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公开(公告)号:US12053768B2
公开(公告)日:2024-08-06
申请号:US17270125
申请日:2019-07-30
Applicant: BASF CORPORATION
Inventor: Yuejin Li
IPC: B01J37/02 , B01J21/12 , B01J23/42 , B01J29/76 , B01J35/00 , B01J35/56 , F01N3/08 , F01N3/20 , F01N3/28
CPC classification number: B01J37/0244 , B01J21/12 , B01J23/42 , B01J29/763 , B01J35/19 , B01J35/56 , F01N3/0842 , F01N3/2066 , F01N3/2803 , F01N2510/0682 , F01N2510/0684
Abstract: A selective catalytic reduction (SCR) catalyst composition effective in the abatement of nitrogen oxides (NOx) is provided. The SCR catalyst composition significantly increases the conversion of NOx relative to a Cu-chabazite reference catalyst composition at any temperature, and especially at low temperatures. A catalyst article, an exhaust gas treatment system, and a method of treating an exhaust gas stream, each including the SCR catalyst composition of the invention, are also provided. The SCR catalyst composition is particularly useful for treatment of exhaust from a lean-burn engine.
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公开(公告)号:US20230027701A1
公开(公告)日:2023-01-26
申请号:US17935179
申请日:2022-09-26
Applicant: BASF CORPORATION
Inventor: Kevin Hallstrom , David Youngren , Yuejin Li
IPC: F01N3/28 , B01D53/94 , B01J23/89 , B01J29/76 , B01J35/04 , B01J37/02 , F01N3/035 , F01N3/08 , F01N3/20
Abstract: The present disclosure is directed to a system for treating an exhaust gas stream from an engine, which includes a diesel oxidation catalyst (DOC) located downstream of the engine and adapted for oxidation of hydrocarbons and carbon monoxide, an injector adapted for the addition of a reductant to the exhaust gas stream located downstream of the DOC, a catalyzed soot filter (CSF) located downstream of the injector, and a selective catalytic reduction component adapted for the oxidation of nitrogen oxides located downstream of the CSF. The CSF is adapted for oxidizing hydrocarbons and includes a selective oxidation catalyst composition on a filter with high selectivity ratio for hydrocarbon oxidation:ammonia oxidation (e.g., at least 0.6).
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公开(公告)号:US20190242282A1
公开(公告)日:2019-08-08
申请号:US16386873
申请日:2019-04-17
Applicant: BASF Corporation
Inventor: Yuejin Li
CPC classification number: F01N3/035 , B01D53/90 , B01D53/94 , B01D53/9418 , B01D53/9422 , B01D53/9427 , B01D53/9436 , B01D53/9477 , B01D2251/202 , B01D2255/102 , B01D2255/1021 , B01D2255/1023 , B01D2255/20738 , B01D2255/20761 , B01D2255/50 , B01D2255/9205 , B01D2255/9207 , B01D2258/012 , F01N3/021 , F01N3/0814 , F01N3/0842 , F01N3/106 , F01N3/206 , F01N3/2066 , F01N13/009 , F01N2370/00 , F01N2510/06 , F01N2610/04 , Y02A50/2325 , Y02T10/24
Abstract: Disclosed herein are emission treatment systems, articles, and methods for selectively reducing NOx compounds. The systems include a hydrogen generator, a hydrogen selective catalytic reduction (H2-SCR) article, and one or more of a diesel oxidation catalyst (DOC) and/or a lean NOx trap (LNT) and/or a low temperature NOx adsorber (LTNA). Certain articles may comprise a zone coated substrate and/or a layered coated substrate and/or an intermingled coated substrate of one or more of the H2-SCR and/or DOC and/or LNT and/or LTNA catalytic compositions.
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公开(公告)号:US10253667B2
公开(公告)日:2019-04-09
申请号:US15555117
申请日:2016-03-24
Applicant: BASF CORPORATION
Inventor: Xiaofan Yang , Wen-Mei Xue , John K. Hochmuth , Matthew J. Schladt , Yuejin Li
IPC: F01N3/08 , B01J23/46 , B01J29/76 , B01J35/00 , F01N13/00 , B01D53/94 , F01N3/10 , F01N3/20 , F01N3/035 , B01J23/44 , B01J35/04 , B01J23/40 , B01J23/42 , B01J29/04 , B01J29/072
Abstract: Described are exhaust gas treatment systems for treatment of a gasoline engine exhaust gas stream containing NOx, particulate matter, and sulfur. The exhaust gas treatment system comprises: one or more catalytic articles selected from a three-way conversion catalyst (TWC), a lean NOx trap (LNT), and an integrated LNT-TWC; a platinum-containing catalytic article downstream from the one or more catalytic articles; and one or more selective catalytic reduction (SCR) catalytic articles immediately downstream from the platinum-containing catalytic article, the one or more SCR catalytic articles including a molecular sieve. The system stabilizes the SCR catalytic article from poisoning by sulfur.
