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1.发明申请公开(公告)号：US20060193767A1
公开(公告)日：2006-08-31
申请号：US11347578
申请日：2006-02-06
Applicant: Pascal Raybaud , Francois Ropital
Inventor： Pascal Raybaud , Francois Ropital
IPC: C01B3/08
CPC classification number: C01B3/001 , C01B3/0026 , C01B3/0031 , C01B6/04 , C01B21/0602 , C01B21/0612 , C01B21/0923 , F17C11/005 , Y02E60/321 , Y02E60/327 , Y02E60/364
Abstract: A process for the reversible storage of hydrogen, comprising bringing into contact a material that consists of magnesium elements and nitrogen elements with gaseous hydrogen leading to the formation of an amide or corresponding hydrides, comprises the use of a balanced system corresponding to the formula: Mg3N2
Abstract translation: 一种用于氢的可逆储存的方法，包括使由镁元素和氮元素组成的材料与导致形成酰胺或相应的氢化物的气态氢接触的材料包括使用对应于下式的平衡系统： ？in-line-formula description =“In-line Formulas”end =“lead”？> Mg 3 N 2 ）<2> + 2MgHn <？in-line-formula description =“In-line Formulas”end =“tail”？>其中n是与氢化物的化学计量相对应的氢原子数， 形成氢化物。 所述材料还可以以少量的比例包含选自Sc，Ti，V，Cr，Mn，Fe，Co，Ni，Cu，Zn中的至少一种元素周期表第3至12族的过渡金属和 钯
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2.发明授权Olefin oligomerization method involving a catalytic system based on organometallic complexes and a porous solid 有权涉及基于有机金属配合物和多孔固体的催化体系的烯烃低聚方法公开(公告)号：US09101919B2
公开(公告)日：2015-08-11
申请号：US12994958
申请日：2009-04-29
Applicant: Herve Toulhoat , Theodorus De Bruin , Pascal Raybaud
Inventor： Herve Toulhoat , Theodorus De Bruin , Pascal Raybaud
IPC: C07C2/24 , B01J31/22 , B01J31/06 , B01J31/16 , B82Y30/00 , C07C2/32 , C07C2/34 , B01J21/18 , B01J29/04 , B01J29/06 , B01J29/08 , B01J29/70 , B01J29/83
CPC classification number: B01J31/2295 , B01J21/185 , B01J29/041 , B01J29/06 , B01J29/08 , B01J29/70 , B01J29/83 , B01J31/069 , B01J31/1691 , B01J2229/34 , B01J2231/20 , B82Y30/00 , C07C2/32 , C07C2/34 , C07C2529/08 , C07C2529/83 , C07C2531/22
Abstract: The present invention relates to a method of oligomerizing olefins M selectively to oligomers Mn, involving a catalytic system comprising at least one organometallic complex with a metal of groups 4 to 10 of the periodic table of molecular volume Vmo, and a micro- or mesoporous solid whose average micropore diameter Φ is greater than or equal to Φmin defined as a function of the molecular volume (Vmo+nVmM), where n is the number of monomeric olefins strung together upon obtaining the metallacycle intermediate and VmM the molecular volume of the monomeric olefin.
Abstract translation: 本发明涉及一种将烯烃M选择性低聚低聚物Mn的方法，其涉及包含至少一种有机金属配合物与元素周期表第4至10族金属的分子体积Vmo的催化体系，以及微孔或介孔固体 其平均微孔直径Φ大于或等于作为分子体积（Vmo + nVmM）的函数定义的Φmin，其中n是在获得金属环中间体时串联在一起的单体烯烃的数量，VmM是单体烯烃的分子体积 。
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3.发明申请OLEFIN OLIGOMERIZATION METHOD INVOLVING A CATALYTIC SYSTEM BASED ON ORGANOMETALLIC COMPLEXES AND A POROUS SOLID 有权涉及基于有机复合物和多孔固体的催化体系的烯烃低聚化方法公开(公告)号：US20110137100A1
公开(公告)日：2011-06-09
申请号：US12994958
申请日：2009-04-29
Applicant: Herve Toulhoat , Theodorus De Bruin , Pascal Raybaud
Inventor： Herve Toulhoat , Theodorus De Bruin , Pascal Raybaud
IPC: C07C2/24
CPC classification number: B01J31/2295 , B01J21/185 , B01J29/041 , B01J29/06 , B01J29/08 , B01J29/70 , B01J29/83 , B01J31/069 , B01J31/1691 , B01J2229/34 , B01J2231/20 , B82Y30/00 , C07C2/32 , C07C2/34 , C07C2529/08 , C07C2529/83 , C07C2531/22
Abstract: The present invention relates to a method of oligomerizing olefins M selectively to oligomers Mn, involving a catalytic system comprising at least one organometallic complex with a metal of groups 4 to 10 of the periodic table of molecular volume Vmo, and a micro- or mesoporous solid whose average micropore diameter Φ is greater than or equal to Φmin defined as a function of the molecular volume (Vmo+nVmM), where n is the number of monomeric olefins strung together upon obtaining the metallacycle intermediate and VmM the molecular volume of the monomeric olefin.
