公开(公告)号：US10022700B2

公开(公告)日：2018-07-17

申请号：US14966284

申请日：2015-12-11

Applicant: ExxonMobil Research and Engineering Company

Inventor： Paul Podsiadlo ,  Quanchang Li ,  David Charles Calabro ,  Lei Zhang ,  Kiara M. Benitez ,  Himanshu Gupta ,  Xiaochun Xu ,  Scott J. Weigel ,  Darryl Donald Lacy ,  Bal Kaul ,  James William Gleeson ,  Wenyih Frank Lai ,  Mobae Afeworki ,  Simon Christopher Weston ,  David A. Griffin ,  Meghan Nines

IPC: B01J20/22 ,  B01D15/00 ,  B01J20/06 ,  B01J20/08 ,  B01J20/10 ,  B01J20/18 ,  B01J20/26 ,  B01D53/04 ,  B01J20/28 ,  B01J20/286 ,  B01J20/30 ,  B01J20/32 ,  B01J29/03 ,  C01B37/00 ,  C08F36/04 ,  C08F36/20 ,  C08G77/60 ,  C08F2/00 ,  C08F2/42 ,  C10G25/00 ,  C10G45/44 ,  B01J20/02 ,  B01J20/16 ,  B01D53/02 ,  B01D53/047 ,  B01J23/44 ,  B01J31/02 ,  B01J37/02 ,  C10G45/52 ,  B01J35/10 ,  C07F7/08 ,  C08G77/26 ,  C10M101/02 ,  B01D67/00 ,  B01D69/10 ,  B01D71/70 ,  C10G31/09 ,  C23C16/56 ,  C08F2/10 ,  C08F4/659 ,  C08F4/6592

Abstract: Methods of preparing organosilica materials, which are a polymer comprising of at least one independent cyclic polyurea monomer of Formula wherein each R1 is a Z1OZ2Z3SiZ4 group, wherein each Z1 represents a hydrogen atom, a C1-C4 alkyl group, or a bond to a silicon atom of another monomer unit; each Z2 and Z3 independently represent a hydroxyl group, a C1-C4 alkyl group, a C1-C4 alkoxy group or an oxygen atom bonded to a silicon atom of another monomer unit; and each Z4 represents a C1-C8 alkylene group bonded to a nitrogen atom of the cyclic polyurea are provided herein. Methods of preparing and processes of using the organosilica materials, e.g., for gas separation, color removal, etc., are also provided herein.

公开(公告)号：US09968882B2

公开(公告)日：2018-05-15

申请号：US15274382

申请日：2016-09-23

Applicant: ExxonMobil Research and Engineering Company

Inventor： Simon C. Weston ,  Mobae Afeworki ,  Bhupender S. Minhas ,  Ramesh Gupta ,  Hugo S. Caram ,  Manoj K. Chaudhury ,  Hans Thomann ,  Hilda B. Vroman ,  Meghan Nines

IPC: B01D53/04 ,  B01J20/22 ,  B01J20/26 ,  B01J20/18 ,  B01J20/32 ,  B01D53/14

CPC classification number: B01D53/0462 ,  B01D53/0423 ,  B01D53/0446 ,  B01D53/1475 ,  B01D2253/108 ,  B01D2253/204 ,  B01D2253/25 ,  B01D2257/504 ,  B01J20/18 ,  B01J20/22 ,  B01J20/226 ,  B01J20/262 ,  B01J20/3204 ,  B01J20/3206 ,  B01J20/3214 ,  B01J20/3246 ,  B01J20/3272 ,  Y02C10/08

Abstract: A heat transfer fluid can be used as part of a multi-phase adsorption environment to allow for improved separations of gas components using a solid adsorbent. The heat transfer fluid can reduce or minimize the temperature increase of the solid adsorbent that occurs during an adsorption cycle. Reducing or minimizing such a temperature increase can enhance the working capacity for an adsorbent and/or enable the use of adsorbents that are not practical for commercial scale adsorption using conventional adsorption methods. The multi-phase adsorption environment can correspond to a trickle bed environment, a slurry environment, or another convenient environment where at least a partial liquid phase of a heat transfer fluid is present during gas adsorption by a solid adsorbent.

公开(公告)号：US20170087506A1

公开(公告)日：2017-03-30

申请号：US15274382

申请日：2016-09-23

Applicant: ExxonMobil Research and Engineering Company

Inventor： Simon C. WESTON ,  Mobae AFEWORKI ,  Bhupender S. MINHAS ,  Ramesh GUPTA ,  Hugo S. CARAM ,  Manoj K. CHAUDHURY ,  Hans THOMANN ,  Hilda B. Vroman ,  Meghan Nines

IPC: B01D53/04 ,  B01J20/32 ,  B01J20/18 ,  B01J20/22 ,  B01J20/26

CPC classification number: B01D53/0462 ,  B01D53/0423 ,  B01D53/0446 ,  B01D53/1475 ,  B01D2253/108 ,  B01D2253/204 ,  B01D2253/25 ,  B01D2257/504 ,  B01J20/18 ,  B01J20/22 ,  B01J20/226 ,  B01J20/262 ,  B01J20/3204 ,  B01J20/3206 ,  B01J20/3214 ,  B01J20/3246 ,  B01J20/3272 ,  Y02C10/08

Abstract: A heat transfer fluid can be used as part of a multi-phase adsorption environment to allow for improved separations of gas components using a solid adsorbent. The heat transfer fluid can reduce or minimize the temperature increase of the solid adsorbent that occurs during an adsorption cycle. Reducing or minimizing such a temperature increase can enhance the working capacity for an adsorbent and/or enable the use of adsorbents that are not practical for commercial scale adsorption using conventional adsorption methods. The multi-phase adsorption environment can correspond to a trickle bed environment, a slurry environment, or another convenient environment where at least a partial liquid phase of a heat transfer fluid is present during gas adsorption by a solid adsorbent.