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公开(公告)号:US20210115342A1
公开(公告)日:2021-04-22
申请号:US16943513
申请日:2020-07-30
Applicant: ExxonMobil Research and Engineering Company
Inventor: Mohsen N. Harandi , Yira Y. Aponte Torrealba
IPC: C10G35/095 , B01J29/40
Abstract: Provided are novel process for upgrading naphtha and increasing the yield of reformate. Olefinic naphtha and light paraffins are combined and fed to a catalytic fluidized bed reactor maintained at a temperature about 775° F. and about 1250° F. and an operating pressure between about 10 psig and about 500 psig to produce a product comprising at least 1 wt. % higher C5+ hydrocarbon than the combined feed and at least 55 wt. % aromatics.
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公开(公告)号:US20210018347A1
公开(公告)日:2021-01-21
申请号:US16930786
申请日:2020-07-16
Applicant: ExxonMobil Research and Engineering Company
Inventor: George A. Khoury , Erin S. Percell , Mohsen N. Harandi , Nicholas W. Silvestri
Abstract: A method for identifying sensor drift can include: setting an autocorrelation threshold for a sensor in a long-short term memory (LSTM) model developed based on historical process measurements from an analogous sensor to a sensor; collecting measured data from the sensor; applying the LSTM model to the measured data from the sensor, wherein applying the LSTM model comprises: applying the LSTM model to the measured data from the sensor to yield LSTM predicted data; calculating key performance indicators (KPIs) of the LSTM data based on an accumulated slow drift error (ASDE) model, wherein the KPIs comprise an error, an accumulated prediction error, an accumulated slow-drift error, and an estimated autocorrelation; and identifying sensor drift when the estimated autocorrelation violates the autocorrelation threshold.
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公开(公告)号:US20200239785A1
公开(公告)日:2020-07-30
申请号:US16741906
申请日:2020-01-14
Applicant: ExxonMobil Research and Engineering Company
Inventor: Charles R. Bolz , Suriyanarayanan Rajagopalan , Mohsen N. Harandi , David W. Staubs
Abstract: Systems and processes for removing organic acids from liquid hydrocarbon product streams are provided. The systems and processes can include injecting an ammoniated water wash into a liquid hydrocarbon product stream, such as an effluent stream from a methanol conversion process, and subsequently separating the treated liquid hydrocarbon product stream from the wash water. The addition of ammonia can reduce the amount of water wash by an unexpected amount.
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公开(公告)号:US10414991B2
公开(公告)日:2019-09-17
申请号:US15626288
申请日:2017-06-19
Applicant: ExxonMobil Research and Engineering Company
Inventor: Benjamin S. Umansky , Himanshu Gupta , John D. Nelson , Cindy J. Hughart , Jane C. Cheng , Steven W. Levine , Stephen H. Brown , Todd P. Marut , David C. Dankworth , Stuart L. Soled , Thomas F. Degnan, Jr. , Robert J. Falkiner , Mohsen N. Harandi , Juan D. Henao , Lei Zhang , Chuansheng Bai , Richard C. Dougherty
IPC: C10G65/12 , B01J27/185 , B01J27/186 , B01J35/10 , C10G31/09 , C10G45/16 , C10G67/14 , B01J23/885 , B01J27/19 , C10G45/08 , C10G47/04 , B01J23/882
Abstract: Systems and methods are provided for hydroconversion of a heavy oil feed under slurry hydroprocessing conditions and/or solvent assisted hydroprocessing conditions. The systems and methods for slurry hydroconversion can include the use of a configuration that can allow for improved separation of catalyst particles from the slurry hydroprocessing effluent. In addition to allowing for improved catalyst recycle, an amount of fines in the slurry hydroconversion effluent can be reduced or minimized. This can facilitate further processing or handling of any “pitch” generated during the slurry hydroconversion. The systems and methods for solvent assisted hydroprocessing can include processing of a heavy oil feed in conjunction with a high solvency dispersive power crude.
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公开(公告)号:US20190144768A1
公开(公告)日:2019-05-16
申请号:US15812340
申请日:2017-11-14
Applicant: ExxonMobil Research and Engineering Company
Inventor: Mohsen N. Harandi , Suriyanarayanan Rajagopalan
IPC: C10J3/46 , C10J3/82 , C10J3/48 , B01J8/26 , C07C29/151 , C07C273/10 , C01C1/04
CPC classification number: C10J3/466 , B01J8/26 , B01J2208/00752 , B01J2208/00982 , C01C1/0405 , C07C29/1518 , C07C273/10 , C10J3/48 , C10J3/485 , C10J3/82 , C10J3/84 , C10J2300/0903 , C10J2300/0943 , C10J2300/0959 , C10J2300/1665 , C10J2300/1668 , C07C31/04
Abstract: Systems and methods are provided for producing high quality synthesis gas from a fluidized coking system that includes an integrated gasifier. Additionally or alternately, systems and methods are provided for integrating a fluidized coking process, a coke gasification process, and processes for production of compounds from the synthesis gas generated during the coke gasification. The integrated process can also allow for reduced or minimized production of inorganic nitrogen compounds by using oxygen from an air separation unit as the oxygen source for gasification. Although the amount of nitrogen introduced as a diluent into the gasification will be reduced, minimized, or eliminated, the integrated process can also allow for gasification of coke while reducing, minimizing, or eliminating production of slag or other glass-like substances in the gasifier. Examples of compounds that can be produced from the synthesis gas include, but are not limited to, methanol, ammonia, and urea.