Abstract translation: 本发明涉及一种将烯烃M选择性低聚低聚物Mn的方法，其涉及包含至少一种有机金属配合物与元素周期表第4至10族金属的分子体积Vmo的催化体系，以及微孔或介孔固体 其平均微孔直径Φ大于或等于作为分子体积（Vmo + nVmM）的函数定义的Φmin，其中n是在获得金属环中间体时串联在一起的单体烯烃的数量，VmM是单体烯烃的分子体积 。
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4.发明授权Method of preparing alcohol esters from triglycerides and alcohols using heterogeneous catalysts based on nitrogen-containing metallophosphates 有权使用基于含氮金属磷酸盐的非均相催化剂从甘油三酯和醇制备醇酯的方法公开(公告)号：US08686170B2
公开(公告)日：2014-04-01
申请号：US13150765
申请日：2011-06-01
Applicant: Delphine Bazer-Bachi , Francois Chevire , Vincent Lecocq , Erwan Ray , Pascal Raybaud , Franck Tessier
Inventor： Delphine Bazer-Bachi , Francois Chevire , Vincent Lecocq , Erwan Ray , Pascal Raybaud , Franck Tessier
IPC: C11C3/00
Abstract: A method of preparing a composition of alcohol esters of linear monocarboxylic acids with 6 to 26 carbon atoms from a vegetable or animal oil, neutral or acid, virgin or recycled, with monoalcohols having 1 to 18 carbon atoms, in the presence of a catalyst of nitrogen-containing metallophosphate type.
Abstract translation: 一种在具有1至18个碳原子的一元醇的植物或动物油，中性或酸性，原始或循环的碳原子数6至26的直链单羧酸的醇酯组合物的存在下， 含氮金属磷酸盐型。
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5.发明申请公开(公告)号：US20120004433A1
公开(公告)日：2012-01-05
申请号：US13150765
申请日：2011-06-01
Applicant: Delphine BAZER-BACHI , Francois Chevire , Vincent Lecocq , Erwan Ray , Pascal Raybaud , Franck Tessier
Inventor： Delphine BAZER-BACHI , Francois Chevire , Vincent Lecocq , Erwan Ray , Pascal Raybaud , Franck Tessier
IPC: C11C3/00
Abstract: A method of preparing a composition of alcohol esters of linear monocarboxylic acids with 6 to 26 carbon atoms from a vegetable or animal oil, neutral or acid, virgin or recycled, with monoalcohols having 1 to 18 carbon atoms, in the presence of a catalyst of nitrogen-containing metallophosphate type.
