公开(公告)号：US20180223194A1

公开(公告)日：2018-08-09

申请号：US15748851

申请日：2016-06-08

Applicant: PetroChina Company Limited

Inventor： Shoutao Ma ,  Xiaoqiao Huang ,  Famin Sun ,  Qingfeng Ma ,  Fangming Xie ,  Yongsheng Duan ,  Xianjun Wu ,  Fengxuan Li ,  Dongmei Ge ,  Endong Xia ,  Ruifeng Li ,  Ronglei Ji ,  Liying Liu ,  Lihong Qin ,  Xiangbin Meng ,  Chunming Dong ,  Xuefeng Lu ,  Rui Wang ,  Tiegang Xu ,  Shurong Ni

IPC: C10G45/58 ,  C10G45/72 ,  C10G69/02 ,  C10M177/00

Abstract: Provided are a liquid-phase hydroisomerization system and a process therefor and use thereof. The system comprises a gas-liquid mixer (3), a hydroisomerization reactor (4) and a fractionating column (6). An oil product and hydrogen are mixed as a liquid hydrogen-oil mixture, and are introduced into the hydroisomerization reactor for a hydroisomerization reaction, and after being fractionated, a target product is led out. A supplemental hydrogen-dissolving inner member is provided at least between a group of two adjacent catalyst bed layers in order to supplement hydrogen to the reactants. The process cancels a circulating hydrogen compressor, has a simple process flow, and can be applied to the production of a lubricant base oil by the hydroisomerization of a lubricant raw material or the production of a low freezing point diesel by the hydroisomerization of and the reduction in the freezing point of a diesel raw material.

公开(公告)号：US10258965B2

公开(公告)日：2019-04-16

申请号：US14964204

申请日：2015-12-09

Applicant: PetroChina Company Limited

Inventor： Xiaodong Yang ,  Yanfeng Liu ,  Sheng Hu ,  Chunmei Yu ,  Hongling Chu ,  Xinmiao Wang ,  Shanbin Gao ,  Bin Xie ,  Famin Sun ,  Wencheng Zhang ,  Jintao Guo ,  Quanguo Zhang ,  Lili Jiang ,  Xiaofeng Wang ,  Yuanyuan Ji ,  Ran Sun ,  Yuxiao Feng ,  Xianjun Wu ,  Guojia Zhang ,  Tan Zhao ,  Wenyong Liu ,  Rui Li ,  Ruifeng Li ,  Cheng Tang

IPC: B01J23/40 ,  B01J23/44 ,  B01J37/02 ,  B01J37/08 ,  C10G45/52 ,  B01J35/00 ,  B01J35/10 ,  B01J37/28 ,  B01J37/00

Abstract: The present invention relates to a method for preparing a sulfur-resistant catalyst for aromatics saturated hydrogenation, comprising the steps of: preparing noble metal impregnation solutions from a noble metal and deionized water or an acid solution; impregnating a carrier with the impregnation solutions sequentially from high to low concentrations by incipient impregnation; homogenizing, drying, and calcinating to obtain the sulfur-resistant catalyst for aromatics saturated hydrogenation. The catalyst for aromatics saturated hydrogenation prepared by the method according to the present invention is primarily used in processing low-sulfur and high-aromatics light distillate, middle distillate, atmospheric gas oil, and vacuum gas oil. The method according to the present invention is advantageous in that the catalyst for aromatics saturated hydrogenation exhibits good hydrofining performance, superior aromatics saturation performance, high liquid yield of products, as well as excellent desulfurization and sulfur-resistance, and the catalyst has remarkable effects in use and a great prospect of application.

公开(公告)号：US10252255B2

公开(公告)日：2019-04-09

申请号：US14964348

申请日：2015-12-09

Applicant: PetroChina Company Limited

Inventor： Xiaodong Yang ,  Chunmei Yu ,  Yanfeng Liu ,  Sheng Hu ,  Zhihua Zhang ,  Famin Sun ,  Wencheng Zhang ,  Jintao Guo ,  Wenyong Liu ,  Xinmiao Wang ,  Shanbin Gao ,  Bin Xie ,  Jinxian Jiang ,  Yuhe Yang ,  Rui Li ,  Guojia Zhang ,  Lili Jiang ,  Tan Zhao ,  Dongqing Wang ,  Jingying Zhao ,  Quanguo Zhang ,  Ruifeng Li ,  Shengbo Sun ,  Hong Li ,  Cheng Tang

IPC: B01J35/02 ,  B01J29/74 ,  B01J35/00 ,  B01J29/80 ,  B01J37/02 ,  B01J37/08 ,  C10G65/00 ,  C10M101/02

Abstract: Disclosed are a method for preparing a noble metal hydrogenation catalyst comprising preparing a carrier from a molecular sieve having a 10-member ring structure and/or an amorphous porous material; preparing a noble metal impregnation solution; and preparing noble metal impregnation solutions in a concentration gradient ranging from 0.05 to 5.0 wt % with deionized water, and sequentially impregnating the carrier with the impregnation solutions from low to high concentrations during the carrier impregnation process, or preparing a noble metal impregnation solution at a low concentration ranging from 0.05 to 0.5 wt % and impregnating the carrier by gradually increasing the concentration of the noble metal impregnation solution to 2.0 to 5.0 wt % in the impregnation process, followed by homogenization, drying, and calcination, as well as a noble metal hydrogenation catalyst, use thereof, and a method for preparing lubricant base oil.

