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公开(公告)号：US08778826B2
公开(公告)日：2014-07-15
申请号：US12651032
申请日：2009-12-31
Applicant: Kelly Gonzalez , Clark C. Williams , Linfeng Chen
Inventor： Kelly Gonzalez , Clark C. Williams , Linfeng Chen
IPC: C08F110/06 , C08F4/16
CPC classification number: C08F10/06 , C07C37/02 , C07C37/14 , C07C37/16 , C07C37/50 , C07C37/56 , C07C37/60 , C07C67/14 , C08F110/06 , C08F210/06 , C07C69/78 , C08F4/651 , C08F210/16 , C08F2500/12 , C07C39/08 , C08F4/6494 , C08F4/6465 , C08F2500/18 , C08F4/6545
Abstract: Disclosed herein are processes for preparing procatalyst compositions and polymers, i.e., propylene-based polymers, produced therefrom. The present procatalyst compositions improve catalyst selectivity and also increase the bulk density of the formant polymer.
Abstract translation: 本文公开了制备原催化剂组合物和聚合物的方法，即由其制备的基于丙烯的聚合物。 本发明的前催化剂组合物改善催化剂选择性并且还增加共振峰聚合物的体积密度。
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公开(公告)号：US08604235B2
公开(公告)日：2013-12-10
申请号：US12651268
申请日：2009-12-31
Applicant: Linfeng Chen , Tak W. Leung , Tao Tao , Kuanqiang Gao , James X. Shu
Inventor： Linfeng Chen , Tak W. Leung , Tao Tao , Xiaodong Huang , Kuanqiang Gao
IPC: C07C69/76
CPC classification number: C07C69/78 , C07C69/753 , C07C69/76 , C07C69/92
Abstract: The present disclosure provides processes for the production of substituted phenylene aromatic diesters and the resultant compositions. The processes include reacting an aromatic diol with an aromatic carboxylic acid or a derivative thereof. The aromatic diol and/or the aromatic carboxylic acid (or derivative thereof) is/are substituted. The reaction forms a substituted phenylene aromatic diester with the structure (II): wherein R1-R14 are the same or different. At least one of R1-R14 is selected from a substituted hydrocarbyl group having 1 to 20 carbon atoms, an unsubstituted hydrocarbyl group having 1 to 20 carbon atoms, an alkoxy group having 1 to 20 carbon atoms, a heteroatom, and combinations thereof.
Abstract translation: 本公开提供了制备取代的亚苯基芳族二酯和所得组合物的方法。 该方法包括使芳族二醇与芳族羧酸或其衍生物反应。 芳族二醇和/或芳族羧酸（或其衍生物）被取代。 该反应形成具有结构（II）的取代的亚苯基芳族二酯：其中R1-R14相同或不同。 R1-R14中的至少一个选自碳原子数1〜20的取代烃基，碳原子数1〜20的未取代烃基，碳原子数1〜20的烷氧基，杂原子及其组合。
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3.发明授权Catalyst composition with halo-malonate internal electron donor and polymer from same 有权具有卤代丙二酸酯内电子给体的催化剂组合物及其相同的聚合物公开(公告)号：US08383540B2
公开(公告)日：2013-02-26
申请号：US12974402
申请日：2010-12-21
Applicant: Linfeng Chen , Tak W. Leung , Tao Tao
Inventor： Linfeng Chen , Tak W. Leung , Tao Tao
IPC: B01J31/38 , C08F210/06 , C08F110/06
CPC classification number: C08F4/6494 , C08F10/00 , C08F110/06 , C08F4/651 , C08F2500/12 , C08F2500/04
Abstract: Disclosed herein are procatalyst compositions, catalyst compositions and polymers, i.e., propylene-based polymers, produced therefrom. The present procatalyst compositions contain a halo-malonate and a 2-fluoro-malonate in particular. The present catalyst compositions improve catalyst selectivity, improve catalyst activity, and also improve hydrogen response during polymerization. Propylene-based polymer produced from the present catalyst composition has a melt flow rate greater than 50 g/10 min.
