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公开(公告)号:US20190262813A1
公开(公告)日:2019-08-29
申请号:US16403172
申请日:2019-05-03
Applicant: James J. Spivey , Kunlun Ding , Swarom Kanitkar
Inventor: James J. Spivey , Kunlun Ding , Swarom Kanitkar
Abstract: Catalysts are disclosed having metal oxide support structures and acidic reaction sites. Those reaction sites may have multiple bromine atoms bound to an aluminum atom with that aluminum-bromine group having an associated hydrogen ion. Additional structural features of the reaction sites are dictated by the aluminum oxide based catalysts and a silicon oxide based catalyst selected.
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公开(公告)号:US10328422B2
公开(公告)日:2019-06-25
申请号:US15867920
申请日:2018-01-11
Applicant: James J. Spivey , Kunlun Ding , Swarom Kanitkar
Inventor: James J. Spivey , Kunlun Ding , Swarom Kanitkar
Abstract: Catalysts are disclosed having metal oxide support structures and acidic reaction sites. The reaction sites may be according to the general formula MxOyAlBrzX]−H+ where x is one or two; y is one or two; z is one or two; X is selected from Br or Cl; M is Al or Si and one or more of M, O and Al has a molecular bond with the metal oxide support structure.
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公开(公告)号:US11951464B2
公开(公告)日:2024-04-09
申请号:US17270662
申请日:2019-08-21
Applicant: Kunlun Ding
Inventor: Kunlun Ding
IPC: B01J35/00 , B01J21/08 , B01J23/44 , B01J23/46 , B01J23/52 , B01J23/89 , B01J35/02 , B01J37/00 , B01J37/04 , B01J37/06 , B01J37/08 , B01J37/18 , B01J37/30
CPC classification number: B01J35/0006 , B01J21/08 , B01J23/44 , B01J23/462 , B01J23/468 , B01J23/52 , B01J23/8906 , B01J23/8913 , B01J23/892 , B01J23/8926 , B01J35/023 , B01J37/0063 , B01J37/009 , B01J37/04 , B01J37/06 , B01J37/082 , B01J37/18 , B01J37/30
Abstract: The present invention relates in part to a method of fabricating multimetallic nanoparticles, the method comprising the steps of providing a substrate; activating the substrate surface; adsorbing a cationic transition metal complex onto the substrate surface to form a substrate-supported cationic transition metal complex; adsorbing an anionic transition metal complex onto the substrate-supported cationic transition metal complex to form a substrate-supported multimetallic complex salt; and reducing the substrate-supported multimetallic complex salt to provide a plurality of multimetallic nanoparticles. The invention also relates in part to a composition of multimetallic nanoparticles comprising at least two metals Ma and Mb; wherein the ratio of Ma to Mb is between about 2:1 and about 1:2.
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公开(公告)号:US20180304241A1
公开(公告)日:2018-10-25
申请号:US15867920
申请日:2018-01-11
Applicant: James J. Spivey , Kunlun Ding , Swarom Kanitkar
Inventor: James J. Spivey , Kunlun Ding , Swarom Kanitkar
CPC classification number: B01J29/70 , B01J27/06 , B01J29/041 , B01J29/40 , B01J37/0209 , C07C2/76 , C07C5/2705 , C07C5/2708 , C07C2521/04 , C07C2521/08 , C07C2527/08 , C07C2527/125 , C07C2527/126 , C07C2529/70 , C07C9/12 , C07C11/04 , C07C11/06 , C07C11/08 , C07C9/10 , C07C11/10
Abstract: Catalysts are disclosed having metal oxide support structures and acidic reaction sites. The reaction sites may be according to the general formula MxOyAlBrzX]−H+ where x is one or two; y is one or two; z is one or two; X is selected from Br or Cl; M is Al or Si and one or more of M, O and Al has a molecular bond with the metal oxide support structure.
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公开(公告)号:US11376573B2
公开(公告)日:2022-07-05
申请号:US16791554
申请日:2020-02-14
Applicant: James J. Spivey , Kunlun Ding , Swarom Kanitkar
Inventor: James J. Spivey , Kunlun Ding , Swarom Kanitkar
Abstract: Methods of preparing an acidic catalyst are disclosed that include heating a metal halide to produce a vapor phase metal halide, contacting an initial support material with the vapor phase metal halide in a reaction vessel causing a first chemical reaction and producing an intermediate acidic catalyst, contacting the intermediate acidic catalyst with HBr causing a second chemical reaction and producing an acidic catalyst product which is both more acidic than the intermediate acidic catalyst and more acidic than the initial support material.
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公开(公告)号:US20210252494A1
公开(公告)日:2021-08-19
申请号:US17270662
申请日:2019-08-21
Applicant: Kunlun Ding
Inventor: Kunlun Ding
IPC: B01J35/00 , B01J21/08 , B01J23/89 , B01J23/52 , B01J23/46 , B01J37/04 , B01J37/06 , B01J37/08 , B01J37/30 , B01J37/00 , B01J37/18 , B01J35/02 , B01J23/44
Abstract: The present invention relates in part to a method of fabricating multimetallic nanoparticles, the method comprising the steps of providing a substrate; activating the substrate surface; adsorbing a cationic transition metal complex onto the substrate surface to form a substrate-supported cationic transition metal complex; adsorbing an anionic transition metal complex onto the substrate-supported cationic transition metal complex to form a substrate-supported multimetallic complex salt; and reducing the substrate-supported multimetallic complex salt to provide a plurality of multimetallic nanoparticles. The invention also relates in part to a composition of multimetallic nanoparticles comprising at least two metals Ma and Mb; wherein the ratio of Ma to Mb is between about 2:1 and about 1:2.
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公开(公告)号:US10596559B2
公开(公告)日:2020-03-24
申请号:US16403172
申请日:2019-05-03
Applicant: James J. Spivey , Kunlun Ding , Swarom Kanitkar
Inventor: James J. Spivey , Kunlun Ding , Swarom Kanitkar
Abstract: Catalysts are disclosed having metal oxide support structures and acidic reaction sites. Those reaction sites may have multiple bromine atoms bound to an aluminum atom with that aluminum-bromine group having an associated hydrogen ion. Additional structural features of the reaction sites are dictated by the aluminum oxide based catalysts and a silicon oxide based catalyst selected.
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