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公开(公告)号:US20250153884A1
公开(公告)日:2025-05-15
申请号:US19024941
申请日:2025-01-16
Applicant: CORNING INCORPORATED
Inventor: Nikolai Aleksandrovich Antipin , Qiang Fu , Petr Gorelchenko , Aniello Mario Palumbo , Michael S Pambianchi , Erick Franklin VanDuyne
Abstract: Glass-ceramic containers and methods of making glass ceramic containers with high transparency and fracture toughness suitable for use as, for example a beverage or food container, such as for example, a baby bottle or personal hydration bottle. The glass ceramic containers may have an average wall thickness in the range of 1 mm to 2.5 mm and a fracture toughness of 1 MPa*m{circumflex over ( )}1/2 or more.
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公开(公告)号:US20240182354A1
公开(公告)日:2024-06-06
申请号:US18426677
申请日:2024-01-30
Applicant: CORNING INCORPORATED
Inventor: Lionel Joel Mary Beunet , Marie Jacqueline Monique Comte , Allan Mark Fredholm , Qiang Fu , Anne Paris , Sophie Peschiera , Charlene Marie Smith
CPC classification number: C03C10/0027 , C03B32/02 , C03C3/093 , C03C10/0018 , C03C10/0045 , C03C10/0054 , C03C21/002 , Y10T428/315
Abstract: Glass-ceramics exhibiting a Vickers indentation crack initiation threshold of at least 15 kgf are disclosed. These glass-ceramics may be ion exchangeable or ion exchanged. The glass-ceramics include a crystalline and amorphous phases generated by subjecting a thin precursor glass article to ceramming cycle having an average cooling rate in the range from about 10° C./minute to about 25° C./minute. In one or more embodiments, the crystalline phase may comprise at least 20 wt % of the glass-ceramics. The glass-ceramics may include β-spodumene ss as the predominant crystalline phase and may exhibit an opacity ≥ about 85% over the wavelength range of 400-700 nm for an about 0.8 mm thickness and colors an observer angle of 10° and a CIE illuminant F02 determined with specular reflectance included of a* between −3 and +3, b* between −6 and +6, and L* between 88 and 97.
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3.
公开(公告)号:US20240174553A1
公开(公告)日:2024-05-30
申请号:US18388009
申请日:2023-11-08
Applicant: CORNING INCORPORATED
Inventor: Carol Ann Click , Qiang Fu , Mathieu Gerard Jacques Hubert , Charlene Marie Smith , Alana Marie Whittier
CPC classification number: C03C10/0027 , C03C4/02 , C03C2204/04
Abstract: A glass-ceramic article, comprising (in mol %):
67-74% SiO2;
2-6% Al2O3;
0.5-1.5% P2O5;
18-25% Li2O;
0-1% Na2O;
0-1% K2O;
1-4% ZrO2;
0-2% CaO; and
0.001-0.5% SnO2. The glass-ceramic article is opaque, and further comprises a lithium disilicate crystalline phase, a β-spodumene solid solution crystalline phase, a Zr-based crystalline phase, and a lithium phosphate crystalline phase. The glass-ceramic article can further comprise a fracture toughness (KIC) of from 1.0 to 3.0 MPa*m1/2, as measured by the Chevron Notch Short Bar Method, and an opacity from 60 to 97%, as measured through the glass-ceramic article with a thickness of 0.5 mm.-
公开(公告)号:US11926555B2
公开(公告)日:2024-03-12
申请号:US17085115
申请日:2020-10-30
Applicant: CORNING INCORPORATED
Inventor: Lionel Joel Mary Beunet , Marie Jacqueline Monique Comte , Allan Mark Fredholm , Qiang Fu , Anne Paris , Sophie Peschiera , Charlene Marie Smith
CPC classification number: C03C10/0027 , C03B32/02 , C03C3/093 , C03C10/0018 , C03C10/0045 , C03C10/0054 , C03C21/002 , Y10T428/315
Abstract: Glass-ceramics exhibiting a Vickers indentation crack initiation threshold of at least 15 kgf are disclosed. These glass-ceramics may be ion exchangeable or ion exchanged. The glass-ceramics include a crystalline and amorphous phases generated by subjecting a thin precursor glass article to ceramming cycle having an average cooling rate in the range from about 10° C./minute to about 25° C./minute. In one or more embodiments, the crystalline phase may comprise at least 20 wt % of the glass-ceramics. The glass-ceramics may include β-spodumene ss as the predominant crystalline phase and may exhibit an opacity≥about 85% over the wavelength range of 400-700 nm for an about 0.8 mm thickness and colors an observer angle of 10° and a CIE illuminant F02 determined with specular reflectance included of a* between −3 and +3, b* between −6 and +6, and L* between 88 and 97.