公开(公告)号：US10683459B2

公开(公告)日：2020-06-16

申请号：US15748851

申请日：2016-06-08

Applicant: PetroChina Company Limited

Inventor： Shoutao Ma ,  Xiaoqiao Huang ,  Famin Sun ,  Qingfeng Ma ,  Fangming Xie ,  Yongsheng Duan ,  Xianjun Wu ,  Fengxuan Li ,  Dongmei Ge ,  Endong Xia ,  Ruifeng Li ,  Ronglei Ji ,  Liying Liu ,  Lihong Qin ,  Xiangbin Meng ,  Chunming Dong ,  Xuefeng Lu ,  Rui Wang ,  Tiegang Xu ,  Shurong Ni

IPC: C10G45/58 ,  C10M177/00 ,  C10G67/02 ,  C10L1/08 ,  C10M101/02 ,  C10G45/72 ,  C10G69/02

Abstract: Provided are a liquid-phase hydroisomerization system and a process therefor and use thereof. The system comprises a gas-liquid mixer (3), a hydroisomerization reactor (4) and a fractionating column (6). An oil product and hydrogen are mixed as a liquid hydrogen-oil mixture, and are introduced into the hydroisomerization reactor for a hydroisomerization reaction, and after being fractionated, a target product is led out. A supplemental hydrogen-dissolving inner member is provided at least between a group of two adjacent catalyst bed layers in order to supplement hydrogen to the reactants. The process cancels a circulating hydrogen compressor, has a simple process flow, and can be applied to the production of a lubricant base oil by the hydroisomerization of a lubricant raw material or the production of a low freezing point diesel by the hydroisomerization of and the reduction in the freezing point of a diesel raw material.

公开(公告)号：US09534178B2

公开(公告)日：2017-01-03

申请号：US14764485

申请日：2013-08-01

Applicant: PETROCHINA COMPANY LIMITED

Inventor： Shoutao Ma ,  Ran Tian ,  Zhihua Zhang ,  Gang Wang ,  Famin Sun ,  Ruiqin Zhang ,  Chunmei Yu ,  Shengbo Sun ,  Xiufang Feng ,  Fengxuan Li ,  Jinling Zhu

IPC: B01J8/00 ,  B01J8/02 ,  B01J8/04 ,  C10G45/00 ,  C10G45/02 ,  C10G65/00 ,  C10G65/02 ,  C10G65/04 ,  C10G65/08 ,  C10L1/04 ,  C10G45/20 ,  C10L1/08 ,  C10G49/00 ,  C10L1/00

CPC classification number: C10G65/08 ,  B01J8/0453 ,  B01J8/0492 ,  B01J2208/00849 ,  B01J2208/00938 ,  C10G45/20 ,  C10G65/04 ,  C10G2400/02 ,  C10G2400/04 ,  C10G2400/08 ,  C10G2400/10 ,  C10L1/04 ,  C10L1/08 ,  C10L2270/026 ,  C10L2290/545

Abstract: A hydrogenation method and distillate two-phase hydrogenation reactor in which the size of an upper space of the reactor is greater than that of a lower catalyst bed part. The reactor comprises 2 to 4 catalyst beds. An inner component for gas replenishment and for stripping a liquid-phase stream containing impurities is arranged between at least one adjacent catalyst bed and comprises a separator plate and exhaust pipes. The separator plate is provided with multiple downcomer through holes. The separator plate is connected with a plurality of exhaust pipes. The exhaust pipes are vertically arranged above the separator plate. The top parts of the exhaust pipes are in contact with the lower part of the upper catalyst bed.

Abstract translation: 一种氢化方法和蒸馏二相氢化反应器，其中反应器的上部空间的大小大于下部催化剂床部分的尺寸。 反应器包含2至4个催化剂床。 用于补充气体和用于汽提含有杂质的液相物流的内部部件设置在至少一个相邻的催化剂床之间，并且包括隔板和排气管。 隔板设有多个降液管通孔。 分隔板与多个排气管连接。 排气管垂直布置在隔板的上方。 排气管的顶部与上部催化剂床的下部接触。