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公开(公告)号:US20230338928A1
公开(公告)日:2023-10-26
申请号:US17725828
申请日:2022-04-21
Inventor: Yuntao Gu , Fudong Liu , Wei Li , Shaohua Xie , Yuejin Li , Xiaolai Zheng
CPC classification number: B01J23/44 , B01J23/10 , B01J21/04 , B01J6/001 , B01J37/0201 , B01J37/0215 , B01J37/0236 , F01N3/101 , F01N2570/12 , F01N2570/14 , F01N2570/10
Abstract: A three-way catalyst for reduced palladium loading is provided. The catalyst includes an inert substrate and a palladium catalyst material coating the substrate. The palladium catalyst material includes a support material formed from one of 10% CeO2/Al2O3, 20% CeO2—Al2O3 (20CeAlOy), 30% CeO2—Al2O3 (30CeAlOy), Al2O3, and MOx-Al2O3, wherein M is one of copper, iron, manganese, titanium, zirconium, magnesium, strontium, and barium. The palladium catalyst material includes a layer of CeO2 material disposed upon the support material, wherein the layer of CeO2 material is dispersed on a surface of the support material. The palladium catalyst material includes an active component including a layer of praseodymium oxide particles dispersed across the surface of the layer of CeO2 material and a layer of palladium particles disposed upon and dispersed across the surface of the layer of CeO2 material at locations each corresponding to a respective location of each of the praseodymium particles.
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公开(公告)号:US10792615B2
公开(公告)日:2020-10-06
申请号:US15562628
申请日:2016-03-30
Applicant: BASF Corporation
Inventor: Yuejin Li , Stanley A. Roth
IPC: B01D46/24 , B01D53/94 , B01J23/44 , B01J29/76 , B01J35/00 , B01J35/04 , B01J37/02 , F01N13/00 , F01N3/035 , F01N3/20
Abstract: Provided are catalyst articles, methods of manufacturing catalyst articles, and methods for controlling emissions in diesel engine exhaust streams with catalyst articles, where the emission treatment system of various embodiments effectively treats diesel engine exhaust with a catalyst article. In one or more embodiments, the catalyst articles have a platinum group metal end coating covering an outlet end surface of the catalytic article. In one or more embodiments, a method is provided where an applicator transfers a platinum group metal coating to an outlet end face of a catalytic article.
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公开(公告)号:US10188987B2
公开(公告)日:2019-01-29
申请号:US15562621
申请日:2016-03-30
Applicant: BASF Corporation
Inventor: Yuejin Li , Stanley A. Roth
IPC: B01D53/94 , F01N3/035 , F01N3/20 , B01J23/42 , B01J29/76 , B01J35/00 , B01J35/10 , B01J37/02 , B01J23/63 , B01J35/02 , B01J35/04 , B01D46/24
Abstract: Provided are multi-zone catalyst articles, methods of manufacturing multi-zone catalyst articles, and methods for controlling emissions in diesel engine exhaust streams with multi-zone catalyst articles, where the emission treatment system of various embodiments effectively treats diesel engine exhaust with a single multi-zone catalyst article.
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公开(公告)号:US20170362984A1
公开(公告)日:2017-12-21
申请号:US15532751
申请日:2015-12-08
Applicant: BASF Corporation
Inventor: Yuejin Li , Xiaolai Zheng , Stanley Roth , Olga Gerlach , Andreas Sundermann
IPC: F01N3/20 , B01D53/94 , F01N3/08 , B01J37/08 , B01J37/02 , B01J35/10 , B01J35/04 , B01J35/00 , B01J33/00 , B01J23/46 , B01J23/44 , B01J23/42 , B01J23/10 , F01N3/10 , F01N3/28
CPC classification number: F01N3/2066 , B01D53/9427 , B01D53/945 , B01D53/9468 , B01D53/9472 , B01D2255/1025 , B01D2255/2065 , B01D2255/9022 , B01D2255/9032 , B01D2255/9155 , B01D2255/9205 , B01D2255/9207 , B01D2257/402 , B01J23/10 , B01J23/42 , B01J23/44 , B01J23/464 , B01J23/468 , B01J23/52 , B01J23/63 , B01J33/00 , B01J35/0006 , B01J35/006 , B01J35/023 , B01J35/04 , B01J35/1014 , B01J35/1019 , B01J35/1038 , B01J37/0201 , B01J37/0215 , B01J37/0244 , B01J37/0246 , B01J37/0248 , B01J37/08 , B01J37/082 , B01J37/088 , B01J2523/00 , F01N3/0842 , F01N3/101 , F01N3/2839 , Y02C20/10 , Y02T10/22 , B01J2523/36 , B01J2523/3712 , B01J2523/822 , B01J2523/3706 , B01J2523/3718 , B01J2523/3725 , B01J2523/3737 , B01J2523/375
Abstract: A nitrous oxide (N2O) removal catalyst composite is provided, comprising a N2O removal catalytic material on a substrate, the catalytic material comprising a rhodium (Rh) component supported on a ceria-based support, wherein the catalyst composite has a H2-consumption peak of about 100° C. or less as measured by hydrogen temperature-programmed reduction (H2-TPR). Methods of making and using the same are also provided.
