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1.发明申请HYDRODESULFURIZATION, DEOXYGENATION AND DEWAXING PROCESSES WITH WATER STABLE CATALYSTS FOR BIOMASS-CONTAINING HYDROCARBON FEEDSTOCKS 审中-公开用于生物质含烃油料的水稳定催化剂的水解，脱氧和脱蜡工艺公开(公告)号：US20130338414A1
公开(公告)日：2013-12-19
申请号：US13906907
申请日：2013-05-31
Applicant: ExxonMobil Research and Engineering Company
Inventor： Bradley R. Fingland , Joseph E. Gatt
IPC: C10G65/02
CPC classification number: C10G65/02 , C10G3/47 , C10G3/49 , C10G3/50 , C10G45/10 , C10G45/12 , C10G45/62 , C10G45/64 , C10G2300/1011 , C10G2300/202 , Y02P30/20
Abstract: This invention relates to a method for hydroprocessing feedstreams containing both sulfur-containing mineral oils and biomass-derived feedstocks in a single reactor configuration. The process produces a desulfurized, deoxygenated and dewaxed hydrocarbon product having reduced oxygen content, increased iso-paraffin content, low n-paraffin content, and good cold flow properties. In preferred embodiments, the processes herein utilize water tolerant hydrodewaxing catalysts in order to prevent deactivation and/or catalyst loss due to water produced during the deoxygenation reactions in the biomass components.
Abstract translation: 本发明涉及在单一反应器构型中加氢处理含有含硫矿物油和生物质衍生原料的原料流的方法。 该方法产生具有降低的氧含量，增加的异链烷烃含量，低正链烷烃含量和良好的冷流特性的脱硫，脱氧和脱蜡的烃产物。 在优选的实施方案中，本文的方法使用耐水加氢脱蜡催化剂，以防止由于在生物量组分中的脱氧反应期间产生的水而导致的失活和/或催化剂损失。
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公开(公告)号：US11220429B2
公开(公告)日：2022-01-11
申请号：US16838726
申请日：2020-04-02
Applicant: ExxonMobil Research and Engineering Company
Inventor： Anastasios I. Skoulidas , Everett J. O'Neal , Joseph E. Gatt , Anjaneya S. Kovvali
Abstract: Systems and methods are provided for improving thermal management and/or efficiency of reaction systems including a reverse flow reactor for performance of at least one endothermic reaction and at least one supplemental exothermic reaction. The supplemental exothermic reaction can be performed in the recuperation zone of the reverse flow reactor system. By integrating the supplemental exothermic reaction into the recuperation zone, the heat generated from the supplemental exothermic reaction can be absorbed by heat transfer surfaces in the recuperation zone. The adsorbed heat can then be used to heat at least one of the fuel and the oxidant for the combustion reaction performed during regeneration, thus reducing the amount of combustion that is needed to achieve a desired temperature profile at the end of the regeneration step.
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公开(公告)号：US20210061657A1
公开(公告)日：2021-03-04
申请号：US16838726
申请日：2020-04-02
Applicant: ExxonMobil Research and Engineering Company
Inventor： Anastasios I. Skoulidas , Everett J. O'Neal , Joseph E. Gatt , Anjaneya S. Kovvali
Abstract: Systems and methods are provided for improving thermal management and/or efficiency of reaction systems including a reverse flow reactor for performance of at least one endothermic reaction and at least one supplemental exothermic reaction. The supplemental exothermic reaction can be performed in the recuperation zone of the reverse flow reactor system. By integrating the supplemental exothermic reaction into the recuperation zone, the heat generated from the supplemental exothermic reaction can be absorbed by heat transfer surfaces in the recuperation zone. The adsorbed heat can then be used to heat at least one of the fuel and the oxidant for the combustion reaction performed during regeneration, thus reducing the amount of combustion that is needed to achieve a desired temperature profile at the end of the regeneration step.
