CMAS resistant thermal barrier coatings

    公开(公告)号:US10179945B2

    公开(公告)日:2019-01-15

    申请号:US14107225

    申请日:2013-12-16

    Abstract: The present application provides Calcia-Magnesia-Alumina-Silica (CMAS) (or molten silicate) resistant thermal barrier coatings (TBC). The coatings include elongate growth domains of non-equiaxed, randomly arranged overlapping grains or splats. The elongate growth domains include overlapping individual, randomly distributed splats of tough and soft phases. In some embodiments, the elongate growth domains are formed via air plasma spray. In some embodiments, the tough phases are at least partially stabilized zirconia and/or hafnia compositions, and the soft phases are CMAS (or molten silicate) reactive or resistant compositions. Within each elongate growth domain, the mixture of the tough and soft phases act together to limit penetration of CMAS and also provide sufficient domain toughness to minimize cracking forces produced during crystallization of infiltrated CMAS. The soft phases may react with the CMAS and increase its melting point, increase its viscosity, and reduce the destabilization of the tough phases.

    ARTICLES FOR HIGH TEMPERATURE SERVICE AND METHOD FOR MAKING
    5.
    发明申请
    ARTICLES FOR HIGH TEMPERATURE SERVICE AND METHOD FOR MAKING 有权
    高温服务和制造方法的文章

    公开(公告)号:US20160177746A1

    公开(公告)日:2016-06-23

    申请号:US14576760

    申请日:2014-12-19

    Abstract: Articles, such as components for high temperature turbomachinery components, include one or more coatings bearing certain perovskite compositions resistant to incursion by liquid calcium-magnesium-aluminum-silicon-oxide (CMAS) materials during service. The CMAS-reactive material includes a perovskite-structured oxide, which comprises a) a rare earth element, b) niobium, tantalum or a combination of tantalum and niobium, and c) oxygen. The CMAS-reactive material is present in an effective amount to react with a CMAS composition at an operating temperature, thereby forming a reaction product having one or both of melting temperature and viscosity greater than that of the CMAS composition.

    Abstract translation: 诸如用于高温涡轮机组件的部件的制品包括一种或多种在使用期间承载某种钙钛矿组合物以耐受液态钙镁 - 铝 - 氧化硅(CMAS)材料侵入的涂层。 CMAS反应性材料包括钙钛矿结构氧化物,其包括a)稀土元素,b)铌,钽或钽和铌的组合,以及c)氧。 CMAS反应性材料以有效量存在,以在操作温度下与CMAS组合物反应,从而形成具有比CMAS组合物的熔融温度和粘度更大的熔融温度和粘度中的一个或两个的反应产物。

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