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公开(公告)号：US20210309587A1
公开(公告)日：2021-10-07
申请号：US16910027
申请日：2020-06-23
Applicant: ExxonMobil Research and Engineering Company
Inventor： Arsam Behkish , Lei Zhang , Brandon J. O'Neill , Mark A. Deimund , Alice Lin
Abstract: Systems and methods are provided for oligomerization of olefins to distillate boiling range products while also recycling naphtha boiling range olefins as part of the feed. By performing the olefin oligomerization while also recycling naphtha boiling range olefins, it has been discovered that the resulting distillate boiling range products can have an unexpected improvement in diesel combustion quality, such as an unexpected improvement in cetane rating. In order to manage coke formation and maintain consistent activity profile for the oligomerization catalyst, the reaction can be performed in a moving bed reactor. Additional temperature control can be maintained by the recycling of the naphtha boiling range portions of the oligomerization product back to the reactor.
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公开(公告)号：US11118120B2
公开(公告)日：2021-09-14
申请号：US16707667
申请日：2019-12-09
Applicant: ExxonMobil Research and Engineering Company
Inventor： Stephen H. Brown , Samia Ilias , Randolph J. Smiley , Richard Demmin , Shifang Luo , Brenda A. Raich , Aldrin G. Cuevas , Keith Wilson , Jesse R. McManus , Lei Zhang
Abstract: A method of upgrading refining streams with high polynucleararomatic hydrocarbon (PNA) concentrations can include: hydrocracking a PNA feed in the presence of a catalyst and hydrogen at 380° C. to 430° C., 2500 psig or greater, and 0.1 hr−1 to 5 hr−1 liquid hourly space velocity (LSHV), wherein the weight ratio of PNA feed to hydrogen is 30:1 to 10:1, wherein the PNA feed comprises 25 wt % or less of hydrocarbons having a boiling point of 700° F. (371° C.) or less and having an aromatic content of 50 wt % or greater to form a product comprising 50 wt % or greater of the hydrocarbons having a boiling point of 700° F. (371° C.) or less and having an aromatic content of 20 wt % or less.
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公开(公告)号：US10414991B2
公开(公告)日：2019-09-17
申请号：US15626288
申请日：2017-06-19
Applicant: ExxonMobil Research and Engineering Company
Inventor： Benjamin S. Umansky , Himanshu Gupta , John D. Nelson , Cindy J. Hughart , Jane C. Cheng , Steven W. Levine , Stephen H. Brown , Todd P. Marut , David C. Dankworth , Stuart L. Soled , Thomas F. Degnan, Jr. , Robert J. Falkiner , Mohsen N. Harandi , Juan D. Henao , Lei Zhang , Chuansheng Bai , Richard C. Dougherty
IPC: C10G65/12 , B01J27/185 , B01J27/186 , B01J35/10 , C10G31/09 , C10G45/16 , C10G67/14 , B01J23/885 , B01J27/19 , C10G45/08 , C10G47/04 , B01J23/882
Abstract: Systems and methods are provided for hydroconversion of a heavy oil feed under slurry hydroprocessing conditions and/or solvent assisted hydroprocessing conditions. The systems and methods for slurry hydroconversion can include the use of a configuration that can allow for improved separation of catalyst particles from the slurry hydroprocessing effluent. In addition to allowing for improved catalyst recycle, an amount of fines in the slurry hydroconversion effluent can be reduced or minimized. This can facilitate further processing or handling of any “pitch” generated during the slurry hydroconversion. The systems and methods for solvent assisted hydroprocessing can include processing of a heavy oil feed in conjunction with a high solvency dispersive power crude.