Abstract translation: 一种在具有1至18个碳原子的一元醇的植物或动物油，中性或酸性，原始或循环的碳原子数6至26的直链单羧酸的醇酯组合物的存在下， 含氮金属磷酸盐型。
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Patent Agency Ranking
6.发明申请Process for the storage of hydrogen using a system that strikes a balance between an alloy of alkaline metal and silicon and the corresponding hydride 审中-公开使用在碱金属和硅的合金和相应的氢化物之间平衡的系统来储存氢气的方法公开(公告)号：US20060188425A1
公开(公告)日：2006-08-24
申请号：US11347576
申请日：2006-02-06
Applicant: Pascal Raybaud , Francois Ropital
Inventor： Pascal Raybaud , Francois Ropital
CPC classification number: C01B3/001 , C01B3/0031 , Y02E60/327
Abstract: A process for the reversible storage of hydrogen, comprising bringing an alloy of alkaline metal and silicon into contact with gaseous hydrogen leading to the formation of the hydride or corresponding hydrides, comprises the use of at least one balanced system that corresponds to the formula: MXMSiMXMSiHn where M is selected from among Li, Na, or K and in which atomic ratios XM take on the following values: XLi=1
Abstract translation: 一种用于氢的可逆储存的方法，包括使碱金属和硅的合金与导致氢化物或相应的氢化物形成的气态氢接触，包括使用对应于下式的至少一个平衡系统： ？in-line-formula description =“In-line Formulas”end =“lead”？> M
其中M选自Li，Na或K，其中原子比X M M取以下值：<？in-line-formula description =“In 线公式“end =”lead“？> X = 1 <？in-line-formula description =”In-line Formulas“end =”tail“？>
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7.发明授权Catalyst compromising a mixed sulphide and its use for hydrorefining and hydroconverting hydrocarbons 失效催化剂损害混合硫化物及其用于加氢精制和加氢转化碳氢化合物的用途
公开(公告)号：US6149799A
公开(公告)日：2000-11-21
申请号：US7049
申请日：1998-01-14
Applicant: Pascal Raybaud , Herve Toulhoat , Slavik Kasztelan
Inventor： Pascal Raybaud , Herve Toulhoat , Slavik Kasztelan
IPC: B01J23/40 , B01J23/56 , B01J23/648 , B01J23/76 , B01J23/89 , B01J27/04 , B01J27/043 , B01J29/064 , B01J35/00 , B01J37/20 , C10G45/04 , C10G45/06 , C10G45/08 , C10G45/10 , C10G49/00 , C10G49/02 , C10G11/02 , B01J27/02 , B01J27/055 , C10G11/04 , C10G35/06
CPC classification number: B01J23/892 , B01J23/6482 , B01J27/04 , B01J27/043 , B01J35/002 , B01J35/0073 , B01J37/20 , C10G49/02 , B01J23/40 , B01J23/56 , B01J23/76 , B01J23/89
Abstract: The invention concerns a catalyst for hydrorefining and hydroconverting hydrocarbon feeds, comprising a mixed sulphide comprising at least two elements selected from elements with an atomic number selected from the group formed by the following numbers: 3, 11, 12, 19 to 33, 37, to 51, 55 to 83, 87 to 103, characterized in that the mixed sulphide results from a combination of at least one element the sulphide of which has a bond energy between the metal and sulphur of less than 50.+-.3 kcal/mol (209.+-.12 kJ/mol) and at least one element the sulphide of which has a bond energy between the metal and sulphur of more than 50.+-.3 kcal/mol (209.+-.12 kJ/mol), the mixed sulphide thus having a mean bond energy between the metal and sulphur which is in the range 30 to 70 kcal/mol (125 to 293 kJ/mol).
Abstract translation: 本发明涉及用于加氢精制和加氢转化烃进料的催化剂，其包含混合硫化物，该混合硫化物包含至少两种元素，所述元素选自具有选自以下数字形成的基团的原子序数：3,11,12,19至33,37， 至51,55至83,87至103，其特征在于，所述混合硫化物来自至少一种元素的组合，其中硫化物的硫化物的金属和硫之间的键能小于50 +/- 3kcal / mol （209 +/- 12kJ / mol）和至少一种元素，其硫化物在金属和硫之间具有大于50 +/- 3kcal / mol（209 +/- 12kJ / mol）的键能， 因此混合硫化物在金属和硫之间具有在30至70kcal / mol（125至293kJ / mol）范围内的平均键能。
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8.发明授权公开(公告)号：US07867464B2
公开(公告)日：2011-01-11
申请号：US12480257
申请日：2009-06-08
Applicant: Pascal Raybaud , François Ropital
Inventor： Pascal Raybaud , François Ropital
CPC classification number: C01B3/001 , C01B3/0031 , Y02E60/327
Abstract: A process for the reversible storage of hydrogen, comprising bringing an alloy of alkaline metal and silicon into contact with gaseous hydrogen leading to the formation of the hydride or corresponding hydrides, comprises the use of at least one balanced system that corresponds to the formula: MXMSi MXMSiHn where M is selected from among Li, Na, or K and in which atomic ratios XM take on the following values: XLi=1 1≦XNa≦3 1≦XK≦2 n is the number of hydrogen atoms corresponding to the stoichiometry of the hydride or formed hydrides. or to the formula MSiXSi MSiXSiH2XSi+1 where M is selected from among Li, Na, or K and in which the atomic ratio XSi=Si/M takes on a value of 1 to 4.