Abstract translation: 本文公开的是前催化剂组合物，催化剂组合物和聚合物，即由其制备的基于丙烯的聚合物。 本发明的前催化剂组合物特别包含卤代丙二酸酯和2-氟 - 丙二酸酯。 本催化剂组合物改善催化剂选择性，改善催化剂活性，并且还改善聚合期间的氢响应。 由本催化剂组合物制备的基于丙烯的聚合物的熔体流动速率大于50g / 10min。
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4.发明申请Procatalyst Composition with Substituted Amide Ester Internal Electron Donor 有权具有取代的酰胺酯内部电子给体的主催化剂组合物公开(公告)号：US20120322962A1
公开(公告)日：2012-12-20
申请号：US13580409
申请日：2011-02-24
Applicant: Linfeng Chen , Tak W. Leung , Tao Tao , Kunqiang Gao , James X. Shu , Xiaodong Huang
Inventor： Linfeng Chen , Tak W. Leung , Tao Tao , Kunqiang Gao , James X. Shu , Xiaodong Huang
CPC classification number: C08F110/06 , C08F10/06 , C08F4/651 , C08F2500/12 , C08F2500/18 , C08F2500/04 , C08F4/654
Abstract: Disclosed are procatalyst compositions having an internal electron donor which includes a substituted amide ester and optionally an electron donor component. Ziegler-Natta catalyst compositions containing the present procatalyst compositions exhibit improved catalyst activity and/or improved catalyst selectivity and produce propylene-based olefins with broad molecular weight distribution.
Abstract translation: 公开了具有内电子给体的前催化剂组合物，其包括取代的酰胺酯和任选的电子给体组分。 包含本发明的前催化剂组合物的齐格勒 - 纳塔催化剂组合物表现出改进的催化剂活性和/或改进的催化剂选择性并产生具有宽分子量分布的丙烯基烯烃。
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5.发明申请Procatalyst Composition with Alkoxyalkyl 2-Propenoate Internal Electron Donor and Polymer from Same 失效主催化剂组合物与2-丙烯酸烷氧基烷基酯内部电子供体及其相同的聚合物公开(公告)号：US20120157643A1
公开(公告)日：2012-06-21
申请号：US12974667
申请日：2010-12-21
Applicant: Linfeng Chen , Tak W. Leung , Tao Tao
Inventor： Linfeng Chen , Tak W. Leung , Tao Tao
CPC classification number: C08F10/00 , C08F110/06 , Y02P20/52 , C08F4/651 , C08F4/6565 , C08F2500/12 , C08F2500/04
Abstract: Disclosed herein are catalyst compositions and polymers, i.e., propylene-based polymers, produced therefrom. The present catalyst compositions contain an internal electron donor of an alkoxyalkyl 2-propenoate and optionally a mixed external electron donor. The present catalyst compositions improve catalyst selectivity and polymer stiffness. Polypropylene homopolymer produced from the present catalyst composition has a xylene solubles content less than 4 wt % and a TMF greater than 172.0° C.
Abstract translation: 本文公开了催化剂组合物和聚合物，即由其制备的基于丙烯的聚合物。 本催化剂组合物含有2-丙烯酸烷氧基烷基酯和任选的混合的外电子给体的内电子给体。 本催化剂组合物改善催化剂选择性和聚合物刚度。 由本催化剂组合物制备的聚丙烯均聚物的二甲苯可溶物含量小于4wt％，TMF大于172.0℃。
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Patent Agency Ranking
公开(公告)号：US20110152424A1
公开(公告)日：2011-06-23
申请号：US12970617
申请日：2010-12-16
Applicant: Ping Cai , Linfeng Chen , Jan W. Van Egmond , Michael W. Tilston
Inventor： Ping Cai , Linfeng Chen , Jan W. Van Egmond , Michael W. Tilston
IPC: C08K5/541
CPC classification number: C08F10/06 , C08F4/649 , C08F4/00 , C08F2500/24 , C08F2500/18
Abstract: The present invention relates to an improvement for gas phase olefin polymerization process under two or more different flow regimes. The process involves adding a mixed electron donor system to a reactor having two or more different flow regimes, wherein the mixed electron donor system comprises at least one selectivity control agent and at least one activity limiting agent. The invention is particularly well suited for reactor systems which include a regime characterized by having a low-velocity or high-solid holdup, which have been reported to have operational problems such as particle agglomeration and formation of polymer “chunks”.
