公开(公告)号：US10385033B2

公开(公告)日：2019-08-20

申请号：US15746082

申请日：2016-07-01

Applicant: BASF SE

Inventor： Alvaro Gordillo ,  Holger Werhan ,  Richard Dehn ,  Benoit Blank ,  Joaquim Henrique Teles ,  Stephan A Schunk ,  Markus Piepenbrink ,  Rene Backes ,  Lei Zhang

IPC: C07D307/02 ,  C07D307/46 ,  B01J21/18 ,  B01J23/42

Abstract: A process for preparing furan-2,5-dicarboxylic acid is disclosed. The process includes the following steps: preparing or providing a starting mixture including 5-(hydroxy-methyl)furfural (HMF), 5,5′-[oxy-bis(methylene)]bis-2-furfural (di-HMF), and water; subjecting said starting mixture to oxidation conditions in the presence of an oxygen-containing gas and a catalytically effective amount of a heterogeneous catalyst including one or more noble metals on a support so that both HMF and di-HMF react to give furane-2,5-dicarboxylic acid in a product mixture also including water and oxidation by-products. The use of a catalyst is also disclosed, the catalyst including one or more noble metals on a support as an heterogeneous oxidation catalyst for catalyzing in an aqueous starting mixture the reaction of both HMF and di-HMF to furane-2,5-dicarboxylic acid.

公开(公告)号：US20180319759A1

公开(公告)日：2018-11-08

申请号：US15772207

申请日：2016-11-03

Applicant: BASF SE

Inventor： Alvaro Gordillo ,  Martin Alexander Bohn ,  Stephan A Schunk ,  Ivana Jevtovikj ,  Holger Werhan ,  Svenia Duefert ,  Markus Piepenbrink ,  Rene Backes ,  Richard Dehn

IPC: C07D307/50

CPC classification number: C07D307/50 ,  C07D307/46

Abstract: Provided herein is a process for preparing a mixture including 5-(hydroxy-methyl)furfural (HMF) and one or more HMF esters of formula (I), the process including the following steps: (A-1) preparing or providing a starting mixture which includes one, two or more carbohydrate compounds and as the solvent or as a co-solvent for the carbohydrate compounds an amount of one or more carboxylic acid esters of formula (II); (A-2) subjecting the starting mixture to reaction conditions so that at least one of the one, two or more carbohydrate compounds reacts, and a fraction of the amount of one or more carboxylic acid esters of formula (II) is hydrolyzed, so that a mixture results that includes 5-(hydroxy-methyl)furfural and/or the one or more HMF esters of formula (I), one or more carboxylic acids of formula (III) and a remaining fraction of the amount of one or more carboxylic acid esters of formula (II).

公开(公告)号：US09758504B2

公开(公告)日：2017-09-12

申请号：US14902231

申请日：2014-06-25

Applicant: BASF SE

Inventor： Richard Dehn ,  Michael Kraus ,  Martine Dehn ,  Manuel Danz ,  Joaquim Henrique Teles

IPC: C07C45/00 ,  C07D311/72 ,  C07C46/08 ,  C07C50/02 ,  C07C50/04

CPC classification number: C07D311/72 ,  C07C46/08 ,  C07C50/02 ,  C07C50/04

Abstract: The invention relates to a method for producing 2,3,5-trimethyl benzoquinone or a compound containing 2,3,5-trimethyl benzoquinone, the method comprising the following steps: Oxidation of 2,3,6-trimethylphenol with oxygen or an oxygen-containing gas in a two- or multi-phase reaction medium in the presence of a catalyst or catalyst system containing at least one copper (II)-halide to a mixture containing 2,3,5-trimethyl benzoquinone, characterized in that the reaction medium contains water and at least one secondary aliphatic acyclic alcohol having 6 or more, preferably 7 or more, carbon atoms.