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公开(公告)号：US20180318790A1
公开(公告)日：2018-11-08
申请号：US16031449
申请日：2018-07-10
Applicant: ExxonMobil Research and Engineering Company
Inventor： Paul Podsiadlo , Quanchang Li , David Charles Calabro , Jean Willem Lodewijk Beeckman , Lei Zhang , Kiara M. Benitez , Matthew Scott Ide , Stephen John McCarthy , Mobae Afeworki , Simon Christopher Weston , Preeti Kamakoti , Matu J. Shah , Wenyih Frank Lai , Meghan Kochersperger , David A. Griffin , Ivy D. Johnson
IPC: B01J20/22 , C07F7/08 , C23C16/56 , C10M101/02 , C10G45/52 , C10G45/44 , C10G31/09 , C10G25/00 , C08G77/60 , C08G77/26 , C08F210/02 , C08F36/20 , C08F36/04 , C08F4/64 , C08F4/02 , C08F2/42 , C08F2/10 , C08F2/00 , C01B37/00 , B01J37/02 , B01J35/10 , B01J31/02 , B01J29/03 , B01J23/44 , B01J20/32 , B01J20/30 , B01J20/286 , B01J20/28 , B01J20/26 , B01J20/18 , B01J20/16 , B01J20/10 , B01J20/08 , B01J20/06 , B01J20/02 , B01D71/70 , B01D69/10 , B01D67/00 , B01D53/047 , B01D53/04 , B01D53/02 , B01D15/00
CPC classification number: B01J20/223 , B01D15/00 , B01D53/02 , B01D53/04 , B01D53/0462 , B01D53/047 , B01D67/0088 , B01D69/10 , B01D71/70 , B01D2253/20 , B01D2253/25 , B01D2256/245 , B01D2257/302 , B01D2257/304 , B01D2257/40 , B01D2257/504 , B01D2257/80 , B01J20/0229 , B01J20/0237 , B01J20/06 , B01J20/08 , B01J20/10 , B01J20/103 , B01J20/16 , B01J20/18 , B01J20/22 , B01J20/226 , B01J20/262 , B01J20/264 , B01J20/28011 , B01J20/28057 , B01J20/28061 , B01J20/28064 , B01J20/28066 , B01J20/28069 , B01J20/28071 , B01J20/28073 , B01J20/28076 , B01J20/28078 , B01J20/28083 , B01J20/286 , B01J20/3042 , B01J20/3204 , B01J20/3212 , B01J20/3236 , B01J20/3238 , B01J20/3272 , B01J23/42 , B01J23/44 , B01J29/0308 , B01J31/0274 , B01J31/125 , B01J31/127 , B01J35/1019 , B01J35/1023 , B01J35/1028 , B01J35/1061 , B01J37/0213 , B01J37/0236 , B01J37/036 , B01J2220/86 , B01J2231/641 , B01J2231/646 , C01B37/00 , C01B39/00 , C07F7/08 , C07F7/0807 , C07F7/081 , C07F7/0818 , C08F2/00 , C08F2/10 , C08F2/42 , C08F4/027 , C08F4/64089 , C08F4/64148 , C08F4/64158 , C08F4/659 , C08F4/65912 , C08F4/65916 , C08F4/65925 , C08F4/65927 , C08F36/04 , C08F36/20 , C08F210/02 , C08G77/26 , C08G77/60 , C10G25/003 , C10G31/09 , C10G45/44 , C10G45/46 , C10G45/52 , C10M101/02 , C23C16/56 , Y02C20/20 , C08F210/14 , C08F4/64048 , C08F4/64013 , C08F4/64189 , C08F4/64193
Abstract: Hydrogenation catalysts for aromatic hydrogenation including an organosilica material support, which is a polymer comprising independent units of a monomer of Formula [Z1OZ2OSiCH2]3 (I), wherein each Z1 and Z2 independently represent a hydrogen atom, a C1-C4 alkyl group or a bond to a silicon atom of another monomer; and at least one catalyst metal are provided herein. Methods of making the hydrogenation catalysts and processes of using, e.g., aromatic hydrogenation, the hydrogenation catalyst are also provided herein.
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公开(公告)号：US10022700B2
公开(公告)日：2018-07-17
申请号：US14966284
申请日：2015-12-11
Applicant: ExxonMobil Research and Engineering Company
Inventor： Paul Podsiadlo , Quanchang Li , David Charles Calabro , Lei Zhang , Kiara M. Benitez , Himanshu Gupta , Xiaochun Xu , Scott J. Weigel , Darryl Donald Lacy , Bal Kaul , James William Gleeson , Wenyih Frank Lai , Mobae Afeworki , Simon Christopher Weston , David A. Griffin , Meghan Nines
IPC: B01J20/22 , B01D15/00 , B01J20/06 , B01J20/08 , B01J20/10 , B01J20/18 , B01J20/26 , B01D53/04 , B01J20/28 , B01J20/286 , B01J20/30 , B01J20/32 , B01J29/03 , C01B37/00 , C08F36/04 , C08F36/20 , C08G77/60 , C08F2/00 , C08F2/42 , C10G25/00 , C10G45/44 , B01J20/02 , B01J20/16 , B01D53/02 , B01D53/047 , B01J23/44 , B01J31/02 , B01J37/02 , C10G45/52 , B01J35/10 , C07F7/08 , C08G77/26 , C10M101/02 , B01D67/00 , B01D69/10 , B01D71/70 , C10G31/09 , C23C16/56 , C08F2/10 , C08F4/659 , C08F4/6592
Abstract: Methods of preparing organosilica materials, which are a polymer comprising of at least one independent cyclic polyurea monomer of Formula wherein each R1 is a Z1OZ2Z3SiZ4 group, wherein each Z1 represents a hydrogen atom, a C1-C4 alkyl group, or a bond to a silicon atom of another monomer unit; each Z2 and Z3 independently represent a hydroxyl group, a C1-C4 alkyl group, a C1-C4 alkoxy group or an oxygen atom bonded to a silicon atom of another monomer unit; and each Z4 represents a C1-C8 alkylene group bonded to a nitrogen atom of the cyclic polyurea are provided herein. Methods of preparing and processes of using the organosilica materials, e.g., for gas separation, color removal, etc., are also provided herein.
