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公开(公告)号:US20210180200A1
公开(公告)日:2021-06-17
申请号:US16713871
申请日:2019-12-13
Applicant: MacDermid Enthone Inc.
Inventor: Shaopeng Sun , Kyle Whitten , Stephan Braye , Elie Najjar
Abstract: An electroplated cobalt deposit and a method of electrodepositing cobalt on a surface to produce a level deposit across the surface of the substrate. The cobalt electrolyte contains (1) a source of cobalt ions; (2) boric acid; (3) a pH adjuster; and (4) an organic additive, which contains a suppressor. The electroplated cobalt deposit exhibits a level surface such that the thickness difference across substantially the entire surface of the substrate of less than about 200 nm.
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公开(公告)号:US10995417B2
公开(公告)日:2021-05-04
申请号:US15739314
申请日:2016-06-30
Applicant: MacDermid Enthone Inc.
Inventor: John Commander , Vincent Paneccasio, Jr. , Eric Rouya , Kyle Whitten , Shaopeng Sun , Jianwen Han
Abstract: Processes and compositions for electroplating a cobalt deposit onto a semiconductor base structure comprising submicron-sized electrical interconnect features. In the process, a metalizing substrate within the interconnect features is contacted with an electrodeposition composition comprising a source of cobalt ions, an accelerator comprising an organic sulfur compound, an acetylenic suppressor, a buffering agent and water. Electrical current is supplied to the electrolytic composition to deposit cobalt onto the base structure and fill the submicron-sized features with cobalt. The process is effective for superfilling the interconnect features.
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公开(公告)号:US20220136123A1
公开(公告)日:2022-05-05
申请号:US17524450
申请日:2021-11-11
Applicant: MacDermid Enthone Inc.
Inventor: Shaopeng Sun , Kyle Whitten , Stephan Braye , Elie Najjar
Abstract: An electroplated cobalt deposit and a method of electrodepositing cobalt on a surface to produce a level deposit across the surface of the substrate. The cobalt electrolyte contains (1) a source of cobalt ions; (2) boric acid; (3) a pH adjuster; and (4) an organic additive, which contains a suppressor. The electroplated cobalt deposit exhibits a level surface such that the thickness difference across substantially the entire surface of the substrate of less than about 200 nm.
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公开(公告)号:US20210310141A1
公开(公告)日:2021-10-07
申请号:US17347934
申请日:2021-06-15
Applicant: MacDermid Enthone Inc.
Inventor: Vincent Paneccasio, JR. , Kyle Whitten , Thomas B. Richardson , Ivan Li
Abstract: An aqueous electrolytic composition and a process for electrodeposition of copper on a dielectric or semiconductor base structure using the aqueous electrolytic compostion. The process includes (i) contacting a metalizing substrate comprising a seminal conductive layer on the base structure with an aqueous electrolytic deposition composition; and (ii) supplying electrical current to the electrolytic deposition composition to deposit copper on the substrate. The aqueous electrolytic composition comprises: (a) copper ions; (b) an acid; (c) a suppressor; and (d) a quaternized poly(epihalohydrin) comprising n repeating units corresponding to structure 1N and p repeating units corresponding to structure 1P:
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公开(公告)号:US20210222314A1
公开(公告)日:2021-07-22
申请号:US17220540
申请日:2021-04-01
Applicant: MacDermid Enthone Inc.
Inventor: John Commander , Vincent Paneccasio, JR. , Eric Rouya , Kyle Whitten , Shaopeng Sun , Jianwen Han
Abstract: Processes and compositions for electroplating a cobalt deposit onto a semiconductor base structure comprising sub-micron-sized electrical interconnect features. In the process, a metalizing substrate within the interconnect features is contacted with an electrodeposition composition comprising a source of cobalt ions, an accelerator comprising an organic sulfur compound, an acetylenic suppressor, a buffering agent and water. Electrical current is supplied to the electrolytic composition to deposit cobalt onto the base structure and fill the submicron-sized features with cobalt. The process is effective for superfilling the interconnect features.
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公开(公告)号:US10519557B2
公开(公告)日:2019-12-31
申请号:US15412809
申请日:2017-01-23
Applicant: MacDermid Enthone Inc.