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公开(公告)号:US11845689B2
公开(公告)日:2023-12-19
申请号:US17040323
申请日:2019-04-09
Applicant: CORNING INCORPORATED
Inventor: Kirk Wegner Christiansen , Qiang Fu , Petr Gorelchenko , Aniello Mario Palumbo , Michael S Pambianchi , Erick Franklin VanDuyne
CPC classification number: C03C10/0027 , B65D1/0207 , C03B32/02 , C03C2204/00 , Y10T428/131
Abstract: Locally cerammed optically transparent glass-ceramic articles for consumer products. The locally cerammed glass-ceramic articles may have one or more primary glass-ceramic regions including primary crystal phases of a glass-ceramic material and one or more secondary glass-ceramic regions including secondary crystal phases of the glass-ceramic material. The primary glass-ceramic region(s) may be optically transparent and the secondary glass-ceramic region(s) may be non-optically transparent. The primary glass-ceramic region(s) may have a fracture toughness less than the fracture toughness of the secondary glass-ceramic region(s).
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公开(公告)号:US11724957B2
公开(公告)日:2023-08-15
申请号:US16809173
申请日:2020-03-04
Applicant: CORNING INCORPORATED
Inventor: Qiang Fu
CPC classification number: C03C3/066 , C03C12/00 , C03C13/00 , C03C2204/02
Abstract: An antibacterial composition, includes: a borate-based glass material having a composition of: 0-25 wt. % SiO2, 30-75 wt. % B2O3, 0-10 wt. % P2O5, 0-30 wt. % Al2O3, 0-5 wt. % Li2O, 1-25 wt. % Na2O, 0-15 wt. % K2O, 0-10 wt. % MgO, 10-25 wt. % CaO, 12-30 wt. % MO, 8-25 wt. % R2O, and 30-75 (B2O3+Al2O3), such that at least one of P2O5 or Al2O3 is present, MO is the sum of MgO, CaO, SrO, and BaO, R2O is the sum of Na2O, K2O, Li2O, and Rb2O, and the borate-based glass material is configured to achieve at least a 3.5-log kill rate of at least one of E. coli, P. gingivalis, or S. mutans bacteria.
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7.
公开(公告)号:US11718554B2
公开(公告)日:2023-08-08
申请号:US17522221
申请日:2021-11-09
Applicant: CORNING INCORPORATED
Inventor: George Halsey Beall , Matthew John Dejneka , Qiang Fu , Sinue Gomez , Robert Michael Morena , Charlene Marie Smith
IPC: C03C3/097 , C03C3/087 , C03C21/00 , C03C3/091 , C03C3/093 , B32B17/06 , H05K5/03 , C03C3/085 , C03C4/18 , H05K5/00
CPC classification number: C03C3/097 , B32B17/06 , C03C3/085 , C03C3/087 , C03C3/091 , C03C3/093 , C03C21/002 , H05K5/03 , B32B2307/50 , C03C4/18 , C03C2204/00 , H05K5/0017
Abstract: A group of glass compositions in the Li2O—Al2O3—SiO2—B2O3 family that can be chemically strengthened in single or multiple ion exchange baths containing at least one of NaNO3 and KNO3 for a short time (2-4 hours) to develop a deep depth of layer (DOL). In some instances, the DOL is at least 70 μm; in others, at least about 100 μm. The ion exchanged glasses have a high damage resistance (indentation fracture toughness ranging form greater than 10 kgf to greater than 50 kgf) that is better than or at least comparable to that of sodium aluminosilicate glasses.
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公开(公告)号:US20230167014A1
公开(公告)日:2023-06-01
申请号:US17992183
申请日:2022-11-22
Applicant: CORNING INCORPORATED
Inventor: George Halsey Beall , Qiang Fu , Charlene Marie Smith , Alana Marie Whittier
CPC classification number: C03C10/0027 , C03C10/0054 , C03C3/085 , H05K5/02 , C03B32/02 , C03C21/002
Abstract: A transparent β-spodumene glass-ceramic is provided. The glass-ceramic includes a primary crystal phase including a β-spodumene solid solution, a secondary crystal phase including tetragonal ZrO2, and an amorphous phase. The glass-ceramic may be ion exchanged utilizing molten alkali nitrate salt baths. Methods for producing the glass-ceramic are also provided.
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公开(公告)号:US20230133219A1
公开(公告)日:2023-05-04
申请号:US17980955
申请日:2022-11-04
Applicant: Corning Incorporated
Inventor: Qiang Fu , Aize Li , Charisse Marye Spier
IPC: C03C3/087
Abstract: A silicate-based glass composition includes 15-65 wt. % SiO2, 15-50 wt. % CaO, 1-30 wt. % P2O5, and 1-20 wt. % ZrO2, such that the composition has a hydrolytic resistance of glass grains (HGB) of at most 3, when measured by International Organization for Standardization section 719 (ISO 719), and forms a bioactive crystalline phase in simulated body fluid.
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公开(公告)号:US20220169557A1
公开(公告)日:2022-06-02
申请号:US17533514
申请日:2021-11-23
Applicant: CORNING INCORPORATED
Inventor: Qiang Fu , Yuhui Jin , Jackie Lynn Kurzejewski , Santona Pal , Florence Christine Monique Verrier , Lei Yuan
Abstract: An antimicrobial glass-based article comprises: a first major surface opposing a second major surface. A first surface region extends 1 micron into the article from the first major surface. The first surface region has an average Ag2O concentration across the first surface region of equal to or greater than 10 mol % and equal to or less than 30 mol %, and a surface roughness Ra of 100 nm or greater.
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