公开(公告)号：US09669394B2

公开(公告)日：2017-06-06

申请号：US15150944

申请日：2016-05-10

Applicant: Advanced Refining Technologies LLC

Inventor： Rong He ,  Stanislaw Plecha ,  Meenakshi S. Krishnamoorthy ,  Bharat M. Patel

IPC: B01J27/19 ,  B01J21/04 ,  B01J37/03 ,  B01J37/28 ,  B01J21/06 ,  B01J23/755 ,  B01J23/883 ,  B01J35/10 ,  B01J37/00 ,  C10G45/08 ,  B01J37/12 ,  B01J37/16 ,  C10G45/00 ,  B01J37/08 ,  B01J37/02

CPC classification number: B01J27/19 ,  B01J21/04 ,  B01J21/063 ,  B01J23/755 ,  B01J23/883 ,  B01J35/1019 ,  B01J35/1042 ,  B01J35/1047 ,  B01J35/1061 ,  B01J35/1066 ,  B01J35/1071 ,  B01J35/1076 ,  B01J37/0009 ,  B01J37/0045 ,  B01J37/0201 ,  B01J37/03 ,  B01J37/031 ,  B01J37/08 ,  B01J37/12 ,  B01J37/16 ,  B01J37/28 ,  C10G45/00 ,  C10G45/08 ,  C10G2300/10 ,  C10G2300/107 ,  C10G2300/1077 ,  C10G2300/70 ,  C10G2300/708

Abstract: Improved catalyst supports, supported catalyst, and method of preparing and using the catalysts for the hydrodesulfurization of a residuum hydrocarbon feedstock are disclosed. The catalyst supports comprise titania alumina having 5 wt % or less titania and have greater than 70% of their pore volume in pores having a diameter between 70 Å and 130 Å and less than 2% in pores having a diameter above 1000 Å. Catalysts prepared from the supports contain Groups 6, 9 and 10 metals or metal compounds, and optionally phosphorus, supported on the titania alumina supports. Catalysts in accordance with the invention exhibit improved sulfur and MCR conversion in hydrotreating processes.

公开(公告)号：US09675965B2

公开(公告)日：2017-06-13

申请号：US15146598

申请日：2016-05-04

Applicant: Advanced Refining Technologies LLC

Inventor： Rong He ,  Stanislaw Plecha ,  Meenakshi S. Krishnamoorthy ,  Bharat M. Patel

IPC: B01J37/16 ,  B01J27/19 ,  B01J21/04 ,  B01J37/03 ,  B01J37/28 ,  B01J21/06 ,  B01J23/755 ,  B01J23/883 ,  B01J35/10 ,  B01J37/00 ,  C10G45/08 ,  B01J37/12 ,  C10G45/00 ,  B01J37/08 ,  B01J37/02

CPC classification number: B01J27/19 ,  B01J21/04 ,  B01J21/063 ,  B01J23/755 ,  B01J23/883 ,  B01J35/1019 ,  B01J35/1042 ,  B01J35/1047 ,  B01J35/1061 ,  B01J35/1066 ,  B01J35/1071 ,  B01J35/1076 ,  B01J37/0009 ,  B01J37/0045 ,  B01J37/0201 ,  B01J37/03 ,  B01J37/031 ,  B01J37/08 ,  B01J37/12 ,  B01J37/16 ,  B01J37/28 ,  C10G45/00 ,  C10G45/08 ,  C10G2300/10 ,  C10G2300/107 ,  C10G2300/1077 ,  C10G2300/70 ,  C10G2300/708

Abstract: Improved catalyst supports, supported catalyst, and method of preparing and using the catalysts for the hydrodesulfurization of a residuum hydrocarbon feedstock are disclosed. The catalyst supports comprise titania alumina having 5 wt % or less titania and have greater than 70% of their pore volume in pores having a diameter between 70 Å and 130 Å and less than 2% in pores having a diameter above 1000 Å. Catalysts prepared from the supports contain Groups 6, 9 and 10 metals or metal compounds, and optionally phosphorus, supported on the titania alumina supports. Catalysts in accordance with the invention exhibit improved sulfur and MCR conversion in hydrotreating processes.

