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公开(公告)号:US11739181B2
公开(公告)日:2023-08-29
申请号:US16094662
申请日:2017-04-20
Applicant: Novamont S.p.A.
Inventor: Catia Bastioli , Luigi Capuzzi , Tiziana Milizia , Angelos Rallis , Roberto Vallero
IPC: C08G63/181 , C08G63/16 , C08L97/02 , B29C45/00 , C08G63/199 , C08G63/52 , C08L67/02 , C08L99/00 , C08L101/00 , C08K3/013 , C08J5/04 , C08J5/18 , C08K7/02 , B29K67/00 , C08K5/00
CPC classification number: C08G63/181 , B29C45/0001 , C08G63/16 , C08G63/199 , C08G63/52 , C08J5/045 , C08J5/18 , C08K3/013 , C08K7/02 , C08L67/02 , C08L97/02 , C08L99/00 , C08L101/00 , B29K2067/00 , C08G2230/00 , C08J2367/02 , C08K5/0025 , C08L2201/06 , C08L2205/16
Abstract: This invention relates to a new polyester which is particularly suitable for use in the manufacture of mass-produced articles characterised by excellent mechanical properties, in particular high tensile strength and tensile modulus, associated with a high barrier property against oxygen and carbon dioxide.
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公开(公告)号:US11345779B2
公开(公告)日:2022-05-31
申请号:US16682628
申请日:2019-11-13
Applicant: Novamont S.p.A.
Inventor: Catia Bastioli , Giampietro Borsotti , Luigi Capuzzi , Roberto Vallero
IPC: C08G63/16 , C08G63/181 , C08G63/672 , C08L67/02 , C08L1/02 , C08L3/02 , C08L67/04 , C08L93/00 , C08J5/18
Abstract: Disclosed are aliphatic-aromatic biodegradable polyesters obtained from aliphatic dicarboxylic acids comprising azelaic acid, sebacic acid, suberic acid, brassylic acid and their esters; polyfunctional aromatic acids of renewable origin and particularly 2,5-furan dicarboxylic acid, and diols, such as 1,2-ethanediol, 1,2-propanediol, 1,3-propanediol, 1,4-butanediol, 1,5-pentanediol, 1,6-haxanediol, 1,7-heptanediol, 1,8-octanediol, 1,9-nonanediol, 1,10-decanediol, 1,11-undecanediol, 1,12-dodecanediol, 1,13-tridecanediol, 1,4-cyclohexanedimethanol, propylene glycol, neopentyl glycol, 2-methyl-1,3-propanediol, dianhydrosorbitol, dianhydromannitol, dianhydroiditol, cyclohexanediol, cyclohexane-methanediol, aromatic diols such as phenols, and furan diol. Also disclosed are blends of the polyesters with other biodegradable polymers of either natural or synthetic origin. The polyesters have properties and viscosity values that make them suitable, after adjusting their molecular weight, for use in numerous practical applications such as films, injection molded products, extrusion coatings, fibers, foams, thermoformed products, extruded profiles and sheets, extrusion blow molding, injection blow molding, rotomolding, stretch blow molding.
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公开(公告)号:US10526442B2
公开(公告)日:2020-01-07
申请号:US14881640
申请日:2015-10-13
Applicant: Novamont S.p.A.
Inventor: Catia Bastioli , Giampietro Borsotti , Luigi Capuzzi , Roberto Vallero
IPC: C08G63/16 , C08G63/181 , C08G63/672 , C08L67/02 , C08L67/04 , C08L93/00 , C08J5/18 , C08L1/02 , C08L3/02
Abstract: Disclosed are aliphatic-aromatic biodegradable polyesters obtained from aliphatic dicarboxylic acids, polyfunctional aromatic acids of renewable origin and particularly 2,5-furan dicarboxylic acid, and diols. Also disclosed are blends of the polyesters with other biodegradable polymers of either natural or synthetic origin. The polyesters have properties and viscosity values that make them suitable, after adjusting their molecular weight, for use in numerous practical applications such as films, injection molded products, extrusion coatings, fibers, foams, thermoformed products, extruded profiles and sheets, extrusion blow molding, injection blow molding, rotomolding, stretch blow molding.
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公开(公告)号:US20220298090A1
公开(公告)日:2022-09-22
申请号:US17834151
申请日:2022-06-07
Applicant: NOVAMONT S.P.A.
