公开(公告)号：US20210066621A1

公开(公告)日：2021-03-04

申请号：US17003078

申请日：2020-08-26

Applicant: PHILLIPS 66 COMPANY

Inventor： Hualong Pan ,  Kathy A. Repa ,  Brian J. Worfolk ,  Alyssa Brooke Chinen-Mendez

IPC: H01L51/00

Abstract: A polymer comprising: In this embodiment, R′ and R″, can be independently selected from the group consisting of: a halogen, a substituted alkyl, an unsubstituted alkyl, a substituted aryl, and an unsubstituted aryl. Additionally, X1 and X2 can be independently selected from the group consisting of: O, S, Se, N—R, and Si—R—R. Lastly, Ar and Ar′ can be identical or different and can be independently selected from the group consisting of: a substituted aryl, and an unsubstituted aryl.

公开(公告)号：US20210066610A1

公开(公告)日：2021-03-04

申请号：US17003066

申请日：2020-08-26

Applicant: PHILLIPS 66 COMPANY

Inventor： Hualong Pan ,  Kathy A. Repa ,  Brian J. Worfolk ,  Alyssa Brooke Chinen-Mendez

IPC: H01L51/00 ,  C08G61/12 ,  C08K9/04 ,  C08K3/04

Abstract: An organic photovoltaic device comprising a polymer: and an acceptor. In this organic photovoltaic device, R1, R2, R3, R4, R5 and R6 are independently selected from the group consisting of: a halogen, a substituted alkyl, an unsubstituted alkyl, a substituted aryl, an unsubstituted aryl, a substituted heteroaryl and an unsubstituted heteroaryl.

公开(公告)号：US11678562B2

公开(公告)日：2023-06-13

申请号：US17003066

申请日：2020-08-26

Applicant: PHILLIPS 66 COMPANY

Inventor： Hualong Pan ,  Kathy A. Repa ,  Brian J. Worfolk ,  Alyssa Brooke Chinen-Mendez

IPC: H10K85/10 ,  C08K9/04 ,  C08K3/04 ,  C08G61/12 ,  H10K85/20 ,  H10K85/60 ,  H10K30/00 ,  H10K50/15 ,  H10K50/16

CPC classification number: H10K85/113 ,  C08G61/126 ,  C08K3/045 ,  C08K9/04 ,  H10K85/151 ,  H10K85/215 ,  H10K85/6576 ,  C08G2261/122 ,  C08G2261/145 ,  C08G2261/149 ,  C08G2261/1426 ,  C08G2261/18 ,  C08G2261/228 ,  C08G2261/314 ,  C08G2261/3223 ,  C08G2261/3243 ,  C08G2261/334 ,  C08G2261/411 ,  C08G2261/51 ,  C08G2261/514 ,  C08G2261/91 ,  C08K2201/001 ,  C08K2201/011 ,  H10K30/00 ,  H10K50/15 ,  H10K50/16

Abstract: An organic photovoltaic device comprising a polymer:




and an acceptor. In this organic photovoltaic device, R1, R2, R3, R4, R5 and R6 are independently selected from the group consisting of: a halogen, a substituted alkyl, an unsubstituted alkyl, a substituted aryl, an unsubstituted aryl, a substituted heteroaryl and an unsubstituted heteroaryl.

公开(公告)号：US11600779B2

公开(公告)日：2023-03-07

申请号：US17003078

申请日：2020-08-26

Applicant: PHILLIPS 66 COMPANY

Inventor： Hualong Pan ,  Kathy A. Repa ,  Brian J. Worfolk ,  Alyssa Brooke Chinen-Mendez

IPC: H01L51/00 ,  C08K9/04 ,  C08K3/04 ,  C08G61/12 ,  H01L51/42 ,  H01L51/50

Abstract: A polymer comprising: In this embodiment, R′ and R″, can be independently selected from the group consisting of: a halogen, a substituted alkyl, an unsubstituted alkyl, a substituted aryl, and an unsubstituted aryl. Additionally, X1 and X2 can be independently selected from the group consisting of: O, S, Se, N—R, and Si—R—R. Lastly, Ar and Ar′ can be identical or different and can be independently selected from the group consisting of: a substituted aryl, and an unsubstituted aryl.

公开(公告)号：US11289653B2

公开(公告)日：2022-03-29

申请号：US17002821

申请日：2020-08-26

Applicant: PHILLIPS 66 COMPANY

Inventor： Hualong Pan ,  Kathy A. Repa ,  Brian J. Worfolk ,  Alyssa Brooke Chinen-Mendez

IPC: H01L51/00 ,  C08K9/04 ,  C08K3/04 ,  C08G61/12 ,  H01L51/42 ,  H01L51/50

Abstract: A method of reacting bis(R1) 5,5′″-dibromo-3″,4′-difluoro-[2,2′:5′,2″:5″,2′″-quaterthiophene]-3,3′″-dicarboxylate and bis(R2) 5,5′″-dibromo-3″,4′-difluoro-[2,2′:5′,2″:5″,2′″-quaterthiophene]-3,3′″-dicarboxylate to form the polymer: In this polymer R1, R2, R3, R4, R5 and R6 are independently selected from the group consisting of: a halogen, a substituted alkyl, an unsubstituted alkyl, a substituted aryl, an unsubstituted aryl, a substituted heteroaryl and an unsubstituted heteroaryl.

公开(公告)号：US20210066603A1

公开(公告)日：2021-03-04

申请号：US17002821

申请日：2020-08-26

Applicant: PHILLIPS 66 COMPANY

Inventor： Hualong Pan ,  Kathy A. Repa ,  Brian J. Worfolk ,  Alyssa Brooke Chinen-Mendez

IPC: H01L51/00 ,  C08G61/12

Abstract: A method of reacting bis(R1) 5,5′″-dibromo-3″,4′-difluoro-[2,2′:5′,2″:5″,2′″-quaterthiophene]-3,3′″-dicarboxylate and bis(R2) 5,5′″-dibromo-3″,4′-difluoro-[2,2′:5′,2″:5″,2′″-quaterthiophene]-3,3′″-dicarboxylate to form the polymer: In this polymer R1, R2, R3, R4, R5 and R6 are independently selected from the group consisting of: a halogen, a substituted alkyl, an unsubstituted alkyl, a substituted aryl, an unsubstituted aryl, a substituted heteroaryl and an unsubstituted heteroaryl.