METHOD FOR PRODUCING FLUORINATED POLYSILANES
    9.
    发明申请
    METHOD FOR PRODUCING FLUORINATED POLYSILANES 审中-公开
    生产氟化多晶硅的方法

    公开(公告)号:US20130270102A1

    公开(公告)日:2013-10-17

    申请号:US13823731

    申请日:2011-09-14

    CPC classification number: C01B33/03 C01B33/107 C08G77/60

    Abstract: The invention relates to a method for producing fluorinated polysilanes. Hydrogen fluoride and/or hexafluorosilicic acid, which are obtained in particular during acid digestion of mineral phosphates in the production of phosphate fertilisers, are used for the production of SiF4. The SiF4 obtained is thermally or plasma-chemically converted to fluorinated polysilane. The method is particularly efficient and cost-effective.

    Abstract translation: 本发明涉及一种氟化聚硅烷的制备方法。 在生产磷酸盐肥料时,特别是在磷酸钙矿物酸消解过程中特别获得的氟化氢和/或六氟硅酸用于生产SiF4。 所得到的SiF 4被热或等离子体化学转化成氟化聚硅烷。 该方法是特别有效和具有成本效益的。

    KINETICALLY STABLE CHLORINATED POLYSILANES AND PRODUCTION AND USE THEREOF
    10.
    发明申请
    KINETICALLY STABLE CHLORINATED POLYSILANES AND PRODUCTION AND USE THEREOF 有权
    动态稳定的氯化多晶硅及其生产和使用

    公开(公告)号:US20130001467A1

    公开(公告)日:2013-01-03

    申请号:US13513018

    申请日:2010-12-06

    CPC classification number: C08G77/60 C01B33/04 C01G17/00 C08G79/14 Y02P20/582

    Abstract: Kinetically stable halogenated polysilanes include mixture of compounds having respectively at least four silicon atoms bound together, the substituents thereof comprising chlorine, and chlorine and hydrogen, and in the composition thereof, the atomic ratio of substituent to silicon is at least 1:1, wherein a) the kinetically stable halogenated polysilanes have a kinetically high stability in relation to oxidative-splitting by chlorine, and the degree of conversion at temperatures of 120° C. within 10 hours with an excess of chlorine gas at 1013 hPa does not exceed 30 mol %, and b) the kinetically stable halogenated polysilanes have a percentage of branching points in the polysilane molecules of more than 8 mol %.

    Abstract translation: 动态稳定的卤代聚硅烷包括分别具有至少四个硅原子的化合物的混合物,其中包含氯,氯和氢的取代基,并且在其组成中,取代基与硅的原子比至少为1:1,其中 a)动力学稳定的卤代聚硅烷在氯氧化分解方面具有动态的高稳定性,在10℃以内的温度为120℃,在1013hPa下过量的氯气的转化度不超过30mol %,和b)动力学稳定的卤代聚硅烷在聚硅烷分子中的支化点百分比大于8mol%。

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