Inventor: Marco COTTI COMETTINI , Roberto Vallero , Catia Bastioli , Luigi Capuzzi
IPC: C07C29/76 , B01D3/00 , B01D3/14 , B01D15/36 , C07C29/80 , C07C31/20 , C08G18/42 , C08G63/181 , C08J5/18 , C08L67/02 , C12P7/18
Abstract: The invention relates to a process for the production of 1,4-butanediol comprising the preparation of a fermentation broth comprising 1,4-butanediol from renewable sources and water, separation of a liquid fraction comprising said 1,4-butanediol and water from one or more solid fractions, said liquid fraction comprising 2-pyrrolidone in an amount higher than 80 ppm, one or more passages of the resulting liquid fraction through a bed comprising one or more cation-exchange resins thereby providing an output pH of said liquid fraction from 4 to 2, one or more passages of the resulting liquid fraction through a bed comprising one or more anion-exchange resins thereby providing an output pH of said liquid fraction from 8 to 11, and the distillation of the liquid fraction thereby provided so as to obtain a composition having a concentration of said 1,4-butanediol higher than 99.0% by weight and comprising 2-pyrrolidone in an amount lower than 6 ppm. The resulting composition should exhibit an APHA color value after ageing of less than 30.
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公开(公告)号:US11021569B2
公开(公告)日:2021-06-01
申请号:US16094696
申请日:2017-04-20
Applicant: Novamont S.p.A.
Inventor: Catia Bastioli , Luigi Capuzzi , Tiziana Milizia , Angelos Rallis , Roberto Vallero
IPC: C08G63/181 , C08G63/16 , C08L97/02 , B29C45/00 , C08G63/199 , C08G63/52 , C08L67/02 , C08L99/00 , C08L101/00 , C08K3/013 , C08J5/04 , C08J5/18 , C08K7/02 , B29K67/00 , C08K5/00
Abstract: This invention relates to a biodegradable polyester which is particularly suitable for use in the manufacture of mass-produced articles characterised by excellent mechanical properties, in particular high tensile strength, elongation and tensile modulus, associated with a high barrier property against oxygen and carbon dioxide.
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公开(公告)号:US10294327B2
公开(公告)日:2019-05-21
申请号:US15516489
申请日:2015-10-02
Applicant: Novamont S.p.A.
Inventor: Federico Faiella , Tiziana Milizia , Roberto Vallero
IPC: C08G63/02 , C08G63/183 , C08G63/16 , C08G63/181 , C08G63/85 , C08G63/46
Abstract: This invention relates to a process for the production of polyesters comprising an esterification/transesterification stage and a polycondensation stage, characterized in that the said polycondensation stage is carried out in the presence of a catalyst comprising a mixture of at least one Titanium-based compound and at least one Zirconium-based compound in which the Ti/(Ti+Zr) ratio by weight is equal to or greater than 0.01 and equal to or less than 0.40.
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公开(公告)号:US10738149B2
公开(公告)日:2020-08-11
申请号:US16094726
申请日:2017-04-20
Applicant: Novamont S.p.A.
Inventor: Catia Bastioli , Luigi Capuzzi , Tiziana Milizia , Angelos Rallis , Roberto Vallero
IPC: C08K3/013 , C08G63/181 , C08G63/16 , C08L97/02 , B29C45/00 , C08G63/199 , C08G63/52 , C08L67/02 , C08L99/00 , C08L101/00 , C08J5/04 , C08J5/18 , C08K7/02 , B29K67/00 , C08K5/00
Abstract: Disclosed is a biodegradable compositions containing at least a polyester containing 2,5-furandicarboxylic acid and at least a polymer selected from the group consisting of polyhydroxyalkanoates and/or aliphatic and/or aliphatic-aromatic diacid diol polyesters, which is particularly suitable for use in the manufacture of mass-produced articles. The articles exhibit excellent mechanical properties, associated with a high barrier property against oxygen and carbon dioxide.
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公开(公告)号:US20160200862A1
公开(公告)日:2016-07-14
申请号:US14881640
申请日:2015-10-13
Applicant: Novamont S.p.A.