Abstract translation: 一种用于氢的可逆储存的方法，包括使碱金属和硅的合金与导致形成氢化物或相应的氢化物的气态氢接触，包括使用对应于下式的至少一个平衡系统：MXMSi MXMSiHn其中M选自Li，Na或K，其中原子比XM取以下值：XLi = 1 1＆nlE; XNa＆nlE; 3 1＆nlE; XK＆nlE; 2 n是与化学计量相对应的氢原子数 氢化物或形成的氢化物。 或其中M选自Li，Na或K并且其中原子比XSi = Si / M的值为1至4的式MSiXSi MSiXSiH 2 XSi + 1。
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9.发明申请Process For The Storage Of Hydrogen Using A System That Strikes A Balance Between An Alloy Of Alkaline Metal And SIlicon And The Corresponding Hydride 有权使用在碱金属和SIlicon合金和相应氢化物之间平衡的系统来储存氢的方法公开(公告)号：US20090302270A1
公开(公告)日：2009-12-10
申请号：US12480257
申请日：2009-06-08
Applicant: Pascal Raybaud , Francois Ropital
Inventor： Pascal Raybaud , Francois Ropital
CPC classification number: C01B3/001 , C01B3/0031 , Y02E60/327
Abstract: A process for the reversible storage of hydrogen, comprising bringing an alloy of alkaline metal and silicon into contact with gaseous hydrogen leading to the formation of the hydride or corresponding hydrides, comprises the use of at least one balanced system that corresponds to the formula: MXMSiMXMSiHn where M is selected from among Li, Na, or K and in which atomic ratios XM take on the following values: XLi=1 1≦XNa≦3 1≦XK≦2 n is the number of hydrogen atoms corresponding to the stoichiometry of the hydride or formed hydrides. or to the formula MSiXSiMSiXSiH2XSi+1 where M is selected from among Li, Na, or K and in which the atomic ratio XSi=Si/M takes on a value of 1 to 4.
Abstract translation: 一种用于氢的可逆储存的方法，包括使碱金属和硅的合金与导致形成氢化物或相应的氢化物的气态氢接触，包括使用对应于下式的至少一个平衡系统：MXMSi “img id =”CUSTOM-CHARACTER-00001“he =”2.79mm“wi =”3.13mm“file =”US20090302270A1-20091210-P00001.TIF“img-content =”character“img-format =”tif“/> MXMSiHn其中M选自Li，Na或K，其中原子比XM取以下值：XLi = 1111 n是对应于氢化物或形成的氢化物的化学计量的氢原子数。 或者公式MSiXSi
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10.发明授权公开(公告)号：US07608239B2
公开(公告)日：2009-10-27
申请号：US11347578
申请日：2006-02-06
Applicant: Pascal Raybaud , François Ropital
Inventor： Pascal Raybaud , François Ropital
IPC: C01B3/04
CPC classification number: C01B3/001 , C01B3/0026 , C01B3/0031 , C01B6/04 , C01B21/0602 , C01B21/0612 , C01B21/0923 , F17C11/005 , Y02E60/321 , Y02E60/327 , Y02E60/364
Abstract: A process for the reversible storage of hydrogen, comprising bringing into contact a material that consists of magnesium elements and nitrogen elements with gaseous hydrogen leading to the formation of an amide or corresponding hydrides, comprises the use of a balanced system corresponding to the formula: Mg3N2Mg(NH2)2+2MgHn where n is the number of hydrogen atoms corresponding to the stoichiometry of the hydride or hydrides formed. The material can also comprise, in a minor proportion, at least one transition metal of groups 3 to 12 of the periodic table that is selected from among Sc, Ti, V, Cr, Mn, Fe, Co, Ni, Cu, Zn and Pd.
Abstract translation: 一种用于氢的可逆储存的方法，包括使由镁元素和氮元素组成的材料与导致形成酰胺或相应的氢化物的气态氢接触的材料包括使用对应于下式的平衡系统：Mg 3 N 2 “img id =”CUSTOM-CHARACTER-00001“he =”2.46mm“wi =”2.46mm“file =”US07608239-20091027-P00001.TIF“alt =”custom character“img-content =”character“img-format =“tif”/> Mg（NH 2）2 + 2MgHn其中n是与形成的氢化物或氢化物的化学计量相对应的氢原子数。 所述材料还可以以少量的比例包含选自Sc，Ti，V，Cr，Mn，Fe，Co，Ni，Cu，Zn中的至少一种元素周期表第3至12族的过渡金属和 钯
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