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    Two stage upgrading of light olefins
    1.
    发明授权
    Two stage upgrading of light olefins 有权

    公开(公告)号：US10400182B2

    公开(公告)日：2019-09-03

    申请号：US15871614

    申请日：2018-01-15

    Applicant: PHILLIPS 66 COMPANY

    Inventor： Jianhua Yao ,  Hong Xie ,  Bruce B. Randolph ,  Steven E. Lusk ,  Dhananjay B. Ghonasgi ,  Jonathan R. Marda

    IPC: C10G50/00 ,  C07C2/12 ,  B01J29/40 ,  B01D3/14

    Abstract: The present disclosure relates generally processes and systems for converting a mixture of light hydrocarbons to liquid transportation fuels by first cracking the light hydrocarbons to an intermediate comprising olefins, which is converted by contacting with a catalyst comprising at least one zeolite in two separate conversion stages with an intervening recovery of liquid product. The first stage conversion favors oligomerization of larger olefins to form diesel range products that are collected prior to directing unconverted smaller olefins to be oligomerized in a second stage conversion conducted at a higher temperature and lower pressure.

    Two-stage biomass pyrolysis
    2.
    发明授权
    Two-stage biomass pyrolysis 有权

    公开(公告)号：US10174258B2

    公开(公告)日：2019-01-08

    申请号：US15435990

    申请日：2017-02-17

    Applicant: PHILLIPS 66 COMPANY

    Inventor： Dustin L. Dalluge ,  Steven E. Lusk ,  Samuel T. Jones ,  Johnathan T. Gorke

    IPC: C10B53/02 ,  C10B57/06 ,  C10B49/16 ,  C10B3/00 ,  C10B5/00 ,  C10B7/10 ,  C10B49/06 ,  C10B49/18

    Abstract: The present disclosure relates generally to a two-stage biomass pyrolysis processes that maximize pyrolysis vapor yield from a lignocellulosic biomass while being conducive to commercial-scale throughput of biomass. A lignocellulosic feedstock is first pyrolyzed in a reactor first stage comprising at least one auger at a temperature and residence time that produces pyrolysis vapors derived predominantly from cellulose and hemi-cellulose fractions of the feedstock. Partially-pyrolyzed feedstock from the reactor first stage is then pyrolyzed in a reactor second stage at a higher temperature for an additional residence time to produce additional pyrolysis vapors that are predominantly derived from lignin. Certain embodiments arrange multiple reactor first stages around a single reactor second stage.

    Systems for the catalytic activation of pentane-enriched hydrocarbon mixtures
    3.
    发明授权
    Systems for the catalytic activation of pentane-enriched hydrocarbon mixtures 有权

    公开(公告)号：US10982158B2

    公开(公告)日：2021-04-20

    申请号：US16593476

    申请日：2019-10-04

    Applicant: PHILLIPS 66 COMPANY

    Inventor： Anthony O. Baldridge ,  Neal D. McDaniel ,  James A. Suttil ,  Edward C. Weintrob ,  Jianhua Yao ,  Bruce B. Randolph ,  Maziar Sardashti ,  Robert M. Walston ,  Steven E. Lusk

    IPC: C10G69/12

    Abstract: The present disclosure relates to systems operable to catalytically convert a hydrocarbon feed stream predominantly comprising both isopentane and n-pentane to yield upgraded hydrocarbon products that are suitable for use either as a blend component of liquid transportation fuels or as an intermediate in the production of other value-added chemicals. The hydrocarbon feed stream is isomerized in a first reaction zone to convert at least a portion of the n-pentane to isopentane, followed by catalytic-activation of the isomerization effluent in a second reaction zone with an activation catalyst to produce an activation effluent. The process increases the conversion of the hydrocarbon feed stream to olefins and aromatics, while minimizing the production of C1-C4 light paraffins. Certain embodiments provide for further upgrading of at least a portion of the activation effluent by either oligomerization or alkylation.

    CATALYTIC ACTIVATION AND ALKYLATION OF ISOPENTANE-ENRICHED MIXTURES
    7.
    发明申请
    CATALYTIC ACTIVATION AND ALKYLATION OF ISOPENTANE-ENRICHED MIXTURES 审中-公开

    公开(公告)号：US20190300804A1

    公开(公告)日：2019-10-03

    申请号：US16364799

    申请日：2019-03-26

    Applicant: PHILLIPS 66 COMPANY

    Inventor： Anthony O. Baldridge ,  Neal D. McDaniel ,  James A. Suttil ,  Soumen Kundu ,  Jianhua Yao ,  Bruce B. Randolph ,  Mazi Sardashti ,  Steven E. Lusk ,  Robert M. Walston

    IPC: C10G69/12 ,  C10G5/06 ,  C10G11/05

    Abstract: The present disclosure relates generally to processes and systems for producing liquid transportation fuels by converting a feed stream that comprises both isopentane and n-pentane, and optionally, some C6+ hydrocarbons. Isopentane and smaller hydrocarbons are separated to form a first fraction while n-pentane and larger components of the feed stock form a second fraction. Each fraction is then catalytically-activated in a separate reaction zone with a separate catalyst, where the conditions maintained in each zone maximize the conversion of each fraction to olefins and aromatics, while minimizing the production of C1-C4 light paraffins. In certain embodiments, the first fraction is activated at a lower temperature than the second fraction. Certain embodiments additionally comprise mixing at least a portion of the two effluents and contacting with an alkylation catalyst to provide enhanced yields of mono-alkylated aromatics that are suitable for use as a blend component of liquid transportation fuels or other value-added chemical products.

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