Abstract translation: 本发明涉及在两种或多种不同流动状态下气相烯烃聚合方法的改进。 该方法包括向具有两个或多个不同流动状态的反应器中加入混合电子给体系，其中混合电子给体系包含至少一种选择性控制剂和至少一种活性限制剂。 本发明特别适用于包括具有低速或高固体滞留的状态的反应器系统，其被报告具有诸如颗粒聚集和形成聚合物“块”的操作问题。
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公开(公告)号：US20110124491A1
公开(公告)日：2011-05-26
申请号：US12674485
申请日：2008-08-20
Applicant: Linfeng Chen , Richard E. Campbell, JR.
Inventor： Linfeng Chen , Richard E. Campbell, JR.
CPC classification number: C08F10/06 , C08F110/02 , C08F110/06 , C08F4/6495 , C08F4/6494 , C08F4/651 , C08F2/40
Abstract: A catalyst composition for the polymerization of propylene is provided. The catalyst composition includes one or N more Ziegler-Natta procatalyst compositions having one or more transition metal compounds and an internal electron donor, one or more aluminum containing cocatalysts, and a selectivity control agent (SCA), The SCA is a mixture of an activity limiting agent (ALA) and selectivity determining agent (SDA) such as a non-silane composition. The present catalyst composition is silane-tree, has high catalyst activity and high stereoselectivity, and is self-extinguishing.
Abstract translation: 提供了用于丙烯聚合的催化剂组合物。 催化剂组合物包括一种或多种齐格勒 - 纳塔原催化剂组合物，其具有一种或多种过渡金属化合物和内部电子给体，一种或多种含铝助催化剂和选择性控制剂（SCA）。该SCA是一种活性 限制剂（ALA）和选择性测定剂（SDA），如非硅烷组合物。 本催化剂组合物为硅烷树脂，催化剂活性高，立体选择性高，为自熄性。
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8.发明申请公开(公告)号：US20100273641A1
公开(公告)日：2010-10-28
申请号：US12809663
申请日：2008-12-12
Applicant: Linfeng Chen , Richard E. Campbell, JR.
Inventor： Linfeng Chen , Richard E. Campbell, JR.
CPC classification number: C08F110/06 , C08F4/651 , C08F4/6465
Abstract: A catalyst composition for the polymerization of propylene is provided. The catalyst composition includes one or more Ziegler-Natta procatalyst compositions having one or more transition metal compounds and an internal electron donor, one or more aluminum containing cocatalysts, and an external electron donor. The internal electron donor is a bidentate compound excluding plithalates. Suitable bidentale compounds include diethers, succinates, dialkoxybenzenes and diol esters. The external electron donor is a mixture of an activity limiting agent and selectivity determining agent. The present catalyst composition has high catalyst activity and high stereoselectivity, and is self-extinguishing.
Abstract translation: 提供了用于丙烯聚合的催化剂组合物。 催化剂组合物包括一种或多种具有一种或多种过渡金属化合物和内部电子给体，一种或多种含铝助催化剂和外部电子给体的齐格勒 - 纳塔前催化剂组合物。 内部电子给体是一种不包括五硅酸盐的二齿化合物。 合适的二齿化合物包括二醚，琥珀酸酯，二烷氧基苯和二醇酯。 外部电子给体是活性限制剂和选择性确定剂的混合物。 本催化剂组合物具有高催化剂活性和高立体选择性，并且是自熄性的。
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公开(公告)号：US20090118118A1
公开(公告)日：2009-05-07
申请号：US12352253
申请日：2009-01-12
Applicant: Linfeng Chen , Richard E. Campbell, JR.
