Abstract:
An optical article includes an optical element, a low refractive index layer disposed on the optical element having an effective refractive index of 1.3 or less and a polymeric protective layer disposed on the low refractive index layer. The low refractive index layer includes a binder, a plurality of metal oxide particles dispersed in the binder, and a plurality of interconnected voids. The polymeric protective layer does not increase an effective refractive index of the optical article by greater than 10%.
Abstract:
A hand-tearable masking tape, comprising a plastic backing with a low adhesion backsize on the first major side of the backing and a pressure-sensitive adhesive on the second major side of the backing; wherein the second major side of the backing comprises a microstructured hand-tear pattern and wherein the low adhesion backsize comprises the reaction product of a mercapto-functional silicone macromer.
Abstract:
Siloxane-containing reactive compounds contain moisture-curable alkoxy-silane functional end groups. The siloxane-containing reactive compounds may be prepared from siloxane-containing oxamide compounds or amine compounds. Siloxane-containing polymers may be prepared from the reactive compounds by reaction with water. The siloxane-containing polymers may be release materials or adhesives.
Abstract:
Compounds containing at least one perfluoropolyether segment and at least two oxalylamino groups as well as methods of making these compounds are described. The compounds can be polymeric materials or can be used in the preparation of various copolymeric materials by reaction with compounds having at least two primary or secondary amino groups.
Abstract:
Methods for preparing silicone-containing polymers by essentially adiabatic polymerization methods are disclosed. The polymerization system includes free radically polymerizable monomers. The monomers include ethylenically unsaturated cone-containing monomers and/or mercapto-functional silicones as well as additional free radically polymerizable monomers. The silicone-containing polymers are useful as adhesives or release materials.
Abstract:
A copolymer comprises the reaction product of (a) (meth)acrylate functionalized nanoparticles, (b) vinyl monomer, and (c) silicone macromer. The (meth)acrylate functionalize nanoparticles are selected from the group consisting of silica nanoparticles, zirconia nanoparticles, titania nanoparticles, and combinations thereof.
Abstract:
A composition comprises a copolymer comprising repeating units derived from at least one co-reactant comprising two or more acrylate groups and repeating units derived from a fluoroacrylate comprising the reaction product of: (a) at least one fluorochemical alcohol represented by the formula: C4F9—X—OH wherein: R=hydrogen or an alkyl group of 1 to 4 carbon atoms, m=2 to 8, Rf═CnF2n+1, n=1 to 5, y=0 to 6, and q=1 to 8; (b) at least one unbranched symmetric diisocyanate; and (c) at least one hydroxy-terminated alkyl (meth)acrylate or 2-fluoroacrylate monomer having 2 to about 30 carbon atoms in its alkylene portion; wherein the composition is coatable.
Abstract translation:组合物包含共聚物,其包含衍生自至少一种包含两个或更多个丙烯酸酯基团的共反应物的重复单元和衍生自氟代丙烯酸酯的重复单元,所述重复单元包含以下反应产物:(a)至少一种由式C4F9- X-OH其中:R =氢或1至4个碳原子的烷基,m = 2至8,Rf = C n F 2n + 1,n = 1至5,y = 0至6,q = 1至8; (b)至少一种非支化对称二异氰酸酯; 和(c)至少一种羟基封端的(甲基)丙烯酸烷基酯或其亚烷基部分具有2-30个碳原子的2-氟丙烯酸酯单体; 其中所述组合物是可涂覆的。
Abstract:
In one aspect, the invention provides a water-based release coating composition comprising a mixture of: A. from 0.1 to about 5 wt % of a fluoro(meth)acrylate (co)polymer or a fluorochemical urethane compound containing at least one fluorinated group having the formula —CF2)nCF3, wherein n is an integer from 1 to 3; B. from about 5 to about 99.9 wt % of a copolymer comprising the reaction product of a. from about 40 to about 70 wt % of an alkyl (meth)acrylate, wherein the alkyl group contains from 16 to 22 carbon atoms, b. from about 3 to about 20 wt % of (meth)acrylic acid, c. from about 20 to about 40 wt % acrylonitrile, and d. from 0 to about 15 wt % of vinyl monomer, other than acrylonitrile, wherein the sum of a. through d. equals 100%; and C. from 0 to about 94.9 wt % of an extender polymer, wherein the sum of A., B., and C. is 100% and wt % is based on the total amount of solids in the composition.
Abstract:
A copolymer comprises repeating units derived from at least one co-reactant comprising two or more mercapto functional groups, and repeating units derived from a fluoroacrylate comprising the reaction product of: (a) at least one fluorochemical alcohol represented by the formula: C4F9—X—OH wherein: R=hydrogen or an alkyl group of 1 to 4 carbon atoms, m=2 to 8, Rf=CnF2n+1, n=1 to 5, y=0 to 6, and q=1 to 8; (b) at least one unbranched symmetric diisocyanate; and (c) at least one hydroxy-terminated alkyl (meth)acrylate or 2-fluoroacrylate monomer having 2 to about 30 carbon atoms in its alkylene portion.
Abstract translation:共聚物包含衍生自至少一种包含两个或多个巯基官能团的共反应物的重复单元和衍生自氟代丙烯酸酯的重复单元,该重复单元包含以下反应产物:(a)至少一种由下式表示的含氟醇: -line-formula description =“In-line Formulas”end =“lead”?> C sub> 3 sub> -X-OH <?in-line-formula description = “直链式”末端=“尾”→其中:R =氢或1至4个碳原子的烷基,m = 2至8,R f = C n n = 1〜5,y = 0〜6,q = 1〜8; (b)至少一种非支化的对称二异氰酸酯; 和(c)至少一种羟基封端的(甲基)丙烯酸烷基酯或其亚烷基部分具有2至约30个碳原子的2-氟丙烯酸酯单体。
Abstract:
Fluoroacrylates comprise the reaction product of: (a) at least one fluorochemical alcohol represented by the formula: CnF2n+1—X—OH wherein: R=hydrogen or an alkyl group of 1 to 4 carbon atoms, m=2 to 8, Rf=CnF2n+1, y=0 to 6, and q=1 to 8; (b) at least one unbranched symmetric diisocyanate; and (c) at least one hydroxy-terminated alkyl (meth)acrylate or 2-fluoro acrylate monomer having 2 to about 30 carbon atoms in its alkylene portion.