Aliphatic-aromatic biodegradable polyester

    公开(公告)号:US11345779B2

    公开(公告)日:2022-05-31

    申请号:US16682628

    申请日:2019-11-13

    Abstract: Disclosed are aliphatic-aromatic biodegradable polyesters obtained from aliphatic dicarboxylic acids comprising azelaic acid, sebacic acid, suberic acid, brassylic acid and their esters; polyfunctional aromatic acids of renewable origin and particularly 2,5-furan dicarboxylic acid, and diols, such as 1,2-ethanediol, 1,2-propanediol, 1,3-propanediol, 1,4-butanediol, 1,5-pentanediol, 1,6-haxanediol, 1,7-heptanediol, 1,8-octanediol, 1,9-nonanediol, 1,10-decanediol, 1,11-undecanediol, 1,12-dodecanediol, 1,13-tridecanediol, 1,4-cyclohexanedimethanol, propylene glycol, neopentyl glycol, 2-methyl-1,3-propanediol, dianhydrosorbitol, dianhydromannitol, dianhydroiditol, cyclohexanediol, cyclohexane-methanediol, aromatic diols such as phenols, and furan diol. Also disclosed are blends of the polyesters with other biodegradable polymers of either natural or synthetic origin. The polyesters have properties and viscosity values that make them suitable, after adjusting their molecular weight, for use in numerous practical applications such as films, injection molded products, extrusion coatings, fibers, foams, thermoformed products, extruded profiles and sheets, extrusion blow molding, injection blow molding, rotomolding, stretch blow molding.

    PROCESS FOR THE PRODUCTION OF 1,4-BUTANEDIOL FROM RENEWABLE SOURCES AND POLYESTERS OBTAINED THEREFROM

    公开(公告)号:US20220298090A1

    公开(公告)日:2022-09-22

    申请号:US17834151

    申请日:2022-06-07

    Abstract: The invention relates to a process for the production of 1,4-butanediol comprising the preparation of a fermentation broth comprising 1,4-butanediol from renewable sources and water, separation of a liquid fraction comprising said 1,4-butanediol and water from one or more solid fractions, said liquid fraction comprising 2-pyrrolidone in an amount higher than 80 ppm, one or more passages of the resulting liquid fraction through a bed comprising one or more cation-exchange resins thereby providing an output pH of said liquid fraction from 4 to 2, one or more passages of the resulting liquid fraction through a bed comprising one or more anion-exchange resins thereby providing an output pH of said liquid fraction from 8 to 11, and the distillation of the liquid fraction thereby provided so as to obtain a composition having a concentration of said 1,4-butanediol higher than 99.0% by weight and comprising 2-pyrrolidone in an amount lower than 6 ppm. The resulting composition should exhibit an APHA color value after ageing of less than 30.

    ALIPHATIC-AROMATIC BIODEGRADABLE POLYESTER
    8.
    发明申请
    ALIPHATIC-AROMATIC BIODEGRADABLE POLYESTER 审中-公开
    芳纶可生物降解聚酯

    公开(公告)号:US20160200862A1

    公开(公告)日:2016-07-14

    申请号:US14881640

    申请日:2015-10-13

    Abstract: Disclosed are aliphatic-aromatic biodegradable polyesters obtained from aliphatic dicarboxylic acids, polyfunctional aromatic acids of renewable origin and particularly 2,5-furan dicarboxylic acid, and diols. Also disclosed are blends of the polyesters with other biodegradable polymers of either natural or synthetic origin. The polyesters have properties and viscosity values that make them suitable, after adjusting their molecular weight, for use in numerous practical applications such as films, injection molded products, extrusion coatings, fibers, foams, thermoformed products, extruded profiles and sheets, extrusion blow molding, injection blow molding, rotomolding, stretch blow molding.

    Abstract translation: 公开了由脂族二羧酸,可再生来源的多官能芳族酸,特别是2,5-呋喃二羧酸和二醇获得的脂族 - 芳族可生物降解聚酯。 还公开了聚酯与天然或合成来源的其它可生物降解的聚合物的共混物。 聚酯的性质和粘度值在调整分子量后适用于许多实际应用,如薄膜,注射成型产品,挤出涂料,纤维,泡沫,热成型产品,挤出型材和片材,挤出吹塑 ,注塑吹塑,滚塑,拉伸吹塑成型。

    Process for the production of 1,4-butanediol from renewable sources and polyesters obtained therefrom

    公开(公告)号:US12195420B2

    公开(公告)日:2025-01-14

    申请号:US17834151

    申请日:2022-06-07

    Abstract: The invention relates to a process for the production of 1,4-butanediol comprising the preparation of a fermentation broth comprising 1,4-butanediol from renewable sources and water, separation of a liquid fraction comprising said 1,4-butanediol and water from one or more solid fractions, said liquid fraction comprising 2-pyrrolidone in an amount higher than 80 ppm, one or more passages of the resulting liquid fraction through a bed comprising one or more cation-exchange resins thereby providing an output pH of said liquid fraction from 4 to 2, one or more passages of the resulting liquid fraction through a bed comprising one or more anion-exchange resins thereby providing an output pH of said liquid fraction from 8 to 11, and the distillation of the liquid fraction thereby provided so as to obtain a composition having a concentration of said 1,4-butanediol higher than 99.0% by weight and comprising 2-pyrrolidone in an amount lower than 6 ppm. The resulting composition should exhibit an APHA color value after ageing of less than 30.

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