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9.
公开(公告)号:US11801491B1
公开(公告)日:2023-10-31
申请号:US17725828
申请日:2022-04-21
Applicant: GM GLOBAL TECHNOLOGY OPERATIONS LLC , University of Central Florida Research Foundation, Inc. , BASF Corporation
Inventor: Yuntao Gu , Fudong Liu , Wei Li , Shaohua Xie , Yuejin Li , Xiaolai Zheng
CPC classification number: B01J23/44 , B01J6/001 , B01J21/04 , B01J23/10 , B01J37/0201 , B01J37/0215 , B01J37/0236 , F01N3/101 , F01N2570/10 , F01N2570/12 , F01N2570/14
Abstract: A three-way catalyst for reduced palladium loading is provided. The catalyst includes an inert substrate and a palladium catalyst material coating the substrate. The palladium catalyst material includes a support material formed from one of 10% CeO2/Al2O3, 20% CeO2—Al2O3 (20CeAlOy), 30% CeO2—Al2O3 (30CeAlOy), Al2O3, and MOx-Al2O3, wherein M is one of copper, iron, manganese, titanium, zirconium, magnesium, strontium, and barium. The palladium catalyst material includes a layer of CeO2 material disposed upon the support material, wherein the layer of CeO2 material is dispersed on a surface of the support material. The palladium catalyst material includes an active component including a layer of praseodymium oxide particles dispersed across the surface of the layer of CeO2 material and a layer of palladium particles disposed upon and dispersed across the surface of the layer of CeO2 material at locations each corresponding to a respective location of each of the praseodymium particles.
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公开(公告)号:US11713705B2
公开(公告)日:2023-08-01
申请号:US17483135
申请日:2021-09-23
Applicant: BASF Corporation
Inventor: Yuejin Li , Xiaolai Zheng , Stanley Roth , Olga Gerlach , Andreas Sundermann
IPC: B01J23/10 , B01J23/44 , B01J23/46 , B01J23/52 , B01J23/63 , B01J33/00 , B01J35/00 , B01J35/04 , B01J35/10 , B01J37/02 , B01J37/08 , F01N3/08 , F01N3/10 , F01N3/20 , F01N3/28 , B01D53/94 , B01J23/42 , B01J35/02
CPC classification number: F01N3/2066 , B01D53/9427 , B01J23/10 , B01J23/42 , B01J23/44 , B01J23/464 , B01J23/468 , B01J23/52 , B01J23/63 , B01J33/00 , B01J35/0006 , B01J35/04 , B01J35/1014 , B01J35/1019 , B01J35/1038 , B01J37/0201 , B01J37/0215 , B01J37/0244 , B01J37/0246 , B01J37/0248 , B01J37/08 , B01J37/082 , B01J37/088 , F01N3/0842 , F01N3/101 , F01N3/2839 , B01D53/945 , B01D53/9468 , B01D53/9472 , B01D2255/1025 , B01D2255/2065 , B01D2255/9022 , B01D2255/9032 , B01D2255/9155 , B01D2255/9205 , B01D2255/9207 , B01D2257/402 , B01J35/006 , B01J35/023 , B01J2523/00 , Y02C20/10 , Y02T10/12 , B01J2523/00 , B01J2523/36 , B01J2523/3712 , B01J2523/822 , B01J2523/00 , B01J2523/3706 , B01J2523/3712 , B01J2523/822 , B01J2523/00 , B01J2523/3712 , B01J2523/3718 , B01J2523/822 , B01J2523/00 , B01J2523/3712 , B01J2523/3725 , B01J2523/822 , B01J2523/00 , B01J2523/3712 , B01J2523/3737 , B01J2523/822 , B01J2523/00 , B01J2523/3712 , B01J2523/375 , B01J2523/822
Abstract: A nitrous oxide (N2O) removal catalyst composite is provided, comprising a N2O removal catalytic material on a substrate, the catalytic material comprising a rhodium (Rh) component supported on a ceria-based support, wherein the catalyst composite has a H2-consumption peak of about 100° C. or less as measured by hydrogen temperature-programmed reduction (H2-TPR). Methods of making and using the same are also provided.
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