公开(公告)号：US11529619B2

公开(公告)日：2022-12-20

申请号：US16855514

申请日：2020-04-22

Applicant: BASF CORPORATION

Inventor： Ivor Bull ,  Wen-Mei Xue ,  Patrick Burk ,  R. Samuel Boorse ,  William M. Jaglowski ,  Gerald Stephen Koermer ,  Ahmad Moini ,  Joseph A. Patchett ,  Joseph C. Dettling ,  Matthew Tyler Caudle

IPC: B01J29/06 ,  B01J29/72 ,  B01J29/068 ,  B01D53/56 ,  B01D53/94 ,  B01J23/42 ,  B01J23/89 ,  B01J29/072 ,  B01J29/76 ,  B01J35/00 ,  B01J35/04 ,  B01J37/02 ,  B01J29/74 ,  B01D53/86 ,  B01J29/80 ,  C01B39/46

Abstract: Zeolite catalysts and systems and methods for preparing and using zeolite catalysts having the CHA crystal structure are disclosed. The catalysts can be used to remove nitrogen oxides from a gaseous medium across a broad temperature range and exhibit hydrothermal stable at high reaction temperatures. The zeolite catalysts include a zeolite carrier having a silica to alumina ratio from about 15:1 to about 256:1 and a copper to alumina ratio from about 0.25:1 to about 1:1.

公开(公告)号：US10654031B2

公开(公告)日：2020-05-19

申请号：US15806167

申请日：2017-11-07

Applicant: BASF CORPORATION

Inventor： Ivor Bull ,  Wen-Mei Xue ,  Patrick Burk ,  R. Samuel Boorse ,  William M. Jaglowski ,  Gerald Stephen Koermer ,  Ahmad Moini ,  Joseph A. Patchett ,  Joseph C. Dettling ,  Matthew Tyler Caudle

IPC: B01J29/06 ,  B01J29/72 ,  B01J29/068 ,  B01D53/56 ,  B01D53/94 ,  B01J23/42 ,  B01J23/89 ,  B01J29/072 ,  B01J29/76 ,  B01J35/00 ,  B01J35/04 ,  B01J37/02 ,  B01J29/74 ,  B01D53/86 ,  B01J29/80 ,  C01B39/46

Abstract: Zeolite catalysts and systems and methods for preparing and using zeolite catalysts having the CHA crystal structure are disclosed. The catalysts can be used to remove nitrogen oxides from a gaseous medium across a broad temperature range and exhibit hydrothermal stable at high reaction temperatures. The zeolite catalysts include a zeolite carrier having a silica to alumina ratio from about 15:1 to about 256:1 and a copper to alumina ratio from about 0.25:1 to about 1:1.

公开(公告)号：US09656254B2

公开(公告)日：2017-05-23

申请号：US14973353

申请日：2015-12-17

Applicant: BASF CORPORATION

Inventor： Ivor Bull ,  Wen-Mei Xue ,  Patrick Burk ,  R. Samuel Boorse ,  William M. Jaglowski ,  Gerald Stephen Koermer ,  Ahmad Moini ,  Joseph A. Patchett ,  Joseph C. Dettling ,  Matthew Tyler Caudle

IPC: B01J29/06 ,  B01J29/72 ,  B01J29/068 ,  B01D53/94 ,  B01J23/42 ,  B01J23/89 ,  B01J29/072 ,  B01J29/76 ,  B01J35/00 ,  B01J35/04 ,  B01J37/02 ,  B01J29/74 ,  B01D53/86 ,  B01J29/80 ,  C01B39/46