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Patent Agency Ranking
公开(公告)号：US20220112432A1
公开(公告)日：2022-04-14
申请号：US17496644
申请日：2021-10-07
Applicant: ExxonMobil Research and Engineering Company
Inventor： Wesley Sattler , Keith R. Hajkowski , Changmin Chun , Partha Nandi , Vera Grankina , Joseph E. Gatt , Ning Ma , Anastasios Skoulidas , William R. Gunther , Everett J. O'Neal
Abstract: Systems and methods are provided for using size-reversing materials in vessels where direct heating is used to at least partially provide heat for reforming reactions under cyclic reforming conditions. An example of a size-reversing material is the combination of NiO and Al2O3. It has been discovered that size-reversing materials can undergo a phase transition that can assist with re-dispersion of metal at elevated temperatures. This can assist with maintaining catalytic activity for reforming over longer time periods in the presence of cyclic reforming conditions.
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公开(公告)号：US20220112082A1
公开(公告)日：2022-04-14
申请号：US17496592
申请日：2021-10-07
Applicant: ExxonMobil Research and Engineering Company
Inventor： Changmin Chun , Wesley Sattler , Joseph E. Gatt , Keith R. Hajkowski , Everett J. O'Neal , William R. Gunther , Anastasios Skoulidas
IPC: C01B3/38 , B01J35/10 , B01J37/08 , C01B3/40 , B01J29/74 , B01J23/46 , B01J21/04 , B01J23/10 , B01J23/755 , B01J23/00 , B01J35/00 , B01J35/04 , B01J37/03 , B01J37/04
Abstract: Catalyst systems are provided for reforming of hydrocarbons, along with methods for using such catalyst systems. The catalyst systems can be deposited or otherwise coated on a surface or structure, such as a monolith, to achieve improved activity and/or structural stability. The metal oxide support layer can correspond to a thermally stable metal oxide support layer, such as a metal oxide support layer that is thermally phase stable at temperatures of 800° C. to 1600° C. The catalyst systems can be beneficial for use in cyclical reaction environments, such as reverse flow reactors or other types of reactors that are operated using flows in opposing directions and different times within a reaction cycle.
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公开(公告)号：US20220025282A1
公开(公告)日：2022-01-27
申请号：US17364989
申请日：2021-07-01
Applicant: ExxonMobil Research and Engineering Company
Inventor： Xiaochun Xu , Xinrui Yu , Shifang Luo , Randolph J. Smiley , Joseph E. Gatt
Abstract: Methods of refining a whole crude oil stream. The methods involve first processing the crude either through a hydrotreating reactor comprising a dewaxing reactor bed or a flash evaporation separator. The treated streams are then further processed through a demetalization reactor bed, a hydroprocessing reactor bed, or both. The stream can then be still further processed via additional hydrotreating, distillation, or both.
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公开(公告)号：US10995286B2
公开(公告)日：2021-05-04
申请号：US16709205
申请日：2019-12-10
Applicant: ExxonMobil Research and Engineering Company
Inventor： Joseph E. Gatt , William W. Lonergan , Scott J. Weigel , Ivy D. Johnson , Karl G. Strohmaier , Simon C. Weston
Abstract: In a process for improving the cold flow properties of a hydrocarbon feedstock, the feedstock is contacted with a catalyst composition comprising an EMM-17 molecular sieve and a hydrogenation component under dewaxing conditions effective to produce a dewaxed product having a cloud point and/or pour point that is reduced relative to the cloud point and/or pour point of the feedstock by at least 5° C.
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公开(公告)号：US20210061656A1
公开(公告)日：2021-03-04
申请号：US16838654
申请日：2020-04-02
Applicant: ExxonMobil Research and Engineering Company
Inventor： Everett J. O'Neal , Anastasios I. Skoulidas , Joseph E. Gatt
Abstract: Systems and methods are provided for hydrogenation of CO2 in a reverse flow reactor environment via a reverse water gas shift reaction. A reverse flow reactor environment is suitable for performing endothermic reactions at high temperatures, where a reactant flow is passed into the reactor in a first portion of the cycle in a first flow direction while a combustion or heating flow is passed into the reactor during a second portion of the reaction cycle from the opposite direction. This can allow for efficient heating of surfaces within the reactor to provide heat for the endothermic reverse water gas shift reaction while reducing or minimizing incorporation of combustion products into the desired reaction products.
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