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Patent Agency Ranking
公开(公告)号：US10227539B2
公开(公告)日：2019-03-12
申请号：US15198346
申请日：2016-06-30
Applicant: ExxonMobil Research and Engineering Company
Inventor： Michael P. Lanci , Stuart L. Soled , Javier Guzman , Sabato Miseo , Thomas E. Green , Joseph E. Baumgartner , Lei Zhang , Christine E. Kliewer , Lukasz Koziol , Kanmi Mao , Tracie L. Owens , Gary P. Schleicher
IPC: C10G45/00 , C10M101/02 , B01J23/42 , B01J23/44 , B01J31/02 , B01J31/28 , B01J37/02 , C10G45/34 , C10G45/46 , C10G45/52 , C10G65/12 , B01J37/08 , B01J35/00 , B01J37/00 , B01J21/12 , B01J23/46
Abstract: Methods are provided for modifying hydrogenation catalysts having silica supports (or other non-alumina supports) with additional alumina, and using such catalysts to achieve unexpectedly superior hydrogenation of feedstocks. The modified hydrogenation catalysts can have a relatively low cracking activity while providing an increased activity for hydrogenation.
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公开(公告)号：US10227535B2
公开(公告)日：2019-03-12
申请号：US15198397
申请日：2016-06-30
Applicant: ExxonMobil Research and Engineering Company
Inventor： Michael P. Lanci , Stuart L. Soled , Javier Guzman , Sabato Miseo , Thomas E. Green , Joseph E. Baumgartner , Lei Zhang , Christine E. Kliewer , Lukasz Koziol , Kanmi Mao , Tracie L. Owens , Gary P. Schleicher , Xiaochun Xu
IPC: C10G45/52 , C10G45/00 , B01J23/42 , B01J23/44 , B01J21/04 , B01J21/08 , B01J21/12 , B01J23/46 , B01J31/02 , B01J31/28 , B01J37/02 , C10G45/34 , C10G45/46 , C10G65/08
Abstract: Methods are provided for modifying hydrogenation catalysts having silica supports (or other non-alumina supports) with additional alumina, and using such catalysts to achieve unexpectedly superior hydrogenation of feedstocks. The modified hydrogenation catalysts can have a relatively low cracking activity while providing an increased activity for hydrogenation.
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公开(公告)号：US09359565B2
公开(公告)日：2016-06-07
申请号：US14132206
申请日：2013-12-18
Applicant: ExxonMobil Research and Engineering Company
Inventor： Krista Marie Prentice , Jason M. McMullan , Michel Daage , Gregory J. DeMartin , John Stephen Szobota , Ronald M. Gould , Anastasios Ioannis Skoulidas , Ajit Bhaskar Dandekar , Patrick Loring Hanks , Charles Lambert Baker, Jr. , Lei Zhang , X B Cox, III
Abstract: Systems and methods are provided for using field enhanced separations to produce multiple fractions from a petroleum input. A liquid thermal diffusion and/or electric field separation is used to produce the fractions. The fractions can then be used to form multiple outputs that share a first feature while being different with regard to a second feature. For example, a first fraction from the plurality of fractions can have a desired value for a first property such as viscosity index. Two or more additional fractions from the plurality of fractions can then be blended together to make a blended fraction or output. The blended fraction can have a value for the first property that is substantially similar to the value for the first fraction. However, for a second property, the first fraction and the blended fraction can have distinct values. As a result, multiple output fractions can be formed that share a first feature but differ in a second feature.
Abstract translation: 提供了系统和方法，用于使用场增强分离从石油输入产生多个馏分。 使用液体热扩散和/或电场分离来生产级分。 然后可以使用分数来形成共享第一特征的多个输出，同时关于第二特征不同。 例如，来自多个级分的第一级分可以具有用于第一性质（例如粘度指数）的期望值。 然后将来自多个馏分的两个或更多个附加馏分混合在一起以制备混合部分或输出。 混合分数可以具有基本上类似于第一级分的值的第一性质的值。 然而，对于第二特性，第一级分和混合级分可以具有不同的值。 结果，可以形成共享第一特征但在第二特征中不同的多个输出分数。
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公开(公告)号：US20220106529A1
公开(公告)日：2022-04-07
申请号：US17060126
申请日：2020-10-01
Applicant: ExxonMobil Research and Engineering Company
Inventor： Matthew T. Kapelewski , Lei Zhang , Brandon J. O'Neill
Abstract: Processes for the catalytic conversion of alcohols and/or ethers to olefins over zeolite catalysts are described. ZSM-48 and metal containing variants, such as Zn ZSM-48, produce high yields of olefins, particularly ethylene or C3+ olefins, between 200 and 500° C.
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公开(公告)号：US20220106239A1
公开(公告)日：2022-04-07
申请号：US17060120
申请日：2020-10-01
Applicant: ExxonMobil Research and Engineering Company
Inventor： Matthew T. Kapelewski , Lei Zhang , Brandon J. O'Neill
Abstract: Processes for the catalytic conversion of alcohols and/or ethers to olefins over zeolite catalysts are described. Self-bound ZSM-5 and metal containing variants, such as Zn ZSM-5, produce high yields of olefins, particularly C3+ olefins, between 250 and 450° C.
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