CPC classification number: B01J29/723 ,  B01D53/56 ,  B01D53/8628 ,  B01D53/9413 ,  B01D53/9418 ,  B01D53/9431 ,  B01D53/9477 ,  B01D2251/206 ,  B01D2251/2062 ,  B01D2251/2067 ,  B01D2255/20715 ,  B01D2255/20738 ,  B01D2255/20761 ,  B01D2255/50 ,  B01D2255/9032 ,  B01D2255/904 ,  B01D2255/9155 ,  B01D2257/40 ,  B01D2257/404 ,  B01D2258/012 ,  B01J23/42 ,  B01J23/8926 ,  B01J29/061 ,  B01J29/068 ,  B01J29/072 ,  B01J29/743 ,  B01J29/76 ,  B01J29/763 ,  B01J29/80 ,  B01J35/0006 ,  B01J35/04 ,  B01J37/0246 ,  B01J2029/062 ,  C01B39/46 ,  Y02T10/24 ,  Y10T428/24149

Abstract: Zeolite catalysts and systems and methods for preparing and using zeolite catalysts having the CHA crystal structure are disclosed. The catalysts can be used to remove nitrogen oxides from a gaseous medium across a broad temperature range and exhibit hydrothermal stable at high reaction temperatures. The zeolite catalysts include a zeolite carrier having a silica to alumina ratio from about 15:1 to about 256:1 and a copper to alumina ratio from about 0.25:1 to about 1:1.

公开(公告)号：US20140360171A1

公开(公告)日：2014-12-11

申请号：US14467250

申请日：2014-08-25

Applicant: BASF Corporation

Inventor： Wen-Mei Xue ,  Xinyi Wei ,  Marcus Hilgendorff ,  Patrick Burk

IPC: B01J23/10 ,  F01N3/20 ,  F01N3/10 ,  F01N3/035 ,  B01J27/232 ,  B01D53/94

CPC classification number: F01N3/2066 ,  B01D53/94 ,  B01D53/9418 ,  B01D53/944 ,  B01D53/945 ,  B01D2255/1021 ,  B01D2255/1023 ,  B01D2255/1025 ,  B01D2255/1028 ,  B01D2255/2042 ,  B01D2255/2065 ,  B01D2255/9022 ,  B01D2255/91 ,  B01D2258/012 ,  B01J23/002 ,  B01J23/10 ,  B01J23/63 ,  B01J27/232 ,  B01J35/0006 ,  B01J35/0013 ,  B01J35/002 ,  B01J35/023 ,  B01J35/04 ,  B01J35/1009 ,  B01J35/1014 ,  B01J37/0201 ,  B01J37/0248 ,  B01J37/10 ,  B01J2523/00 ,  F01N3/035 ,  F01N3/101 ,  F01N2250/02 ,  F01N2610/02 ,  Y02C20/10 ,  Y02T10/22 ,  B01J2523/22 ,  B01J2523/25 ,  B01J2523/31 ,  B01J2523/3712 ,  B01J2523/48 ,  B01J2523/824 ,  B01J2523/828

Abstract: A catalyst for the treatment of exhaust gas emissions is disclosed. The catalyst can comprise ceria-alumina particles having a ceria phase present in a weight percent of the composite in the range of about 20% to about 80% on an oxide basis, an alkaline earth metal component supported on the ceria-alumina particles, wherein the CeO2 is present in the form of crystallites that are hydrothermally stable and have an average crystallite size less than 160 Å after aging at 950° C. for 5 hours in 2% O2 and 10% steam in N2.

Abstract translation: 公开了一种用于处理废气排放的催化剂。 该催化剂可以包括二氧化铈 - 氧化铝颗粒，二氧化铈相以氧化物为基准存在于复合材料的重量百分比范围为约20％至约80％的二氧化铈相，负载在二氧化铈 - 氧化铝颗粒上的碱土金属组分，其中 CeO 2以水热稳定的形式存在，并且在950℃下在2％O 2和10％蒸气在N 2中老化5小时后具有小于160的平均微晶尺寸。