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公开(公告)号:US20170183580A1
公开(公告)日:2017-06-29
申请号:US15390896
申请日:2016-12-27
Applicant: ExxonMobil Research and Engineering Company
Inventor: Mohsen N. Harandi , Doron Levin , Himanshu Gupta , James R. Lattner , Glenn C. Wood , Keith K. Aldous , Timothy L. Hilbert , Michael B. Carroll , Ajit B. Dandekar , Sara L. Yohe , Stephen H. Brown , Tracie L. Owens , April D. Ross , Eric B. Senzer , Steven Pyl
IPC: C10G67/04 , C10M101/02
Abstract: Methods are provided for producing lubricant base stocks from deasphalted oils formed by sequential deasphalting. The deasphalted oil can be exposed a first deasphalting process using a first solvent that can provide a lower severity of deasphalting and a second deasphalting process using a second solvent that can provide a higher severity of deasphalting. This can result in formation of at least a deasphalted oil and a resin fraction. The resin fraction can represent a fraction that traditionally would have been included as part of a deasphalter rock fraction.
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公开(公告)号:US11014810B1
公开(公告)日:2021-05-25
申请号:US16775610
申请日:2020-01-29
Applicant: ExxonMobil Research and Engineering Company
Inventor: Martin De Wit , Mohsen N. Harandi
IPC: C01B3/12 , C07C29/151 , C01B3/02 , C01B3/50 , C01C1/04
Abstract: Systems and methods are provided for integrating a fluidized coking operation, a reverse osmosis operation, a coke gasification operation and/or processes for production of compounds from the synthesis gas generated during the coke gasification. Conventional FLEXICOKING™ processes may produce carbon dioxide emissions and low Joule Flexigas, as well as waste water containing metals and poor quality coke containing metals, which may be expensive to process, or may require sending to other facilities for further processing. The systems and methods described herein address these issues in an advantageous and economical manner, with improved carbon capture, waste upgrade and chemicals production, while providing high value ash (e.g., for recovery of metals such as vanadium, nickel, sodium, iron, and mixtures thereof) and upgraded coke streams.
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公开(公告)号:US20200063039A1
公开(公告)日:2020-02-27
申请号:US16529836
申请日:2019-08-02
Applicant: ExxonMobil Research and Engineering Company
Inventor: Mohsen N. Harandi , Michael F. Raterman , David B. Spry
Abstract: A method for reducing CO2 emissions from steam cracking operations can include: introducing an oxygen-rich stream comprising oxygen and from 0 wt % to 15 wt % nitrogen to a vessel; introducing hydrocarbon combustion fuel to the vessel; combusting oxygen and hydrocarbon combustion fuel in the vessel to (1) produce a flue gas comprising carbon dioxide and water and (2) heat a cracking coil passing through the vessel; and performing a steam cracking reaction in the cracking coil passing through the vessel.
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公开(公告)号:US10550341B2
公开(公告)日:2020-02-04
申请号:US15390896
申请日:2016-12-27
Applicant: ExxonMobil Research and Engineering Company
Inventor: Mohsen N. Harandi , Doron Levin , Himanshu Gupta , James R. Lattner , Glenn C. Wood , Keith K. Aldous , Timothy L. Hilbert , Michael B. Carroll , Ajit B. Dandekar , Sara L. Yohe , Stephen H. Brown , Tracie L. Owens , April D. Ross , Eric B. Senzer , Steven Pyl
IPC: C10G65/12 , C10M101/02 , C10G67/04 , C10G55/02 , C10G65/04 , C10K1/00 , C10K3/04 , C01B3/48 , C10J3/82
Abstract: Methods are provided for producing lubricant base stocks from deasphalted oils formed by sequential deasphalting. The deasphalted oil can be exposed a first deasphalting process using a first solvent that can provide a lower severity of deasphalting and a second deasphalting process using a second solvent that can provide a higher severity of deasphalting. This can result in formation of at least a deasphalted oil and a resin fraction. The resin fraction can represent a fraction that traditionally would have been included as part of a deasphalter rock fraction.
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公开(公告)号:US10400177B2
公开(公告)日:2019-09-03
申请号:US15812396
申请日:2017-11-14
Applicant: ExxonMobil Research and Engineering Company
Inventor: Tien V. Le , Brenda A. Raich , Bing Du , Mohsen N. Harandi , Suriyanarayanan Rajagopalan
Abstract: Systems and methods are provided for integrating a fluidized coking process, optionally a coke gasification process, and processes for production of additional liquid products from the coking and/or gasification process. In some aspects, the integrated processes can allow for conversion of olefins generated during a fluidized coking process to form additional liquid products. Additionally or alternately, in some aspects the integrated processes can allow for separation of syngas from the flue gas/fuel gas generated by a gasifier integrated with a fluidized coking process. This syngas can then be used to form methanol, which can then be converted in a methanol conversion process to form heavier products. In such aspects, olefins generated during the fluidized coking process can be added to the methanol conversion process to improve the yield. Additionally, in various aspects, the off-gas from the integrated conversion process can be used as an additional paraffin feed that can be recycled to one of the heat integration conduits in the fluidized coker for additional generation of olefins. This can provide a further increase in liquid yields using a carbon source (C4− paraffins) that is conventionally viewed as a low value product from coking.
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