公开(公告)号：US20160250622A1

公开(公告)日：2016-09-01

申请号：US15150944

申请日：2016-05-10

Applicant: Advanced Refining Technologies LLC

Inventor： Rong He ,  Stanislaw Plecha ,  Meenakshi S. Krishnamoorthy ,  Bharat M. Patel

IPC: B01J27/19 ,  B01J37/02 ,  C10G45/08 ,  B01J35/10

CPC classification number: B01J27/19 ,  B01J21/04 ,  B01J21/063 ,  B01J23/755 ,  B01J23/883 ,  B01J35/1019 ,  B01J35/1042 ,  B01J35/1047 ,  B01J35/1061 ,  B01J35/1066 ,  B01J35/1071 ,  B01J35/1076 ,  B01J37/0009 ,  B01J37/0045 ,  B01J37/0201 ,  B01J37/03 ,  B01J37/031 ,  B01J37/08 ,  B01J37/12 ,  B01J37/16 ,  B01J37/28 ,  C10G45/00 ,  C10G45/08 ,  C10G2300/10 ,  C10G2300/107 ,  C10G2300/1077 ,  C10G2300/70 ,  C10G2300/708

Abstract: Improved catalyst supports, supported catalyst, and method of preparing and using the catalysts for the hydrodesulfurization of a residuum hydrocarbon feedstock are disclosed. The catalyst supports comprise titania alumina having 5 wt % or less titania and have greater than 70% of their pore volume in pores having a diameter between 70 Å and 130 Å and less than 2% in pores having a diameter above 1000 Å. Catalysts prepared from the supports contain Groups 6, 9 and 10 metals or metal compounds, and optionally phosphorus, supported on the titania alumina supports. Catalysts in accordance with the invention exhibit improved sulfur and MCR conversion in hydrotreating processes.

Abstract translation: 公开了改进的催化剂载体，负载催化剂以及制备和使用用于残油烃原料的加氢脱硫的催化剂的方法。 催化剂载体包括具有5重量％或更少的二氧化钛的二氧化钛氧化铝，并且在具有直径大于1000埃的孔中具有直径在70埃至130埃之间且小于2％的孔中具有大于其孔体积的70％。 由载体制备的催化剂含有第6,9和10族金属或金属化合物，以及任选的磷，负载在二氧化钛氧化铝载体上。 根据本发明的催化剂在加氢处理方法中表现出改进的硫和MCR转化率。

公开(公告)号：US20160243528A1

公开(公告)日：2016-08-25

申请号：US15146598

申请日：2016-05-04

Applicant: Advanced Refining Technologies LLC

Inventor： Rong He ,  Stanislaw Plecha ,  Meenakshi S. Krishnamoorthy ,  Bharat M. Patel

IPC: B01J21/06 ,  B01J37/08 ,  B01J35/10 ,  B01J37/03

CPC classification number: B01J27/19 ,  B01J21/04 ,  B01J21/063 ,  B01J23/755 ,  B01J23/883 ,  B01J35/1019 ,  B01J35/1042 ,  B01J35/1047 ,  B01J35/1061 ,  B01J35/1066 ,  B01J35/1071 ,  B01J35/1076 ,  B01J37/0009 ,  B01J37/0045 ,  B01J37/0201 ,  B01J37/03 ,  B01J37/031 ,  B01J37/08 ,  B01J37/12 ,  B01J37/16 ,  B01J37/28 ,  C10G45/00 ,  C10G45/08 ,  C10G2300/10 ,  C10G2300/107 ,  C10G2300/1077 ,  C10G2300/70 ,  C10G2300/708

Abstract: Improved catalyst supports, supported catalyst, and method of preparing and using the catalysts for the hydrodesulfurization of a residuum hydrocarbon feedstock are disclosed. The catalyst supports comprise titania alumina having 5 wt % or less titania and have greater than 70% of their pore volume in pores having a diameter between 70 Å and 130 Å and less than 2% in pores having a diameter above 1000 Å. Catalysts prepared from the supports contain Groups 6, 9 and 10 metals or metal compounds, and optionally phosphorus, supported on the titania alumina supports. Catalysts in accordance with the invention exhibit improved sulfur and MCR conversion in hydrotreating processes.