公开(公告)号：US20140260214A1

公开(公告)日：2014-09-18

申请号：US14204386

申请日：2014-03-11

Applicant: BASF Corporation

Inventor： Wen-Mei Xue ,  Xinyi Wei ,  Marcus Hilgendorff ,  Patrick Burk

IPC: B01J27/232

CPC classification number: B01J23/10 ,  B01D53/9422 ,  B01D53/9481 ,  B01D2255/102 ,  B01D2255/1021 ,  B01D2255/1023 ,  B01D2255/1025 ,  B01D2255/1028 ,  B01D2255/2042 ,  B01D2255/2065 ,  B01D2255/40 ,  B01D2255/9022 ,  B01D2255/91 ,  B01D2258/012 ,  B01J23/63 ,  B01J35/0006 ,  B01J35/002 ,  B01J35/023 ,  B01J37/0201 ,  B01J37/0244 ,  B01J37/0248 ,  B01J37/10 ,  B01J2523/00 ,  B01J2523/22 ,  B01J2523/25 ,  B01J2523/31 ,  B01J2523/3712 ,  B01J2523/48 ,  B01J2523/824 ,  B01J2523/828

Abstract: A lean NOx trap for the treatment of exhaust gas emissions, such as the oxidation of unburned hydrocarbons (HC), and carbon monoxide (CO), and the trapping and reduction of nitrogen oxides (NOx) is disclosed. Nitrogen oxide storage catalysts can comprise a layer on a substrate including ceria-alumina particles having a ceria phase present in a weight percent of the composite in the range of about 20% to about 80% on an oxide basis, an alkaline earth metal component supported on the ceria-alumina particles, wherein the CeO2 is present in the form of crystallites that are hydrothermally stable and have an average crystallite size less than 130 Å after aging at 950° C. for 5 hours in 2% O2 and 10% steam in N2.

Abstract translation: 公开了用于处理废气排放的贫NOx捕集器，例如未燃烧的烃（HC）和一氧化碳（CO）的氧化，以及氮氧化物（NOx）的捕获和还原。 氮氧化物储存催化剂可以包括在基底上的包括二氧化铈 - 氧化铝颗粒的二氧化铈 - 氧化铝颗粒，所述二氧化铈 - 氧化铝颗粒的二氧化铈相以所述复合材料的重量百分比存在于基于氧化物的约20％至约80％的范围内，碱土金属组分被负载 在二氧化铈 - 氧化铝颗粒上，其中CeO 2以水热稳定的形式存在，并且在950℃下在2％O 2和10％蒸汽中在950℃老化5小时后具有小于130的平均微晶尺寸 N2。

公开(公告)号：US20240091751A1

公开(公告)日：2024-03-21

申请号：US18513785

申请日：2023-11-20

Applicant: BASF Corporation

Inventor： Ivor Bull ,  Wen-Mei Xue ,  Patrick Burk ,  R. Samuel Boorse ,  William M. Jaglowski ,  Gerald Stephen Koermer ,  Ahmad Moini ,  Joseph A. Patchett ,  Joseph C. Dettling ,  Matthew Tyler Caudle

IPC: B01J29/72 ,  B01D53/56 ,  B01D53/86 ,  B01D53/94 ,  B01J23/42 ,  B01J23/89 ,  B01J29/06 ,  B01J29/068 ,  B01J29/072 ,  B01J29/74 ,  B01J29/76 ,  B01J29/80 ,  B01J35/00 ,  B01J35/04 ,  B01J37/02 ,  C01B39/46

CPC classification number: B01J29/723 ,  B01D53/56 ,  B01D53/8628 ,  B01D53/9413 ,  B01D53/9418 ,  B01D53/9431 ,  B01D53/9477 ,  B01J23/42 ,  B01J23/8926 ,  B01J29/061 ,  B01J29/068 ,  B01J29/072 ,  B01J29/743 ,  B01J29/76 ,  B01J29/763 ,  B01J29/80 ,  B01J35/0006 ,  B01J35/04 ,  B01J37/0215 ,  B01J37/0246 ,  C01B39/46 ,  B01D2251/206 ,  B01D2251/2062 ,  B01D2251/2067 ,  B01D2255/20715 ,  B01D2255/20738 ,  B01D2255/20761 ,  B01D2255/50 ,  B01D2255/903 ,  B01D2255/9032 ,  B01D2255/904 ,  B01D2255/9155 ,  B01D2257/40 ,  B01D2257/404 ,  B01D2258/012 ,  B01J2029/062 ,  Y02C20/10 ,  Y02T10/12 ,  Y10T428/24149

