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公开(公告)号:US12220861B2
公开(公告)日:2025-02-11
申请号:US18390827
申请日:2023-12-20
Applicant: 3D Systems, Inc.
Inventor: Khalil Moussa
IPC: B33Y70/00 , B29C64/129 , C08F2/48 , C08F220/36 , C08F222/10 , C08F224/00 , C09D11/101 , C09D11/107 , B33Y10/00 , B33Y80/00
Abstract: Additives for three-dimensional build materials or inks are described herein which, in some embodiments, can impart one or more structural enhancements to articles printed from the build materials. In one aspect, a polymerizable liquid comprises at least one additive including a plurality of cyclopolymerizable functionalities separated by an aliphatic linker or alkylene oxide linker.
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公开(公告)号:US12018165B2
公开(公告)日:2024-06-25
申请号:US18326535
申请日:2023-05-31
Applicant: 3D Systems, Inc.
Inventor: Khalil Moussa
IPC: B33Y10/00 , B29C64/112 , B29C64/124 , B33Y70/00 , C09D11/037 , C09D11/101 , C09D11/107 , C09D11/328 , C09D11/38 , B29K33/00 , B29K105/00
CPC classification number: C09D11/38 , B29C64/112 , B29C64/124 , B33Y10/00 , B33Y70/00 , C09D11/037 , C09D11/101 , C09D11/107 , C09D11/328 , B29K2033/12 , B29K2105/0032
Abstract: In one aspect, inks for use with a three-dimensional (3D) printing system are described herein. In some embodiments, an ink described herein comprises up to 80 wt. % oligomeric curable material; up to 80 wt. % monomeric curable material; up to 10 wt. % photoinitiator; up to 1 wt. % non-curable absorber material; and up to 10 wt. % one or more additional components, based on the total weight of the ink, and wherein the total amount of the foregoing components is equal to 100 wt. %. Additionally, the photoinitiator is operable to initiate curing of the oligomeric curable material and/or the monomeric curable material when the photoinitiator is exposed to incident curing radiation having a peak wavelength λ. Moreover, the ink has a penetration depth (Dp), a critical energy (Ec), and a print through depth (DPT) at the wavelength λ of less than or equal to 2×Dp.
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公开(公告)号:US11702559B2
公开(公告)日:2023-07-18
申请号:US17832129
申请日:2022-06-03
Applicant: 3D Systems, Inc.
Inventor: Khalil Moussa
IPC: C09D11/38 , C09D11/328 , C09D11/101 , C09D11/107 , B29C64/124 , B33Y10/00 , B33Y70/00 , C09D11/037 , B29C64/112 , B29K105/00 , B29K33/00
CPC classification number: C09D11/38 , B29C64/112 , B29C64/124 , B33Y10/00 , B33Y70/00 , C09D11/037 , C09D11/101 , C09D11/107 , C09D11/328 , B29K2033/12 , B29K2105/0032
Abstract: In one aspect, inks for use with a three-dimensional (3D) printing system are described herein. In some embodiments, an ink described herein comprises up to 80 wt. % oligomeric curable material; up to 80 wt. % monomeric curable material; up to 10 wt. % photoinitiator; up to 1 wt. % non-curable absorber material; and up to 10 wt. % one or more additional components, based on the total weight of the ink, and wherein the total amount of the foregoing components is equal to 100 wt. %. Additionally, the photoinitiator is operable to initiate curing of the oligomeric curable material and/or the monomeric curable material when the photoinitiator is exposed to incident curing radiation having a peak wavelength λ. Moreover, the ink has a penetration depth (Dp), a critical energy (Ec), and a print through depth (DPT) at the wavelength λ of less than or equal to 2×Dp.
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公开(公告)号:US11602892B2
公开(公告)日:2023-03-14
申请号:US15105186
申请日:2014-12-22
Applicant: 3D Systems, Inc.
Inventor: Khalil Moussa
IPC: B29C64/165 , B29C64/153 , B29C64/141 , B33Y70/10 , B33Y10/00 , B29K105/16 , B29K105/00
Abstract: A method of printing a three dimensional article is provided wherein particles are bonded together with chemical bonds having a bond strength of at least 10 kJ/mol. In one aspect, kits for three dimensional printing are described herein. In some embodiments, a kit described herein comprises a substantially dry particulate material (20) comprising an insoluble filler having a first functional group on the surface of the insoluble filler; and a fluid binder material (26) comprising a multifunctional linker having a second functional group, wherein the insoluble filler is insoluble in the fluid binder material and wherein the first functional group and the second functional group can react with one another to form a covalent bond between the insoluble filler and the multi functional linker.
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公开(公告)号:US09534103B2
公开(公告)日:2017-01-03
申请号:US13871462
申请日:2013-04-26
Applicant: 3D Systems, Inc.
Inventor: Pingyong Xu , Khalil Moussa , John Stockwell
CPC classification number: B29C67/0092 , B29C33/40 , B29C33/52 , B29C35/0805 , B29C64/106 , B29C64/112 , B29C64/386 , B29C64/40 , B29C2035/0827 , B29C2035/0833 , B29C2035/0838 , B29K2075/00 , B29K2891/00 , B29K2995/0062 , B33Y10/00 , B33Y30/00 , B33Y50/02 , B33Y70/00 , B41M5/508 , C08K5/05 , C08L91/06 , C09D7/63 , C09D191/06 , C09K5/066 , Y10T428/24802
Abstract: In one aspect, support materials operable for use in 3D printing systems are described herein. In some embodiments, a support material comprises a wax component comprising at least one ethoxylated fatty alcohol and a viscosity modifying agent, wherein the support material is water dispersible. In some embodiments, the wax component comprises a mixture of at least one fatty alcohol and at least one ethoxylated fatty alcohol.