Inventor: Vincent Paneccasio, Jr. , Kyle Whitten , Thomas B. Richardson , Ivan Li
IPC: C25D3/38 , C08G65/333 , H05K3/18 , H05K3/42 , C25D7/12 , C08G65/24 , C08L71/03 , H01L21/768 , H01L21/48 , H01L21/288
Abstract: An aqueous electrolytic composition and a process for electrodeposition of copper on a dielectric or semiconductor base structure using the aqueous electrolytic composition. The process includes (i) contacting a metalizing substrate comprising a seminal conductive layer on the base structure with an aqueous electrolytic deposition composition; and (ii) supplying electrical current to the electrolytic deposition composition to deposit copper on the substrate. The aqueous electrolytic composition comprises: (a) copper ions; (b) an acid; (c) a suppressor; and (d) a quaternized poly(epihalohydrin) comprising n repeating units corresponding to structure 1N and p repeating units corresponding to structure 1P:
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公开(公告)号:US20190010624A1
公开(公告)日:2019-01-10
申请号:US15641756
申请日:2017-07-05
Applicant: MacDermid Enthone Inc.
Inventor: John Commander , Kyle Whitten , Vincent Paneccasio, JR. , Shaopeng Sun , Eric Yakobson
IPC: C25D3/16 , H01L21/768 , C25D5/02 , C25D7/12
Abstract: Compositions and methods of using such compositions for electroplating cobalt onto semiconductor base structures comprising submicron-sized electrical interconnect features are provided herein. The interconnect features are metallized by contacting the semiconductor base structure with an electrolytic composition comprising a source of cobalt ions, a suppressor, a buffer, and one or more of a depolarizing compound and a uniformity enhancer. Electrical current is supplied to the electrolytic composition to deposit cobalt onto the base structure and fill the submicron-sized features with cobalt. The method presented herein is useful for superfilling interconnect features.
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公开(公告)号:US11807951B2
公开(公告)日:2023-11-07
申请号:US17524450
申请日:2021-11-11
Applicant: MacDermid Enthone Inc.
Inventor: Shaopeng Sun , Kyle Whitten , Stephan Braye , Elie Najjar
CPC classification number: C25D3/16 , B32B3/26 , B32B15/04 , B32B15/043 , C25D5/02 , C25D5/18 , C25D5/611 , C25D7/00 , C25D7/123 , Y10T428/1291 , Y10T428/12931 , Y10T428/12937 , Y10T428/12993 , Y10T428/2495 , Y10T428/24942 , Y10T428/265
Abstract: An electroplated cobalt deposit and a method of electrodepositing cobalt on a surface to produce a level deposit across the surface of the substrate. The cobalt electrolyte contains (1) a source of cobalt ions; (2) boric acid; (3) a pH adjuster; and (4) an organic additive, which contains a suppressor. The electroplated cobalt deposit exhibits a level surface such that the thickness difference across substantially the entire surface of the substrate of less than about 200 nm.
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公开(公告)号:US20210388519A1
公开(公告)日:2021-12-16
申请号:US17400633
申请日:2021-08-12
Applicant: MacDermid Enthone Inc.
Inventor: Thomas Richardson , Kyle Whitten , Vincent Paneccasio, JR. , John Commander , Richard Hurtubise
IPC: C25D3/38 , C08G65/24 , C08G65/333 , C08G73/06 , H01L23/00
Abstract: An electrodeposition composition comprising: (a) a source of copper ions; (b) an acid; (c) a suppressor; and (d) a leveler, wherein the leveler comprises a quaternized dipyridyl compound prepared by reacting a dipyridyl compound with a difunctional alkylating agent or a quaternized poly(epihalohydrin). The electrodeposition composition can be used in a process for forming a copper feature over a semiconductor substrate in wafer level packaging to electrodeposit a copper bump or pillar on an underbump structure of a semiconductor assembly.
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公开(公告)号:US11168406B2
公开(公告)日:2021-11-09
申请号:US16672720
申请日:2019-11-04
Applicant: MacDermid Enthone Inc.
Inventor: Vincent Paneccasio , Kyle Whitten , Thomas B. Richardson , Ivan Li
IPC: C25D3/38 , C08G65/333 , H05K3/18 , H05K3/42 , C25D7/12 , C08G65/24 , C08L71/03 , H01L21/768 , H01L21/48 , H01L21/288
Abstract: An aqueous electrolytic composition and a process for electrodeposition of copper on a dielectric or semiconductor base structure using the aqueous electrolytic composition. The process includes (i) contacting a metalizing substrate comprising a seminal conductive layer on the base structure with an aqueous electrolytic deposition composition; and (ii) supplying electrical current to the electrolytic deposition composition to deposit copper on the substrate. The aqueous electrolytic composition comprises: (a) copper ions; (b) an acid; (c) a suppressor; and (d) a quaternized poly(epihalohydrin) comprising n repeating units corresponding to structure 1N and p repeating units corresponding to structure 1P:
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