Abstract: Zeolite catalysts and systems and methods for preparing and using zeolite catalysts having the CHA crystal structure are disclosed. The catalysts can be used to remove nitrogen oxides from a gaseous medium across a broad temperature range and exhibit hydrothermal stability at high-reaction temperatures. The zeolite catalysts include a zeolite carrier having a silica-to-alumina ratio from about 15:1 to about 256:1 and a copper to alumina ratio from about 0.25:1 to about 1:1.

公开(公告)号：US11845067B2

公开(公告)日：2023-12-19

申请号：US18055708

申请日：2022-11-15

Applicant: BASF Corporation

Inventor： Ivor Bull ,  Wen-Mei Xue ,  Patrick Burk ,  R. Samuel Boorse ,  William M. Jaglowski ,  Gerald Stephen Koermer ,  Ahmad Moini ,  Joseph A. Patchett ,  Joseph C. Dettling ,  Matthew Tyler Caudle

IPC: B01J29/72 ,  B01J29/068 ,  B01D53/56 ,  B01D53/94 ,  B01J23/42 ,  B01J23/89 ,  B01J29/072 ,  B01J29/76 ,  B01J35/00 ,  B01J35/04 ,  B01J37/02 ,  B01J29/74 ,  B01D53/86 ,  B01J29/06 ,  B01J29/80 ,  C01B39/46

CPC classification number: B01J29/723 ,  B01D53/56 ,  B01D53/8628 ,  B01D53/9413 ,  B01D53/9418 ,  B01D53/9431 ,  B01D53/9477 ,  B01J23/42 ,  B01J23/8926 ,  B01J29/061 ,  B01J29/068 ,  B01J29/072 ,  B01J29/743 ,  B01J29/76 ,  B01J29/763 ,  B01J29/80 ,  B01J35/0006 ,  B01J35/04 ,  B01J37/0215 ,  B01J37/0246 ,  C01B39/46 ,  B01D2251/206 ,  B01D2251/2062 ,  B01D2251/2067 ,  B01D2255/20715 ,  B01D2255/20738 ,  B01D2255/20761 ,  B01D2255/50 ,  B01D2255/903 ,  B01D2255/904 ,  B01D2255/9032 ,  B01D2255/9155 ,  B01D2257/40 ,  B01D2257/404 ,  B01D2258/012 ,  B01J2029/062 ,  Y02C20/10 ,  Y02T10/12 ,  Y10T428/24149

Abstract: Zeolite catalysts and systems and methods for preparing and using zeolite catalysts having the CHA crystal structure are disclosed. The catalysts can be used to remove nitrogen oxides from a gaseous medium across a broad temperature range and exhibit hydrothermal stable at high reaction temperatures. The zeolite catalysts include a zeolite carrier having a silica to alumina ratio from about 15:1 to about 256:1 and a copper to alumina ratio from about 0.25:1 to about 1:1.

公开(公告)号：US11167273B2

公开(公告)日：2021-11-09

申请号：US16652875

申请日：2018-10-02

Applicant: BASF Corporation

Inventor： Xiaolai Zheng ,  Patrick Burk

IPC: B01J23/83 ,  B01J23/20 ,  B01J23/30 ,  B01J23/34 ,  B01J23/44 ,  B01J23/46 ,  B01J35/00 ,  B01J35/04 ,  F01N3/10 ,  F01N3/20 ,  F01N3/28

Abstract: The present disclosure provides SCR catalyst compositions, catalyst articles, and catalyst systems, as well as methods of reducing the amount of NOx present in an engine exhaust gas, particularly exhaust from a gasoline engine. The catalyst compositions particularly can comprise a doped ceria substrate, particularly a ceria support doped with at least a niobia component, and optionally further doped with a further material, particularly a base metal oxide (BMO).