Inventor： Linfeng Chen , Richard E. Campbell, JR.
CPC classification number: C08F10/00 , B01J31/0201 , B01J31/0272 , B01J31/04 , B01J31/143 , C08F10/06 , C08F110/06 , C08F4/6496 , C08F4/6495 , C08F4/6494 , C08F4/6465 , C08F2500/12 , C08F2500/18
Abstract: A catalyst composition for the polymerization of propylene comprising one or more Ziegler-Natta procatalyst compositions comprising one or more transition metal compounds and one or more esters of aromatic dicarboxylic acid internal electron donors; one or more aluminum containing cocatalysts; a selectivity control agent (SCA) comprising at least one silicon containing compound containing at least one C1-10 alkoxy group bonded to a silicon atom, and one or more activity limiting agent (ALA) compounds comprising one or more aliphatic or cycloaliphatic carboxylic acids; alkyl-, cycloalkyl- or alkyl(poly)(oxyalkyl)-(poly)ester derivatives thereof; or inertly substituted derivatives of the foregoing.
Abstract translation: 一种用于丙烯聚合的催化剂组合物，其包含一种或多种齐格勒 - 纳塔前催化剂组合物，其包含一种或多种过渡金属化合物和一种或多种芳族二羧酸内电子给体的酯; 一种或多种含铝助催化剂; 包含至少一种含有至少一个与硅原子键合的C 1-10烷氧基的含硅化合物的选择性控制剂（SCA）和一种或多种包含一种或多种脂族或脂环族羧酸的活性限制剂（ALA）化合物; 烷基 - ，环烷基 - 或烷基（聚）（烷氧基） - （聚）酯衍生物; 或惰性取代的衍生物。
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10.发明申请Catalyst composition and polymerization process using mixtures of selectivity control agents 有权使用选择性控制剂混合物的催化剂组合物和聚合方法公开(公告)号：US20060167194A1
公开(公告)日：2006-07-27
申请号：US10514608
申请日：2003-05-20
Applicant: Linfeng Chen , Thomas Nemzek
Inventor： Linfeng Chen , Thomas Nemzek
CPC classification number: C08F10/06 , C08F10/00 , C08F110/06 , C08F210/06 , Y10S526/901 , C08F4/6465 , C08F4/6492 , C08F4/6495 , C08F4/6494 , C08F2/001 , C08F2500/12 , C08F2500/17 , C08F210/16
Abstract: A catalyst composition for the polymerization of olefins and process for the use thereof, comprising the combination of one or more Ziegler-Natta catalysts, comprising one or more transition metal compounds, one or more aluminum containing cocatalyts, and a mixture of different selectivity control agents, including in said mixture of selectivity control agents at least one normally dominating selectivity control agent and one normally dominated selectivity control agent, characterized in that the individual selectivity control agents are present in the mixture in relative amounts to each other and relative to the one or more transition metal compounds, such that the effect of the selectivity control agents on the resulting polymer properties is not determined solely or substantially solely by the normally dominating selectivity control agent.
Abstract translation: 用于烯烃聚合的催化剂组合物及其使用方法，包括一种或多种齐格勒 - 纳塔催化剂的组合，其包含一种或多种过渡金属化合物，一种或多种含铝催化剂和不同选择性控制剂的混合物 包括在选择性控制剂的所述混合物中至少一种通常占主导地位的选择性控制剂和一种通常主导的选择性控制剂，其特征在于，各个选择性控制剂以相对于彼此的相对量相对于混合物存在， 更多的过渡金属化合物，使得选择性控制剂对所得聚合物性质的影响不仅仅是或者基本上仅由通常主导的选择性控制剂来确定。
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