公开(公告)号：US10428039B2

公开(公告)日：2019-10-01

申请号：US15773411

申请日：2016-11-03

Applicant: BASF SE

Inventor： Alvaro Gordillo ,  Martin Alexander Bohn ,  Stephan A. Schunk ,  Ivana Jevtovikj ,  Rene Backes ,  Holger Werhan ,  Svenia Duefert ,  Richard Dehn ,  Markus Piepenbrink

IPC: C07D307/02 ,  C07D307/46 ,  C07D307/68

Abstract: Provided herein is a process for preparing furan-2,5-dicarboxylic acid. The process includes the following steps: (A-1) preparing a starting mixture comprising one, two or more carbohydrate compounds selected from the group consisting of: hexoses, oligosaccharides comprising hexose units, and polysaccharides including hexose units, and as a solvent or as a co-solvent for the carbohydrate compounds an amount of one or more carboxylic acid esters of a formula (II) and (A-2) subjecting the starting mixture to reaction conditions so that at least one of the one, two or more carbohydrate compounds reacts, and a fraction of the amount of one or more carboxylic acid esters of formula (II) is hydrolyzed, resulting in a mixture including 5-(hydroxymethyl)furfural and/or the one or more HMF esters of a formula (I), one or more carboxylic acids of a formula (III) and a remaining fraction of the amount of one or more carboxylic acid esters of formula (II).

公开(公告)号：US20180319758A1

公开(公告)日：2018-11-08

申请号：US15773411

申请日：2016-11-03

Applicant: BASF SE

Inventor： Alvaro Gordillo ,  Martin Alexander Bohn ,  Stephan A Schunk ,  Ivana Jevtovikj ,  Rene Backes ,  Holger Werhan ,  Svenia Duefert ,  Richard Dehn ,  Markus Piepenbrink

IPC: C07D307/46

CPC classification number: C07D307/46 ,  C07D307/68

Abstract: Provided herein is a process for preparing furan-2,5-dicarboxylic acid. The process includes the following steps: (A-1) preparing a starting mixture comprising one, two or more carbohydrate compounds selected from the group consisting of: hexoses, oligosaccharides comprising hexose units, and polysaccharides including hexose units, and as a solvent or as a co-solvent for the carbohydrate compounds an amount of one or more carboxylic acid esters of a formula (II) and (A-2) subjecting the starting mixture to reaction conditions so that at least one of the one, two or more carbohydrate compounds reacts, and a fraction of the amount of one or more carboxylic acid esters of formula (II) is hydrolyzed, resulting in a mixture including 5-(hydroxymethyl)furfural and/or the one or more HMF esters of a formula (I), one or more carboxylic acids of a formula (III) and a remaining fraction of the amount of one or more carboxylic acid esters of formula (II).

公开(公告)号：US20180215724A1

公开(公告)日：2018-08-02

申请号：US15746082

申请日：2016-07-01

Applicant: BASF SE

Inventor： Alvaro Gordillo ,  Holger Werhan ,  Richard Dehn ,  Benoit Blank ,  Joaquim Henrique Teles ,  Stephan A Schunk ,  Markus Piepenbrink ,  Rene Backes ,  Lei Zhang

IPC: C07D307/46 ,  B01J23/42 ,  B01J21/18

CPC classification number: C07D307/46 ,  B01J21/18 ,  B01J23/42

Abstract: A process for preparing furan-2,5-dicarboxylic acid is disclosed. The process includes the following steps: preparing or providing a starting mixture including 5-(hydroxy-methyl)furfural (HMF), 5,5′-[oxy-bis(methylene)]bis-2-furfural (di-HMF), and water; subjecting said starting mixture to oxidation conditions in the presence of an oxygen-containing gas and a catalytically effective amount of a heterogeneous catalyst including one or more noble metals on a support so that both HMF and di-HMF react to give furane-2,5-dicarboxylic acid in a product mixture also including water and oxidation by-products. The use of a catalyst is also disclosed, the catalyst including one or more noble metals on a support as an heterogeneous oxidation catalyst for catalyzing in an aqueous starting mixture the reaction of both HMF and di-HMF to furane-2,5-dicarboxylic acid.