公开(公告)号：US20200055035A1

公开(公告)日：2020-02-20

申请号：US16487447

申请日：2018-02-21

Applicant: BASF Corporation ,  N. E. CHEMCAT CORPORATION

Inventor： Xiaolai Zheng ,  Mahmuda Choudhury ,  Patrick Burk ,  Makoto Nagata ,  Yasuharu Kanno ,  Hiroki Nakayama

IPC: B01J29/85 ,  B01J29/76 ,  B01J35/04 ,  B01J37/02 ,  B01D53/94 ,  F01N3/10

Abstract: The invention provides a selective catalytic reduction (SCR) catalyst effective in the abatement of nitrogen oxides (NOx), the SCR catalyst comprising a metal-promoted molecular sieve promoted with a metal selected from iron, copper, and combinations thereof, wherein the metal is present in an amount of 2.6% by weight or less on an oxide basis based on the total weight of the metal-promoted molecular sieve. A catalyst article, an exhaust gas treatment system method, and a method treating an exhaust gas stream, each comprising the SCR catalyst of the invention, are also provided. The SCR catalyst is particularly useful for treatment of exhaust from a lean burn gasoline engine.

公开(公告)号：US20140219879A1

公开(公告)日：2014-08-07

申请号：US14245712

申请日：2014-04-04

Applicant: BASF Corporation

Inventor： Ivor Bull ,  Wen-Mei Xue ,  Patrick Burk ,  R. Samuel Boorse ,  William M. Jaglowski ,  Gerald Stephen Koermer ,  Ahmad Moini ,  Joseph A. Patchett ,  Joseph C. Dettling ,  Matthew Tyler Caudle

IPC: B01J29/74

CPC classification number: B01J29/723 ,  B01D53/56 ,  B01D53/8628 ,  B01D53/9413 ,  B01D53/9418 ,  B01D53/9431 ,  B01D53/9477 ,  B01D2251/206 ,  B01D2251/2062 ,  B01D2251/2067 ,  B01D2255/20715 ,  B01D2255/20738 ,  B01D2255/20761 ,  B01D2255/50 ,  B01D2255/9032 ,  B01D2255/904 ,  B01D2255/9155 ,  B01D2257/40 ,  B01D2257/404 ,  B01D2258/012 ,  B01J23/42 ,  B01J23/8926 ,  B01J29/061 ,  B01J29/068 ,  B01J29/072 ,  B01J29/743 ,  B01J29/76 ,  B01J29/763 ,  B01J29/80 ,  B01J35/0006 ,  B01J35/04 ,  B01J37/0246 ,  B01J2029/062 ,  C01B39/46 ,  Y02C20/10 ,  Y02T10/24 ,  Y10T428/24149

Abstract: Zeolite catalysts and systems and methods for preparing and using zeolite catalysts having the CHA crystal structure are disclosed. The catalysts can be used to remove nitrogen oxides from a gaseous medium across a broad temperature range and exhibit hydrothermal stable at high reaction temperatures. The zeolite catalysts include a zeolite carrier having a silica to alumina ratio from about 15:1 to about 256:1 and a copper to alumina ratio from about 0.25:1 to about 1:1.

Abstract translation: 公开了沸石催化剂和制备和使用具有CHA晶体结构的沸石催化剂的体系和方法。 催化剂可用于在宽温度范围内从气态介质中除去氮氧化物，并在高反应温度下表现出水热稳定性。 沸石催化剂包括具有约15:1至约256:1的二氧化硅与氧化铝的沸石载体，铜与氧化铝的比例为约0.25:1至约1:1。