公开(公告)号：US09415384B2

公开(公告)日：2016-08-16

申请号：US14409560

申请日：2013-06-20

Applicant: Advanced Refining Technologies LLC

Inventor： Rong He ,  Stanislaw Plecha ,  Meenakshi S. Krishnamoorthy ,  Bharat M. Patel

IPC: B01J37/16 ,  B01J21/04 ,  B01J37/03 ,  B01J37/28 ,  B01J21/06 ,  B01J23/755 ,  B01J23/883 ,  B01J35/10 ,  B01J37/00 ,  C10G45/08 ,  B01J27/19 ,  B01J37/12 ,  C10G45/00

CPC classification number: B01J27/19 ,  B01J21/04 ,  B01J21/063 ,  B01J23/755 ,  B01J23/883 ,  B01J35/1019 ,  B01J35/1042 ,  B01J35/1047 ,  B01J35/1061 ,  B01J35/1066 ,  B01J35/1071 ,  B01J35/1076 ,  B01J37/0009 ,  B01J37/0045 ,  B01J37/0201 ,  B01J37/03 ,  B01J37/031 ,  B01J37/08 ,  B01J37/12 ,  B01J37/16 ,  B01J37/28 ,  C10G45/00 ,  C10G45/08 ,  C10G2300/10 ,  C10G2300/107 ,  C10G2300/1077 ,  C10G2300/70 ,  C10G2300/708

Abstract: Improved catalyst supports, supported catalyst, and method of preparing and using the catalysts for the hydrodesulfurization of a residuum hydrocarbon feedstock are disclosed. The catalyst supports comprise titania alumina having 5 wt % or less titania and have greater than 70% of their pore volume in pores having a diameter between 70 and 130 and less than 2% in pores having a diameter above 1000. Catalysts prepared from the supports contain Groups 6, 9 and 10 metals or metal compounds, and optionally phosphorus, supported on the titania alumina supports. Catalysts in accordance with the invention exhibit improved sulfur and MCR conversion in hydrotreating processes.

Abstract translation: 公开了改进的催化剂载体，负载催化剂以及制备和使用用于残油烃原料的加氢脱硫的催化剂的方法。 催化剂载体包括具有5重量％或更少的二氧化钛的二氧化钛氧化铝，并且在具有直径大于1000的孔中具有直径在70和130之间且小于2％的孔中具有大于其孔体积的70％以上的催化剂载体。 含有第6,9和10族金属或金属化合物，以及任选的磷，负载在二氧化钛氧化铝载体上。 根据本发明的催化剂在加氢处理方法中表现出改进的硫和MCR转化率。

公开(公告)号：US20150144532A1

公开(公告)日：2015-05-28

申请号：US14409560

申请日：2013-06-20

Applicant: Advanced Refining Technologies LLC

Inventor： Rong He ,  Stanislaw Plecha ,  Meenakshi S. Krishnamoorthy ,  Bharat M. Patel

IPC: B01J37/16 ,  B01J21/04 ,  C10G45/00 ,  B01J35/10 ,  B01J27/19 ,  C10G45/08 ,  B01J21/06 ,  B01J37/12

CPC classification number: B01J27/19 ,  B01J21/04 ,  B01J21/063 ,  B01J23/755 ,  B01J23/883 ,  B01J35/1019 ,  B01J35/1042 ,  B01J35/1047 ,  B01J35/1061 ,  B01J35/1066 ,  B01J35/1071 ,  B01J35/1076 ,  B01J37/0009 ,  B01J37/0045 ,  B01J37/0201 ,  B01J37/03 ,  B01J37/031 ,  B01J37/08 ,  B01J37/12 ,  B01J37/16 ,  B01J37/28 ,  C10G45/00 ,  C10G45/08 ,  C10G2300/10 ,  C10G2300/107 ,  C10G2300/1077 ,  C10G2300/70 ,  C10G2300/708

Abstract: Improved catalyst supports, supported catalyst, and method of preparing and using the catalysts for the hydrodesulfurization of a residuum hydrocarbon feedstock are disclosed. The catalyst supports comprise titania alumina having 5 wt % or less titania and have greater than 70% of their pore volume in pores having a diameter between 70 and 130 and less than 2% in pores having a diameter above 1000. Catalysts prepared from the supports contain Groups 6, 9 and 10 metals or metal compounds, and optionally phosphorus, supported on the titania alumina supports. Catalysts in accordance with the invention exhibit improved sulfur and MCR conversion in hydrotreating processes.

Abstract translation: 公开了改进的催化剂载体，负载催化剂以及制备和使用用于残油烃原料的加氢脱硫的催化剂的方法。 催化剂载体包括具有5重量％或更少的二氧化钛的二氧化钛氧化铝，并且在具有直径大于1000的孔中具有直径在70和130之间且小于2％的孔中具有大于其孔体积的70％以上的催化剂载体。 含有第6,9和10族金属或金属化合物，以及任选的磷，负载在二氧化钛氧化铝载体上。 根据本发明的催化剂在加氢处理方法中表现出改进的硫和MCR转化率。