a mixture of stably dispersed metal nanoparticles.

Abstract translation: 本发明提供了还原金属离子（例如银离子）并通过纳米硅酸盐片稳定分散金属纳米粒子的方法。 将有机分散剂，纳米硅酸盐片和金属离子溶液混合以进行还原反应，其中有机分散剂是柠檬酸三钠二水合物（SCD），壳聚糖或聚乙烯吡咯烷酮（PVP）），以产生稳定分散的金属纳米颗粒 。

公开(公告)号：US07495043B2

公开(公告)日：2009-02-24

申请号：US11147761

申请日：2005-06-08

Applicant: Jiang-Jen Lin ,  Chung-Ming Tsai

Inventor： Jiang-Jen Lin ,  Chung-Ming Tsai

IPC: C08K3/34 ,  C08L61/00

CPC classification number: B82Y30/00 ,  C01B33/126 ,  C01B33/44 ,  Y10T428/2982

Abstract: The present invention discloses a method for producing a clay/AMO complex by modifying layered inorganic silicate clay with the intercalating agent AMO (amine-terminated Mannich oligomer). The AMO is prepared by polymerizing polyoxyalkylene amine having molecular weight over 1000, p-cresol and formaldehyde. The present invention also discloses a method for producing nanosilicate plates by extracting the AMO from the above complex with a hydroxide or a chloride of alkali metal or alkaline-earth metal. The extracted AMO can be recycled for reusing.

Abstract translation: 本发明公开了一种用嵌入剂AMO（胺封端的曼尼式低聚物）改性层状无机硅酸盐粘土制备粘土/ AMO配合物的方法。 通过聚合分子量大于1000的聚氧化烯胺，对甲酚和甲醛来制备AMO。 本发明还公开了一种通过用碱金属或碱土金属的氢氧化物或氯化物从上述配合物中提取AMO来制备纳米硅酸盐板的方法。 提取的AMO可以回收再利用。