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    Process for dehydrating methanol to dimethyl ether
    1.
    发明授权
    Process for dehydrating methanol to dimethyl ether 有权

    公开(公告)号：US12084410B2

    公开(公告)日：2024-09-10

    申请号：US17433135

    申请日：2019-02-22

    Applicant: BP P.L.C. ,  BP (CHINA) HOLDINGS LTD

    Inventor： Benjamin James Dennis-Smither ,  John Glenn Sunley ,  Zhiqiang Yang

    IPC: C07C41/09 ,  B01J29/06 ,  B01J29/08 ,  B01J29/18 ,  B01J29/40 ,  B01J29/70

    CPC classification number: C07C41/09 ,  B01J29/06 ,  B01J29/084 ,  B01J29/18 ,  B01J29/40 ,  B01J29/7007 ,  B01J29/7042 ,  B01J29/7046 ,  B01J2229/42

    Abstract: A process for dehydrating methanol to dimethyl ether product in the presence of a catalyst and a promoter, wherein the catalyst is at least one aluminosilicate zeolite, wherein: —the aluminosilicate zeolite is selected from: (i) a zeolite having a 2-dimensional framework structure comprising at least one channel having a 10-membered ring, and having a maximum free sphere diameter of at least 4.8 Angstroms; (ii) a zeolite having a 3-dimensional framework structure comprising at least one channel having a 10-membered ring; or (iii) a zeolite comprising at least one channel having a 12-membered ring; —the promoter is selected from one or more compounds of Formula I: (I) wherein Y is selected from a C1-C4 hydrocarbyl substituent, and wherein each of X and any or all of the Z's may independently be selected from hydrogen, halide, a substituted or unsubstituted hydrocarbyl substituent, or a compound of the formula —CHO, —CO2R, —COR, or —OR, where R is hydrogen or a substituted or unsubstituted hydrocarbyl substituent, and wherein the molar ratio of promoter to methanol is maintained at less than 1.

    Process for dehydrating alcohols to ethers
    4.
    发明授权
    Process for dehydrating alcohols to ethers 有权

    公开(公告)号：US11578026B2

    公开(公告)日：2023-02-14

    申请号：US17433122

    申请日：2020-02-14

    Applicant: BP P.L.C.

    Inventor： Benjamin James Dennis-Smither ,  John Glenn Sunley ,  Fiona Jackson

    IPC: C07C41/09

    Abstract: A process for dehydrating C2+ alcohols to ether products in the presence of a catalyst and promoter, wherein the catalyst is at least one aluminosilicate zeolite catalyst which is a medium pore zeolite having a 3-dimensional framework structure, and the promoter is one or more organic carbonyl compounds or derivatives thereof, and wherein and the molar ratio of promoter to C2+ alcohols is maintained at less than 1.

    Process
    6.
    发明申请
    Process 有权

    公开(公告)号：US20210163390A1

    公开(公告)日：2021-06-03

    申请号：US16641642

    申请日：2018-08-24

    Applicant: BP P.L.C. ,  BP (CHINA) HOLDINGS LTD

    Inventor： Benjamin James Dennis-Smither ,  John Glenn Sunley ,  Zhiqiang Yang

    IPC: C07C41/09 ,  B01J29/40

    Abstract: A process for dehydrating methanol to dimethyl ether using a Brønsted acid catalyst which is a 1-dimensional or a 3-dimensional aluminosilicate zeolite or a heteropolyacid, and a promoter of Formula I CnH(2n+1)CO2CH3 wherein n=1 to 11 or Formula II CmH2m(CO2CH3)2 wherein m=2 to 7 and the molar ratio of promoter to methanol is maintained at less than 1.

    TREATMENT OF ALCOHOLS
    8.
    发明申请
    TREATMENT OF ALCOHOLS 有权
    酒精处理

    公开(公告)号：US20150232399A1

    公开(公告)日：2015-08-20

    申请号：US14428067

    申请日：2013-09-12

    Applicant: BP P.L.C.

    Inventor： Thomas Mark Douglas ,  Andrew John Hogben ,  David John Law ,  John Glenn Sunley ,  Thomas Giles Parsons

    IPC: C07C29/76 ,  C07C1/24

    CPC classification number: C07C29/76 ,  C07C1/24 ,  C07C2529/06 ,  C07C2529/85 ,  C07C31/08 ,  C07C11/04

    Abstract: A process for the treatment of an alcohol composition comprising nitrogen-containing contaminants, the process comprising contacting the alcohol composition with an adsorbent in an adsorption zone, wherein the adsorbent is a transition metal-loaded solid porous material selected from the group consisting of aluminosilicates, silica-aluminas, silicates and aluminas.

    Abstract translation: 一种用于处理包含含氮污染物的醇组合物的方法，所述方法包括使所述醇组合物与吸附区中的吸附剂接触，其中所述吸附剂是选自以下的过渡金属负载固体多孔材料：铝硅酸盐， 二氧化硅 - 氧化铝，硅酸盐和氧化铝。

    Fischer-Tropsch Processes Producing Increased Amounts of Alcohols
    9.
    发明公开
    Fischer-Tropsch Processes Producing Increased Amounts of Alcohols 审中-公开

    公开(公告)号：US20240002317A1

    公开(公告)日：2024-01-04

    申请号：US18252683

    申请日：2021-12-17

    Applicant: BP P.L.C.

    Inventor： Alexander James Paterson ,  John Glenn Sunley

    IPC: C07C29/156 ,  C07C29/151

    CPC classification number: C07C29/156 ,  C07C29/1512

    Abstract: The present disclosure relates generally to compositions and processes for producing Fischer-Tropsch catalysts. In particular, the disclosure provides for a process for producing a product composition comprising alcohols and liquid hydrocarbons via a Fischer-Tropsch synthesis reaction, the process comprising: contacting a mixture of hydrogen and a gaseous carbon oxide that is carbon monoxide, carbon dioxide or a combination thereof and an olefin co-feed with a supported cobalt-manganese Fischer-Tropsch synthesis catalyst to provide the product composition; wherein the olefin co-feed comprises at least one C2-C14 olefin and is present in an amount in the range of 0.001 wt % to 40 wt % relative to the total amount of hydrogen, the gaseous carbon oxide and olefin; wherein a weight ratio of manganese to cobalt in the catalyst is at least 0.05 on an elemental basis.

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