Abstract translation: 在一个方面,本文描述了可操作用于3D打印系统的支撑材料。 在一些实施方案中,载体材料包含包含至少一种乙氧基化脂肪醇和粘度改性剂的蜡组分,其中所述载体材料是水分散的。 在一些实施方案中,蜡组分包含至少一种脂肪醇和至少一种乙氧基化脂肪醇的混合物。
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公开(公告)号:US12168735B2
公开(公告)日:2024-12-17
申请号:US17690763
申请日:2022-03-09
Applicant: 3D Systems, Inc.
Inventor: Khalil Moussa
IPC: C09D4/00 , B29C64/124 , B33Y10/00 , B33Y70/00 , C08F220/22 , C08F220/58 , C08F222/10 , C08K5/521 , C09D7/63 , C09D133/16 , C09D133/24 , C09D135/02 , B29K105/00
Abstract: Polymerizable liquids for 3D printing applications are described herein which, in some embodiments, impart flame resistant and/or flame retardant properties to articles printed from the liquids. The polymerizable liquids may also impart desirable mechanical properties to the articles. In some embodiments, a polymerizable liquid comprises a curable isocyanurate component in an amount of at least 5 wt. %, based on total weight of the polymerizable liquid, and a brominated acrylate ester component. Additionally, methods of printing three-dimensional articles using said polymerizable liquids are described herein.
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公开(公告)号:US11890806B2
公开(公告)日:2024-02-06
申请号:US17737355
申请日:2022-05-05
Applicant: 3D Systems, Inc.
Inventor: Khalil Moussa
IPC: B29C64/129 , C08F222/10 , C08F2/48 , C08F220/36 , C08F224/00 , C09D11/101 , C09D11/107 , B33Y10/00 , B33Y70/00 , B33Y80/00
CPC classification number: B29C64/129 , C08F2/48 , C08F220/36 , C08F222/1065 , C08F224/00 , C09D11/101 , C09D11/107 , B33Y10/00 , B33Y70/00 , B33Y80/00
Abstract: Additives for three-dimensional build materials or inks are described herein which, in some embodiments, can impart one or more structural enhancements to articles printed from the build materials. In one aspect, a polymerizable liquid comprises at least one additive including a plurality of cyclopolymerizable functionalities separated by an aliphatic linker or alkylene oxide linker.
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公开(公告)号:US20210095094A1
公开(公告)日:2021-04-01
申请号:US17060826
申请日:2020-10-01
Applicant: 3D Systems, Inc.
Inventor: Mehrgan Khavari , Khalil Moussa , Scott Broce
IPC: C08K5/08 , C08F220/50 , C08F226/06
Abstract: Build materials for 3D printing applications are described herein which, in some embodiments, comprise a dye component operable to alter spectral characteristics of the printed part over the course of the build cycle. In some embodiments, for example, the dye component can provide desirable light penetration depth during article printing and sufficient optical clarity during final light curing processes.
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公开(公告)号:US12269958B2
公开(公告)日:2025-04-08
申请号:US18654201
申请日:2024-05-03
Applicant: 3D Systems, Inc.
Inventor: Khalil Moussa
IPC: B33Y10/00 , B29C64/112 , B29C64/124 , B33Y70/00 , C09D11/037 , C09D11/101 , C09D11/107 , C09D11/328 , C09D11/38 , B29K33/00 , B29K105/00
Abstract: In one aspect, inks for use with a three-dimensional (3D) printing system are described herein. In some embodiments, an ink described herein comprises up to 80 wt. % oligomeric curable material; up to 80 wt. % monomeric curable material; up to 10 wt. % photoinitiator; up to 1 wt. % non-curable absorber material; and up to 10 wt. % one or more additional components, based on the total weight of the ink, and wherein the total amount of the foregoing components is equal to 100 wt. %. Additionally, the photoinitiator is operable to initiate curing of the oligomeric curable material and/or the monomeric curable material when the photoinitiator is exposed to incident curing radiation having a peak wavelength λ. Moreover, the ink has a penetration depth (Dp), a critical energy (Ec), and a print through depth (DPT) at the wavelength λ of less than or equal to 2×Dp.
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公开(公告)号:US11912846B2
公开(公告)日:2024-02-27
申请号:US17690694
申请日:2022-03-09
Applicant: 3D Systems, Inc.
Inventor: Khalil Moussa
CPC classification number: C08K5/01 , B29C64/106 , B33Y10/00 , B33Y70/10 , C08F20/10 , B29K2033/04
Abstract: Additives for three-dimensional build materials or inks are described herein which, in some embodiments, can impart flame retardant properties and/or structural enhancements to articles printed from the build materials. In some embodiments, such an additive comprises a compound of Formula I herein, wherein L and Z are ring substituents comprising at least one polymerizable point of unsaturation, and wherein R1 and R2 are independently selected from the group consisting of alkylene and alkenylene, and R3-R6 each represent one to four optional ring substituents, each one of the one to four ring substituents independently selected from the group consisting of alkyl, heteroalkyl, haloalkyl, halo, hydroxyl, alkoxy, amine, amide, and ether, and wherein n is an integer from 1 to 7.
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