Inventor: Catia Bastioli , Giampietro Borsotti , Luigi Capuzzi , Roberto Vallero
CPC classification number: C08G63/16 , C08G63/181 , C08G63/672 , C08J5/18 , C08J2367/02 , C08J2403/00 , C08J2467/04 , C08L1/02 , C08L3/02 , C08L67/02 , C08L67/04 , C08L93/00 , C08L2203/16 , C08L2205/02 , C08L2205/03 , C08L2666/18 , C08L2666/02
Abstract: Disclosed are aliphatic-aromatic biodegradable polyesters obtained from aliphatic dicarboxylic acids, polyfunctional aromatic acids of renewable origin and particularly 2,5-furan dicarboxylic acid, and diols. Also disclosed are blends of the polyesters with other biodegradable polymers of either natural or synthetic origin. The polyesters have properties and viscosity values that make them suitable, after adjusting their molecular weight, for use in numerous practical applications such as films, injection molded products, extrusion coatings, fibers, foams, thermoformed products, extruded profiles and sheets, extrusion blow molding, injection blow molding, rotomolding, stretch blow molding.
Abstract translation: 公开了由脂族二羧酸,可再生来源的多官能芳族酸,特别是2,5-呋喃二羧酸和二醇获得的脂族 - 芳族可生物降解聚酯。 还公开了聚酯与天然或合成来源的其它可生物降解的聚合物的共混物。 聚酯的性质和粘度值在调整分子量后适用于许多实际应用,如薄膜,注射成型产品,挤出涂料,纤维,泡沫,热成型产品,挤出型材和片材,挤出吹塑 ,注塑吹塑,滚塑,拉伸吹塑成型。
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公开(公告)号:US12195420B2
公开(公告)日:2025-01-14
申请号:US17834151
申请日:2022-06-07
Applicant: NOVAMONT S.P.A.
Inventor: Marco Cotti Comettini , Roberto Vallero , Catia Bastioli , Luigi Capuzzi
IPC: C07C31/20 , B01D3/00 , B01D3/14 , B01D15/36 , C07C29/76 , C07C29/80 , C08G18/42 , C08G63/181 , C08J5/18 , C08L67/02 , C12P7/18
Abstract: The invention relates to a process for the production of 1,4-butanediol comprising the preparation of a fermentation broth comprising 1,4-butanediol from renewable sources and water, separation of a liquid fraction comprising said 1,4-butanediol and water from one or more solid fractions, said liquid fraction comprising 2-pyrrolidone in an amount higher than 80 ppm, one or more passages of the resulting liquid fraction through a bed comprising one or more cation-exchange resins thereby providing an output pH of said liquid fraction from 4 to 2, one or more passages of the resulting liquid fraction through a bed comprising one or more anion-exchange resins thereby providing an output pH of said liquid fraction from 8 to 11, and the distillation of the liquid fraction thereby provided so as to obtain a composition having a concentration of said 1,4-butanediol higher than 99.0% by weight and comprising 2-pyrrolidone in an amount lower than 6 ppm. The resulting composition should exhibit an APHA color value after ageing of less than 30.
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10.
公开(公告)号:US11377409B2
公开(公告)日:2022-07-05
申请号:US16766498
申请日:2018-11-27
Applicant: NOVAMONT S.P.A
Inventor: Marco Cotti Comettini , Roberto Vallero , Catia Bastioli , Luigi Capuzzi
IPC: C07C29/80 , B01D3/00 , B01D15/00 , C08G18/00 , C07C29/76 , B01D3/14 , B01D15/36 , C07C31/20 , C08G18/42 , C08G63/181 , C08J5/18 , C08L67/02 , C12P7/18
Abstract: The invention relates to a process for the production of 1,4-butanediol comprising the preparation of a fermentation broth comprising 1,4-butanediol from renewable sources and water, separation of a liquid fraction comprising said 1,4-butanediol and water from one or more solid fractions, said liquid fraction comprising 2-pyrrolidone in an amount higher than 80 ppm, one or more passages of the resulting liquid fraction through a bed comprising one or more cation-exchange resins thereby providing an output pH of said liquid fraction from 4 to 2, one or more passages of the resulting liquid fraction through a bed comprising one or more anion-exchange resins thereby providing an output pH of said liquid fraction from 8 to 11, and the distillation of the liquid fraction thereby provided so as to obtain a composition having a concentration of said 1,4-butanediol higher than 99.0% by weight and comprising 2-pyrrolidone in an amount lower than 6 ppm. The resulting composition should exhibit an APHA color value after ageing of less than 30.
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