公开(公告)号：US20130338402A1

公开(公告)日：2013-12-19

申请号：US13916082

申请日：2013-06-12

Applicant: BASF SE

Inventor： Richard Dehn ,  Joaquim Henrique Teles ,  Michael Limbach ,  Stephan Deuerlein ,  Manuel Danz ,  Ralf Pelzer ,  Daniel Schneider

IPC: C07C45/68 ,  C07C49/547 ,  C07C49/527 ,  C07C45/67

CPC classification number: C07C45/68 ,  C07C45/673 ,  C07C49/527 ,  C07C49/547 ,  C07C2601/18 ,  C07C49/607 ,  C07C49/587

Abstract: The present invention relates to a process for preparing cyclic compounds having at least eight carbon atoms and at least one keto group, to the cyclic compounds obtained by this process and to the use thereof, in particular as fragrance or for providing a fragrance.

Abstract translation: 本发明涉及一种制备具有至少8个碳原子和至少一个酮基的环状化合物与通过该方法获得的环状化合物及其用途，特别是作为香料或提供香料的方法。

公开(公告)号：US10364231B2

公开(公告)日：2019-07-30

申请号：US15676398

申请日：2017-08-14

Applicant: BASF SE

Inventor： Richard Dehn ,  Michael Kraus ,  Martine Dehn ,  Manuel Danz ,  Joaquim Henrique Teles

IPC: C07C45/00 ,  C07D311/72 ,  C07C46/08 ,  C07C50/02 ,  C07C50/04

Abstract: The invention relates to a method for producing 2,3,5-trimethyl benzoquinone or a compound containing 2,3,5-trimethyl benzoquinone, the method comprising the following steps: Oxidation of 2,3,6-trimethylphenol with oxygen or an oxygen-containing gas in a two-or multi-phase reaction medium in the presence of a catalyst or catalyst system containing at least one copper (II)-halide to a mixture containing 2,3,5-trimethyl benzoquinone, characterized in that the reaction medium contains water and at least one secondary aliphatic acyclic alcohol having 6 or more, preferably 7 or more, carbon atoms.

公开(公告)号：US10259797B2

公开(公告)日：2019-04-16

申请号：US15772207

申请日：2016-11-03

Applicant: BASF SE

Inventor： Alvaro Gordillo ,  Martin Alexander Bohn ,  Stephan A Schunk ,  Ivana Jevtovikj ,  Holger Werhan ,  Svenia Duefert ,  Markus Piepenbrink ,  Rene Backes ,  Richard Dehn

IPC: C07D307/50 ,  C07D307/46

Abstract: Provided herein is a process for preparing a mixture including 5-(hydroxy-methyl)furfural (HMF) and one or more HMF esters of formula (I), the process including the following steps: (A-1) preparing or providing a starting mixture which includes one, two or more carbohydrate compounds and as the solvent or as a co-solvent for the carbohydrate compounds an amount of one or more carboxylic acid esters of formula (II); (A-2) subjecting the starting mixture to reaction conditions so that at least one of the one, two or more carbohydrate compounds reacts, and a fraction of the amount of one or more carboxylic acid esters of formula (II) is hydrolyzed, so that a mixture results that includes 5-(hydroxy-methyl)furfural and/or the one or more HMF esters of formula (I), one or more carboxylic acids of formula (III) and a remaining fraction of the amount of one or more carboxylic acid esters of formula (II).

公开(公告)号：US10112882B2

公开(公告)日：2018-10-30

申请号：US15514902

申请日：2015-09-30

Applicant: BASF SE

Inventor： Frauke Thrun ,  Joaquim Henrique Teles ,  Albert Werner ,  Richard Dehn ,  Ralf Pelzer ,  Stephan Maurer

IPC: C07C47/38 ,  C07C45/29 ,  C11B9/00

Abstract: The present invention relates to new types of cyclic carbaldehydes, the preparation thereof and the use as aromachemical, in particular as fragrance, and to aroma substance compositions and products comprising these carbaldehydes.